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See also:ATMOSPHERE (Gr. See also:fir µ6r, vapour; orkaipa, a See also:sphere) , the aeriform envelope encircling the See also:earth; also the envelope of a particular See also:gas or gases about any solid or liquid . Meteorological phenomena seated more directly in the See also:atmosphere obtained See also:early recognition; thus See also:Hesiod, in his See also:Works and Days, speculated on the origin of winds, ascribing them to the See also:heating effects of the See also:sun on the See also:air . Ctesibius of See also:Alexandria, See also:Hero and others, founded the See also:science of See also:pneumatics on observations , on the See also:physical properties of air . Anaximenes made air the primordial substance, and it was one of the Aristotelian elements . A See also:direct See also:proof of its material nature was given by Galileo, who weighed a See also:copper See also:ball containing compressed air . Before the development of pneumatic See also:chemistry, air was regarded as a distinct chemical unit or See also:element . The study of calcination and See also:combustion during the 17th and 18th centuries culminated in the See also:discovery that air consists chiefly of a mixture of two gases, See also:oxygen and See also:nitrogen . See also:Cavendish, See also:Priestley, See also:Lavoisier and others contributed to this result . Cavendish made many analyses: from more than 500 determinations of air in See also:winter and summer, in wet and clear See also:weather, and in See also:town and See also:country, he discerned the mean See also:composition of the atmosphere to be, oxygen 20.833 % and nitrogen 79.167 % The same experimenter noticed the presence of an inert gas, in very See also:minute amount ; this gas, afterwards investigated by See also:Rayleigh and See also:Ramsay, is.now named See also:argon (q.v.) . The constancy of composition shown by repeated analyses of atmospheric air led to the view that it was a chemical See also:compound of nitrogen and oxygen; but there was no experimental See also:confirmation of this See also:idea, and all observations tended to the view that it is simply a See also:mechanical mixture . Thus, the gases are not See also:present in See also:simple multiples of their combining weights; atmospheric air results when oxygen and nitrogen are mixed in the prescribed ratio, the mixing being unattended by any manifestation of See also:energy, such as is invariably associated with a chemical See also:action; the gases may be mechanically separated by See also:atmolysis, i.e. by taking See also:advantage of the different rates of See also:diffusion of the two gases; the solubility of air in See also:water corresponds with the " See also:law of partial pressures," each gas being absorbed in amount proportional to its pressure and coefficient of absorption, and oxygen being much more soluble than nitrogen (in the ratio of •04114 to •02035 at o''); air expelled from water by boiling is always richer in oxygen . Various agencies are at See also:work tending to modify the composition of the atmosphere, but these so neutralize each other as to leave it practically unaltered .
Minute See also:variations, however, do occur
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See also:Bunsen analysed fifteen examples of air collected at the same See also:place at different times, and found the extreme range in the percentage of oxygen to be from 2o•97 to 2o•84
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See also:Regnault, from analyses of the air of See also:Paris, obtained a variation of 2o•999 to 20.913; country air varied from 20 903 to 21.000; while air taken from over the See also:sea showed an extreme variation of 20.940 to 20.850
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See also:Angus See also: Ammonia is also present, but in very varying amounts, ranging from 135 to 0•1 parts (calculated as carbonate) in a million parts of air . Ammonia is carried back to the See also:soil by means of rain, and there plays an important See also:part in. providing nitrogenous See also:matter which is after-wards assimilated by See also:vegetable See also:life . The average See also:volume composition of the gases of the atmosphere may be represented (in parts per 1o,000) as follows: Oxygen . . . . 2065.94 Ozone . . . 0.015 Nitrogen . . 7711.60 Aqueous vapour 140.00 Argon (about) . . 79.00 Nitric acid . . o•o8 Carbon dioxide . 3.36 Ammonia . . 0.005 In addition to these gases, there are always present in the atmosphere many micro-organisms or bacteria (see See also:BACTERIOLOGY); another invariable constituent is dust (q.v.), which plays an important'part in meteorological phenomena . Reference should be made to the articles See also:BAROMETER, See also:CLIMATE and See also:METEOROLOGY for the measurement and variation of the pressure of the atmosphere, and the discussion of other properties . |
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