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ANIMAL

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Originally appearing in Volume V20, Page 53 of the 1911 Encyclopedia Britannica.
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ANIMAL  . FA T S Name of See also:

Fat . Source . Yield per cent . See also:Iodine Value . See also:Principal Use . Drying Fats . See also:Ice See also:bear Ursus maritimus 147 See also:Pharmacy See also:Rattlesnake Crotalus durissus 106 Pharmacy Semi-drying Fats . Horses' fat . . ~ Equus cabatlus 75-85 See also:Food, See also:soap Non-drying Fats . See also:Goose fat . Anser cinereus .

70 Food, pomades See also:

Lard See also:Sus scrofa 50-70 Food, soap, candles See also:Beef marrow See also:Bos See also:taurus 55 Pomades See also:Bone . . Bos, Ovis . 46-56 Soap, candles See also:Tallow, beef . Bos taurus 38-46 Food, soap, candles, See also:lubricants Tallow, mutton Ovis See also:aries 35-46 Food, soap, candles, lubricants See also:Butter . Bos taurus 26-38 Food in See also:hair or woollen bags and submitted to See also:hydraulic pressure, by which a further portion of oil or fat is obtained (cf . Pressing, below) . In the See also:case of those animal fats which are intended for edible purposes, such as lard, See also:suet for See also:margarine, the greatest cleanliness must, of course, be observed, and the temperature must be kept as See also:low as possible in See also:order to obtain a perfectly sweet and pure material . Pressing.—The boiling out See also:process cannot be applied to small seeds, such as See also:linseed and See also:rape See also:seed . Whilst the See also:original method of obtaining seed See also:oils may perhaps have been the same which is still used in See also:India, viz. trituration of (rape) seeds in a See also:mortar so that the oil can exude, it may be safely assumed that the process of expressing has been applied in the first instance to the preparation of See also:olive oil .. The first woman who expressed See also:olives packed in a See also:sack by heaping stones on them may be considered as the forerunner of the inventors of all the presses that subsequently came into use . See also:Pliny describes in detail the apparatus and processes for obtaining olive oil in See also:vogue among his See also:Roman contemporaries, who used already a See also:simple See also:screw See also:press, a knowledge of which they had derived from the Greeks . In the See also:East, where See also:vegetable oils See also:form an important See also:article of food and serve also for other domestic purposes, various ingenious applications of See also:lever presses and See also:wedge presses, and even of combined lever and wedge presses, have been used from the remotest See also:time .

At an See also:

early See also:stage of See also:history the See also:Chinese employed the same See also:series of operations which are followed in the most advanced oil See also:mills of See also:modern time, viz. bruising and reducing the seeds to See also:meal under an edge-See also:stone, See also:heating the meal in an open See also:pan, and pressing out the oil in a wedge press in which the wedges were driven See also:home by hammers . This See also:primitive process is still being carried out in See also:Manchuria, in the See also:production of soja See also:bean cake and soja bean oil, one of the See also:staple See also:industries of that See also:country . The olive press, which was also used in the vineyards for expressing the See also:grape juice, found its way from the See also:south of See also:France to the See also:north, and was employed there for expressing See also:poppy seed and rape seed . The apparatus was then gradually improved, and thus were evolved the modern forms of the screw press, next the Dutch or stamper press, and finally the hydraulic press . With the screw press, even in its most improved form, the amount of pressure practically obtainable is limited from the failure of its parts under the severe inelastic See also:strain . Hence this See also:kind of press finds only limited application, as in the See also:industry of olive oil for expressing the best and finest virgin oil, and in the production of animal fats for edible purposes, such as lard and oleomargarine . The Dutch or stamper press, invented in See also:Holland in the 17th See also:century, was up to the early years of the 19th century' almost exclusively employed in See also:Europe for pressing oil-seeds . It consists of two principal parts, an oblong rectangular See also:box with an arrangement of plates,. blocks and wedges, and over it a framework with heavy stampers which produce the pressure by their fall . The press box first consisted of strongly See also:bound oaken planks, but later on See also:cast-See also:iron boxes were introduced . At each extremity of the box a bag of oil-meal was placed between two perforated Iron plates, next to which were inserted filling-up pieces of See also:wood, two of which were oblique, so that the wedges which exercised the pressure could be readily driven home . This press has had to yield See also:place to the hydraulic press, although in some old-fashioned establishments in Holland the stamper press could still be seen at See also:work in the 'eighties of the 19th century . The invention of the hydraulic press in 1795 by See also:Joseph See also:Bramah (Eng. pat., 3oth See also:April 1795) effected the greatest revolution in the oil industry, bringing a new, easily controlled and almost unlimited source of See also:power into See also:play; the limit of the power being solely reached by the limit of the strength of the material which the engineer is able to produce .

Since then the hydraulic press has practically completely superseded all other appliances-used for expression, and in consequence of this See also:

epoch-making invention, assisted as it was later on by the See also:accumulator—invented by See also:William See also:George (later See also:Lord) See also:Armstrong in 1843—the seed-crushing industry reached a perfection of See also:mechanical detail which soon secured its supremacy for See also:England . The sequence of operations in treating oil seeds, oil nuts, &c., for the separation of their contained oils is at the See also:present time as follows: As a preliminary operation the oil seeds and nuts are freed from dust, See also:sand and other impurities by sifting in an inclined revolving See also:cylinder or sieving See also:machine, covered with See also:woven See also:wire;. having meshes varying according to the See also:size and nature of the seed operated upon . This preliminary See also:purification is of the greatest importance, especially for the preparation of edible oils and fats . In the case of those seeds amongst which are found pieces of iron (See also:hammer heads amongst See also:palm kernels, &c.), the seeds are passed over magnetic separators, which retain the pieces of iron . The seeds and nuts are then decorticated (where required), the shells removed,. and the kernels (" meats ") converted into a pulpy See also:mass or meal (in older establishments by crushing and grinding between stones in. edge-runners) on passing through a hopper over rollers consisting of five chilled iron or See also:steel cylinders mounted vertically like the See also:bowls of a See also:calendar . These rollers are finely grooved so that the seed is cut up whilst passing in See also:succession between the first and second rollers in the series, then between the second and the third, and so on to the last, when the grains are sufficiently bruised, crushed and ground . The distance between the rollers can be easily regulated so that the seed leaving the bottom See also:roller has the desired fineness . The comminuted mass, forming a more or less coarse meal, is either expressed in this See also:state or subjected to a preliminary heating, according to the quality of the product to be manufactured . For the preparation of edible oils and fats the meal is expressed in the See also:cold, after having been packed into bags and placed in hydraulic presses under a pressure of three See also:hundred atmospheres or even more . The cakes are allowed to remain under pressure for about seven minutes . The oil exuding in the cold dissolves the smallest amount of colouring See also:matter, &c., and hence has suffered least in its quality . Oils so obtained are known in See also:commerce as " cold See also:drawn oils," " cold pressed oils," " See also:salad oils," " virgin oils." By pressing in the cold, obviously only See also:part of the oil or fat is recovered .

A further quantity is obtained by expressing the seed meal at a somewhat elevated temperature, reached by warming the comminuted seeds or fruits either immediately after they leave the five-roller See also:

mill, or after the " cold drawn oil " has been taken off . Of course the cold pressed cakes must be first disintegrated, which may be done under an edge-runner . The same operation may be repeated once more . Thus oils of the " second expression " and of the " third expression " are obtained . In the case of oleaginous seeds of low value (See also:cotton-seed, linseed) it is of importance to See also:express in one operation the largest possible quantity of oil . Hence the bruised seed is, after leaving the five-roller mill, generally warmed at once in a See also:steam-jacketed See also:kettle fitted with a mixing See also:gear, by passing steam into the jacket, and sending at the same time some steam through a See also:rose, fixed inside the kettle, into the mass while it is being agitated . This practice is a survival of the older method of moistening the seed with a little See also:water, while the seeds were bruised under edge-runners, so as to See also:lower the temperature and facilitate the bursting of the cells . The warm meal is then delivered through measuring boxes into closed pressbags (" scourtins " of the " See also:Marseilles " press), or through measuring boxes, combined with an automatic moulding machine, into cloths open at two sides (Anglo-See also:American press), so that the preliminarily pressed cakes can be put at once into the hydraulic press . In the latest constructions of' cage presses, the use of bags is entirely dispensed with, a measured-out quantity of seed falling See also:direct into the circular press cage and being separated from the material forming the next cake by a circular See also:plate of See also:sheet iron . The essentials of proper oil pressing are a slowly accumulating pressure, so that the liberated oil may have time to flow out and See also:escape, a pressure that increases in proportion as the resistance of the material increases, and that maintains itself as the See also:volume of material decreases through the escape of oil . Numerous forms of hydraulic presses have been devised . See also:Horizontal presses have practically ceased to be used in this See also:branch of industry .

At present See also:

vertical presses are almost exclusively in vogue; the three See also:chief types of these have been already mentioned . Continuously working presses (See also:compression by a conical screw) have been patented, but hitherto they have not been found practicable . Of the vertical presses the Anglo-American type of press is most in use . It represents an open press fitted with a number (usually sixteen) of iron press plates, between which the cakes are inserted by See also:hand . A hydraulic See also:ram then forces the table carrying the cakes against a press-See also:head, and the exuding oil flows down the sides into a tank below . The " Marseilles press" is largely used in the south of France . There the meal is packed by hand in " scourtins," bags made of plaited coco-See also:nut leaves—replacing the woollen cloths used in England . The packing of the press requires more See also:manual labour than in the case of the Anglo-American press; moreover, the Marseilles press offers inconvenience in keeping the bags straight, and the pressure cannot he raised to the same height as in the more modern hydraulic presses . Oil obtained from heated meal is usually more highly coloured and harsher to the See also:taste than cold drawn oil, more of the extractive substances being dissolved and intermixed with the oil . Such oils are hardly suitable for edible purposes, and they are chiefly used for manufacturing processes . According to the care exercised by the manufacturer in the range of temperature to which the seed is heated, various grades of oils are obtained . In the case of those seeds which contain more than 4o% of oil, such as arachis nuts and See also:sesame seed, the first expression in pressbags leads to difficulty, as the meal causes " spueing," i.e. the meal exudes and escapes from the press .

Hence, in modern installations, the first expression of those seeds is carried out in so-called cage (clodding) presses, consisting of hydraulic presses provided with circular boxes or cages, into which the meal is filled . These cages or boxes are either constructed of See also:

metal staves held together by a number of steel rings, or consist of one cylinder having a large number of perforations . The presses having perforated cylinders, although presenting mechanically a more perfect arrangement, are not preferable to the press cages formed by staves, as the holes become easily clogged up by the meal, when the cylinder must be carefully cleaned out . Modern improvements, with a view to cheapening of cost, effect the transport of the cages from one press See also:battery to another on rails . In order to dispense even with the charging of the presses by hand, in some systems the cages are first charged in a preliminary press,from which they are transferred mechanically by a swinging arrangement into the final press . Whilst the meal is under pressure the oil See also:works its way to the edge of the cake, whence it exudes . For this See also:reason an oblong form is the most favourable one for the easy separation of the oil . The edges of the cakes invariably retain a considerable portion of oil; hence the soft edges are pared off, in the case of the oblong cake in a cake-paring machine, and the parings are returned to edge-runners, to be ground up and again pressed with fresh meal . Through the introduction of the cage (clodding) presses circular cakes have become fashionable, and as the material of these presses can be made much stronger and therefore higher pressure can be employed, more oil is expressed from the meal than in open presses . The oil flowing from the presses is caught in reservoirs placed under the level of the See also:floor, from which it is pumped into storage tanks for settling and clarifying . Extraction by Solvents.—The cakes obtained in the foregoing process still retain considerable proportions of oil, not less than 4 to 5 %usually, however, about to % . If it be desired to obtain larger quantities than are yielded by the above-described methods, processes having for their See also:object the extraction of the seeds by volatile solvents must be resorted to .

Extraction by means or See also:

carbon bisulphide was first introduced in 1843 by See also:Jesse See also:Fisher of See also:Birmingham . Thirteen years later E . Deiss of See also:Brunswick again patented the extraction by means of carbon bisulphide (Eng . Pat . No . 390, 1856), and added " See also:chloroform, See also:ether, essences, or benzine or benzole" to the See also:list of solvents . For several years afterwards the process made little advance, for the See also:colour of the oils produced was higher and the taste much sharper . The oil retained traces of See also:sulphur, which showed themselves disagreeably in the See also:smell of soaps made from it, and in the blackening of substances with which it was used . Of course, the meal See also:left by the process was so tainted with carbon bisuiphide that it was absolutely out of the question to use the extracted meal as See also:cattle food . With the improvement in the manufacture of carbon bisulphide, these drawbacks have been surmounted to a large extent, and the process of extracting with carbon bisuiphide has specially gained much See also:extension in the extraction of expressed olive See also:mare in the south of France, in See also:Italy and in See also:Spain . Yet even now traces of carbon bisulphide are retained by the extracted meal, so that it is impossible to feed cattle with it . Carbon bisuiphide is comparatively cheap, and it is heavier than water, hence there are certain advantages in storing so volatile and inflammable a liquid .

But owing to the physiological effect carbon bisuiphide has on the workmen, coupled. with the chemical See also:

action of impure carbon bisuiphide on iron which has frequently led to conflagrations, the employment of carbon bisulphide must remain restricted . In 1863 See also:Richardson, See also:Lundy and See also:Irvine secured a patent (Eng . Pat . No . 2315) for obtaining oil from crushed seeds, or from refuse cake, by the solvent action of volatile See also:hydrocarbons from " See also:petroleum, See also:earth oils, asphaltum oil, See also:coal oil or shale oil, such hydrocarbons being required to be volatile under 2120 F." Since that time the development of the petroleum industry in all parts of the See also:world and the large quantities of low boiling-point hydrocarbons—See also:naphtha —obtained from the petroleum See also:fields, and also the improvements in the apparatus employed, have raised this See also:system of extraction to the See also:rank of a competing See also:practical method of oil production . Of the other proposed volatile solvents See also:ordinary ether has found no practical application, as it is far too volatile and hence far too dangerous . Carbon tetrachloride, chloroform, See also:acetone and See also:benzene are far too expensive . Carbon tetrachloride would be an ideal solvent, as it is non-inflammable and shares with carbon bisulphide the See also:advantage of being heavier than water . Efforts have been made during the last few years to introduce this solvent on a large See also:scale, but its high See also:price and its physiological effect on the workmen have hitherto militated against it . At the present time the choice lies practically only between the two solvents, carbon bisuiphide and naphtha (petroleum ether) . Naphtha is preferable for oil seeds, as it extracts neither resins nor gummy matters from the oil seeds, and takes up less colouring matter than carbon bisulphide . Yet even with naphtha traces of the solvents remain, so that the.tneal obtained cannot be used for cattle feeding, notwithstanding the many statements by interested parties to the contrary .

It is true that on the See also:

continent extracted meal, especially rape meal from See also:good See also:Indian seed and palm See also:kernel meal, are somewhat largely used as food for cattle in admixture with press cakes, but in England no extracted meal is used for feeding cattle, but finds its proper use in manuring the See also:land . The apparatus employed on a large scale depends on the temperature at which the extraction is carried out . In the See also:main two types of extracting apparatus are differentiated, viz. for extraction in the cold and for extraction in the hot . The seed is prepared in a similar manner as for pressing, except that it is not reduced to a See also:fine meal, so as not to impede the percolation of the solvent through the mass . In the case of cold extraction the seed is placed in a series of closed vessels, through which the solvent percolates by displacement, on the " See also:counter-current " system . A battery of vessels is so arranged that one See also:vessel can always be made the last of the series to See also:discharge finished meal and to be recharged with fresh meal, so that the process is practically a continuous one . The See also:solution of the extracted oil or fat is then transferred to a steam-heated still, where the solvent is driven off and recovered by condensing the vapours in a cooling coil, to be used again . The last remnant of volatile solvent in the oil is driven off by a current of open steam blown through the oil in the warm state . The extracting process in the hot is carried out in apparatus, the principle of which is exemplified by the well-known Soxhlet extractor . The comminuted seed is placed inside a vessel connected with an upright refrigerator on trays or baskets, and is surrounded there by the volatile solvent . On heating the solvent with steam through a coil or jacket, the vapours rise through and around the meal . They pass into the refrigerator, where they are condensed and fall back as a condensed liquid through the meal, percolating it as they pass downwards, and reaching to the bottom of the vessel as a more or less saturated solution of oil in the solvent .

The solvent is again evaporated, leaving the oil at the bottom of the vessel until the extraction is deemed finished . The solution of fat is then run off into a still, as described already, and the last traces of solvent are driven out . The solvent is recovered and used again . With regard to the merits and demerits of the last two mentioned processes--expression and extraction—the See also:

adoption of either will largely depend on See also:local conditions and the See also:objects for which the See also:pro-ducts are intended . Wherever the cake is the main product, expression will commend itself as the most advantageous process . Where, however, the fatty material forms the main product, as in the case of palm kernel oil, or sesame and coco-nut oils from damaged seeds (which would no longer yieid proper cattle food), the process of extraction will be preferred, especially when the price of oils is high . In some cases the See also:combination of the two processes commends itself, as in the case of the production of olive oil . The fruits are expressed, and after the edible qualities and best class of oils for technical purposes have been taken off by expression, the remaining pulp is extracted by means of solvents . This process is known under the name of mixed process (huilerie mixte) . Refining and See also:Bleaching . The oils and fats prepared by any of the methods detailed above are in their fresh state, and, if got from perfectly fresh (" sweet ") material, practically neutral . If care be exercised in the process of rendering animal oils and fats or expressing oils in the cold, the products are, as a See also:rule, sufficiently pure to be delivered to the consumer, after a preliminary settling has allowed any mucilaginous matter, such as animal or vegetable See also:fibres or other impurities, and also traces of moisture, to See also:separate out .

This spontaneous clarification was at one time the only method in vogue . This process is now shortened by filtering oils through See also:

filter presses, or otherwise brightening them, e.g. by blowing with See also:air . In many cases these methods still suffice for the production of commercial oils and fats . In See also:special cases, such as the preparation of edible oils and fats, a further improvement in colour and greater purity is obtained by filtering the oils over See also:charcoal, or over natural absorbent earths, such as See also:fuller's earth . Where this process does not suffice, as in the case of coco-nut oil or palm kernel oil, a preliminary purification in a current of steam must be resorted to before the final purification, described above, is carried out . Oils intended for use on the table which See also:deposit " stearine " in See also:winter must be freed from such solid fats . This is done by allowing the oil to cool down to a low temperature and pressing it through cloths in a press, when a limpid oil exudes, which remains See also:proof against cold—" winter oil." Most olive oils are naturally non-congealing oils, whereas the Tunisian and Algerian olive oils deposit so much " stearine " that they must be " demargarina.ted." Similar methods are employed in the production of lard oil, edible cotton-seed oil, &c . For refining oils and fats intended for edible purposes only the foregoing methods, which may be summarized by the name of See also:physical methods, can be used; the only chemicals permissible are alkalis or alkaline earths to remove See also:free fatty acids present . Treatment with other chemicals renders the oils and fats unfit for See also:consumption . Therefore all bleaching and refining processes involving other means than those enumerated can only be used for technical oils and fats, such .as lubricating oils, burning oils, paint oils, soap-making oils, &c . Bleaching by the aid of chemicals requires See also:great circumspection . There is no universal method of oil-refining applicable to any and every oil or fat .

Not only must each kind of oil or fat be considered as a special problem, but frequently even varieties of one and the same oil or fat are See also:

apt to cause the same difficulties as would a new individual . In many cases the purification by means of sulphuric See also:acid, invented and patentedby See also:Charles See also:Gower in 1792 (frequently ascribed to See also:Thenard), is still usefully applied . It consists in treating the oil with a small percentage of a more or less concentrated sulphuric acid, according to the nature of the oil or fat . The acid not only takes up water, but it acts on the suspended impurities, carbonizing them to some extent, and thus causing them to coagulate and fall down in the form of a flocculent mass, which carries with it mechanically other impurities which have not been acted upon . This method is chiefly used in the refining of linseed and rape oils . Purification by means of strong See also:caustic soda was first recommended as a See also:general process by See also:Louis C . See also:Arthur Barreswil, his See also:suggestion being to See also:heat the oil and add 2% to 3% of caustic soda . In most cases the purification consisted in removing the free fatty acids from rancid oils and fats, the caustic soda forming a soap with the fatty acids, which would either rise as a scum and lift up with it impurities, or fall to the bottom and carry down impurities . This process is a useful one in the case of cotton-seed oil . As a rule, however, it is a very See also:precarious one, since emulsions are formed which prevent in many cases the separation of oil altogether . After the treatment with sulphuric acid or caustic soda, the oils must be washed to remove the last traces of chemicals . The water is then allowed to .See also:settle out, and the oils are finally filtered .

The number of chemicals which have been proposed from time to time for the purification of oils and fats is almost See also:

legion, and so See also:long as the nature of oils and fats was little understood, a See also:secret See also:trade in oil-purifying chemicals flourished . With our present knowledge most of these chemicals may be removed into the limbo of useless things . The general methods of bleaching besides those mentioned already as physical methods, viz. filtration over charcoal or bleaching earth, are chiefly methods based on bleaching by means of See also:oxygen or by See also:chlorine . The methods of bleaching by oxygen include all those which aim at the bleaching by exposure to the air and to sunlight (as in the case of artists' linseed-oil), or where oxygen or See also:ozone is introduced in the form of See also:gas or is evolved by chemicals, as See also:manganese dioxide, See also:potassium bichromate or potassium permanganate and sulphuric acid . In the process of bleaching by means of chlorine either bleaching See also:powder or bichromates and hydrochloric acid are used . It must again be emphasized that no general rule can be laid down as to which process should be employed in each given case . There is still a wide See also:field open for the application of proper processes for the removal of impurities and colouring matters without See also:running the See also:risk of attacking the oil or fat itself . Oil Testing.—Reliable scientific methods for testing oils and fats date back only to the end of the 'seventies of the 19th century . Before that time it was believed that not only could individual oils and fats be distinguished from each other by colour reactions, but it was also maintained that falsification could be detected thereby . With one or two exceptions (detection of sesame oil and perhaps also of cotton-seed oil) all colour reactions are entirely useless . The modern methods of oil testing See also:rest chiefly on so-called " quantitative " reactions, a number of characteristic " values " being determined which, being based on the special nature of the fatty acids contained in each individual oil or fat, assist in identifying them and also in revealing See also:adulteration . These " values," together with other useful methods, are enumerated in the order of their utility for the purposes of testing .

The saponification value (saponification number) denotes the number of milligrams which one gramme of an oil or fat requires for saponification, or, in other words, for the neutralization of the See also:

total fatty acids contained in an oil or fat . We thus measure the See also:alkali absorption value of all fatty acids contained in an oil or fat . The saponification values of most oils and fats See also:lie in the neighbourhood of 195 . But the oils belonging to the rape oil See also:group are characterized by considerably lower saponification values, viz. about 175 on See also:account of their containing notable quantities of erucic acid, CnH.t,O2 . In the case of those oils which do not belong to the rape oils and yet show abnormally low saponification values, the suspicion is raised at once that a certain amount of See also:mineral oils (which do not absorb alkali and are therefore termed " unsaponifiable ") has been admixed fraudulently . Their amount can be determined in a direct manner by exhausting the saponified mass, after dilution with water, with ether, evaporating the latter and weighing the amount of mineral oil left behind . A few of the blubber oils, like See also:dolphin See also:jaw and See also:porpoise jaw oils (used for lubricating typewriting See also:machines), have exceedingly high saponification values owing to their containing volatile fatty acids with a small number of carbon atoms . Notable also are coco-nut and palm-nut oils, the saponification See also:numbers of which vary from 240 to 260, and especially butter-fat, which has a saponification value of about 227 . These high saponification values are due to the presence of (glycerides of) volatile fatty acids, and are of extreme usefulness to the See also:analyst, especially in testing butter-fat for added margarine and other fats . These volatile acids are specially measured by the Reichert value (Reichert-Wollny value) . To ascertain this value the volatile acids contained in 5 grammes of an oil or fat are distilled in a minutely prescribed manner, and the distilled-off acids are measured by titration with decinormal alkali . Whereas most of the oils and fats, viz. all those the saponification value of which lies at or below 195, contain practically no volatile acids,i.e. have extremely low Reichert-Wollny values, all those oils and fats haying saponification'values above 195 contain notable amounts of volatile fatty acids .

Thus, the Reichert-Meissl value of butter-fat is 25-30, that of coco-nut oil 6-7, and of palm kernel oil about 5-6 . This value is indispensable for judging the purity of a butter . One of the most important values in oil testing is the iodine value . This indicates the percentage of iodine absorbed by an oil or fat when the latter is dissolved in chloroform or carbon tetrachloride, and treated with an accurately measured amount of free iodine supplied in the form of iodine chloride . By this means a measure is obtained of the unsaturated fatty acids contained in an oil or fat . On this value a scientific See also:

classification of all oils and fats can be based, as is shown by the above-given list of oils and fats . The unsaturated fatty acids which occur chiefly in oils and fats are oleic acid, iodine value 90.07; erucic acid, iodine value 75.15; linolic acid, iodine value 181.42; linolenic acid, iodine value 274.1; and clupanodonic acid, iodine value 367.7 . Oleic acid occurs in all non-drying oils and fats, and to some extent in the semi-drying oils and fats . Linolic acid is a characteristic constituent of all semi-drying, and to some extent of all drying oils . Linolenic acid characterizes all vegetable drying oils; similarly clupanodonic acid characterizes all marine animal oils . If one individual oil or fat is given, the iodine value alone furnishes the readiest means of finding its place in the above system, and in many cases of identifying it . Even if a mixture of several oils . and, fats be present, the iodine value assists greatly in the See also:identification of the components of the mixture, and furnishes the most important See also:key for the attacking and resolving of this not very simple problem .

Thus it points the way to the application of a further method to resolve the isolated fatty acids of an oil or fat into saturated fatty acids, which do not absorb iodine, and into unsaturated fatty acids, which absorb iodine in various proportions as shown above . This separation is effected by converting the alkali soaps of the fatty acids into See also:

lead soaps and treating the latter with ether, in which the lead salts of the saturated acids are insoluble, whereas the salts of the above-named unsaturated acids are soluble . The saturated fatty acids can then be further examined, and valuable See also:information is gained by the determination of the melting-points and by treatment with solvents . Thus some individual fatty acids, such as stearic acid and arachidic acid (which is characteristic of ground nut oil) can be identified . In the mixture of unsaturated fatty acids, by means of some more refined methods, clupanodonic acid, linolenic acid, linolic acid and oleic acid can be recognized . By combining the various methods which have been outlined here, and by the help of some further additional special methods, and by reasoning in a strictly logical manner, it is possible tc resolve a mixture of two oils and fats, and even of three and four, into their components and determine approximately their quantities . The methods sketched here do not yet exhaust the armoury of the See also:analytical chemist, but it can only be pointed out in passing that the detection of hydroxylated acids enables the analyst to ascertain the presence of See also:castor oil, just as the See also:isolation and determination of oxidized fatty acids enables him to differentiate blown oils from other oils . Tests such as the Maumene test, the elaldin test and others, which formerly were the only resource of the chemist, have been practically superseded by the foregoing methods . The viscosity test, although of considerable importance in the examination of lubricating oils, has been shown to have very little discriminative value as a general test . Commerce.—It may be safely said of the See also:United See also:Kingdom that it takes the foremost position in the world as regards the extent of the oil and fat industries . An estimate made by the writer (Cantor Lectures, " Oils and Fats, their Uses and Applications," Society of Arts, 1go4, p . 795), and based on the most. reliable information obtainable, led to the conclusion that the sums involved in the oil and fat trade exceeded £1,000,000 perweek; in 1907 they approximated 1,25o,000 per See also:week .

The great centres of the seed-oil trade (linseed, cotton-seed, rape-seed, castor-seed) are See also:

Hull, See also:London, See also:Liverpool, See also: