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ALKALINE EARTHS . The so-called alkaline See also: earth-metals are the elements See also: beryllium, magnesium, calcium, strontium and barium
.
By the early chemists, the See also: term earth was used to denote those non-metallic substances which were insoluble in See also: water and were unaffected by strong See also: heating; and as some of these substances (e.g. lime) were found to be very similar in properties to those of the alkalis, they were called alkaline earths
.
The alkaline earths were assumed to be elements until 1807, when See also: Sir H
.
See also: Davy showed that they were oxides of various metals
.
The metals comprising this See also: group are never found in the uncombined condition, but occur most often in the See also: form of See also: carbonates and sulphates; they form oxides of the type RO, and in the See also: case of calcium, strontium and barium, of the type R02
.
The oxides of type RO are soluble in water, the solution possessing a strongly alkaline reaction and rapidly absorbing See also: carbon dioxide on exposure; they are basic in character and dissolve readily in acids with the formation of the corresponding salts
.
As the atomic See also: weight of the See also: element increases, it is found that the solubility of the sulphates in water decreases
.
Beryllium to a certain extent stands alone in many of its chemical properties, resembling to some extent the See also: metal aluminium
.
Beryllium and magnesium are permanent in dry air; calcium, strontium and barium, however, oxidize rapidly on exposure
.
The salts of all the metals of this group usually crystallize well, the chlorides and nitrates dissolve readily in water, whilst the carbonates, See also: phosphates and sulphates a're either very sparingly soluble or are insoluble in water
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