Online Encyclopedia

ALKALINE EARTHS

Online Encyclopedia
Originally appearing in Volume V01, Page 685 of the 1911 Encyclopedia Britannica.
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ALKALINE EARTHS  . The so-called alkaline

earth-metals are the elements
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beryllium, magnesium, calcium, strontium and barium . By the early chemists, the
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term earth was used to denote those non-metallic substances which were insoluble in
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water and were unaffected by strong
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heating; and as some of these substances (e.g. lime) were found to be very similar in properties to those of the alkalis, they were called alkaline earths . The alkaline earths were assumed to be elements until 1807, when
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Sir H . Davy showed that they were oxides of various metals . The metals comprising this
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group are never found in the uncombined condition, but occur most often in the form of
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carbonates and sulphates; they form oxides of the type RO, and in the case of calcium, strontium and barium, of the type R02 . The oxides of type RO are soluble in water, the solution possessing a strongly alkaline reaction and rapidly absorbing carbon dioxide on exposure; they are basic in character and dissolve readily in acids with the formation of the corresponding salts . As the atomic
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weight of the element increases, it is found that the solubility of the sulphates in water decreases . Beryllium to a certain extent stands alone in many of its chemical properties, resembling to some extent the metal aluminium . Beryllium and magnesium are permanent in dry air; calcium, strontium and barium, however, oxidize rapidly on exposure . The salts of all the metals of this group usually crystallize well, the chlorides and nitrates dissolve readily in water, whilst the carbonates,
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phosphates and sulphates a're either very sparingly soluble or are insoluble in water .

End of Article: ALKALINE EARTHS
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