Online Encyclopedia

AMYGDALIN (from the Gr. aµurySaXrt, a...

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Originally appearing in Volume V01, Page 900 of the 1911 Encyclopedia Britannica.
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AMYGDALIN (from the Gr. aµurySaXrt, almond), C2,3H27NO11, a glucoside isolated from bitter almonds by H. E. Robiquet and A. F. Boutron-Charlard in 183o, and subsequently investigated by Liebig and Wohler, and others. It is extracted from almond cake by boiling alcohol; on evaporation of the solution and the addition of ether, amygdalin is precipitated as white minute crystals. Sulphuric acid decomposes it into d-glucose, benzaldehyde and prussic acid; while hydrochloric acid gives mandelic acid, d-glucose and ammonia. The decomposition induced by enzymes may occur in two ways. Maltase partially decomposes it, giving d-glucose and mandelic nitrile glucoside, C6H5CH(CN)O•C6H11O5; this compound is isomeric with sambunigrin, a glucoside found by E. E. Bourquelot and Danjou in the berries of the common elder, Sambucus nigra. Emulsin, on the other hand, decomposes it into benzaldehyde, prussic acid, and two molecules of glucose; this enzyme occurs in the bitter almond, and consequently the seeds invariably contain free prussic acid and benzaldehyde. An " amorphous amygdalin " is said to occur in the cherry-laurel. Closely related to these glucosides is dhurrin, C14H1707N, isolated by W. Dunstan and T. A. Henry from the common sorghum or " great millet," Sorghum vulgare; this substance is decomposed by emulsin or hydrochloric acid into d-glucose, prussic acid, and p-hydroxybenzaldehyde.
End of Article: AMYGDALIN (from the Gr. aµurySaXrt, almond), C2
AMUR (known also as the Sakhalin-ula)

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