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ATMOSPHERE (Gr. fir µ6r, vapour; orka...

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Originally appearing in Volume V02, Page 860 of the 1911 Encyclopedia Britannica.
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ATMOSPHERE (Gr. See also:fir µ6r, vapour; orkaipa, a See also:sphere)  , the aeriform envelope encircling the See also:earth; also the envelope of a particular See also:gas or gases about any solid or liquid . Meteorological phenomena seated more directly in the See also:atmosphere obtained See also:early recognition; thus See also:Hesiod, in his See also:Works and Days, speculated on the origin of winds, ascribing them to the See also:heating effects of the See also:sun on the See also:air . Ctesibius of See also:Alexandria, See also:Hero and others, founded the See also:science of See also:pneumatics on observations , on the See also:physical properties of air . Anaximenes made air the primordial substance, and it was one of the Aristotelian elements . A See also:direct See also:proof of its material nature was given by Galileo, who weighed a See also:copper See also:ball containing compressed air . Before the development of pneumatic See also:chemistry, air was regarded as a distinct chemical unit or See also:element . The study of calcination and See also:combustion during the 17th and 18th centuries culminated in the See also:discovery that air consists chiefly of a mixture of two gases, See also:oxygen and See also:nitrogen . See also:Cavendish, See also:Priestley, See also:Lavoisier and others contributed to this result . Cavendish made many analyses: from more than 500 determinations of air in See also:winter and summer, in wet and clear See also:weather, and in See also:town and See also:country, he discerned the mean See also:composition of the atmosphere to be, oxygen 20.833 % and nitrogen 79.167 % The same experimenter noticed the presence of an inert gas, in very See also:minute amount ; this gas, afterwards investigated by See also:Rayleigh and See also:Ramsay, is.now named See also:argon (q.v.) . The constancy of composition shown by repeated analyses of atmospheric air led to the view that it was a chemical See also:compound of nitrogen and oxygen; but there was no experimental See also:confirmation of this See also:idea, and all observations tended to the view that it is simply a See also:mechanical mixture . Thus, the gases are not See also:present in See also:simple multiples of their combining weights; atmospheric air results when oxygen and nitrogen are mixed in the prescribed ratio, the mixing being unattended by any manifestation of See also:energy, such as is invariably associated with a chemical See also:action; the gases may be mechanically separated by See also:atmolysis, i.e. by taking See also:advantage of the different rates of See also:diffusion of the two gases; the solubility of air in See also:water corresponds with the " See also:law of partial pressures," each gas being absorbed in amount proportional to its pressure and coefficient of absorption, and oxygen being much more soluble than nitrogen (in the ratio of •04114 to •02035 at o''); air expelled from water by boiling is always richer in oxygen . Various agencies are at See also:work tending to modify the composition of the atmosphere, but these so neutralize each other as to leave it practically unaltered .

Minute See also:

variations, however, do occur . See also:Bunsen analysed fifteen examples of air collected at the same See also:place at different times, and found the extreme range in the percentage of oxygen to be from 2o•97 to 2o•84 . See also:Regnault, from analyses of the air of See also:Paris, obtained a variation of 2o•999 to 20.913; country air varied from 20 903 to 21.000; while air taken from over the See also:sea showed an extreme variation of 20.940 to 20.850 . See also:Angus See also:Smith determined See also:London air to vary in oxygen content from 2o•857 to 20.95, the air in parks and open spaces showing the higher percentage; See also:Glasgow air showed similar results, varying from 20.887 in the streets to 2o•929 in open spaces . In addition to nitrogen and oxygen, there are a number of other gases and vapours generally present in the atmosphere . Of these, argon and its See also:allies were the last to be definitely isolated . See also:Carbon dioxide is invariably present, as was inferred by Dr See also:David Macbride (1726–1778) of See also:Dublin in 1764, but in a See also:pro-portion which is not absolutely See also:constant; it tends to increase at See also:night, and during dry winds and fogs, and it is greater in towns than in the country and on See also:land than on the sea . Water vapour is always present; the amount is determined by See also:instruments termed hygrometers (q.v.) . See also:Ozone (q.v.) occurs, in an amount supposed to be associated with the development of atmospheric See also:electricity (See also:lightning, &c.); this amount varieswith the seasons, being a maximum in See also:spring, and decreasing through summer and autumn to a minimum in winter . See also:Hydrogen dioxide occurs in a manner closely resembling ozone . Nitric See also:acid and See also:lower nitrogen oxides are present, being formed by See also:electrical discharges, and by the oxidation of atmospheric See also:ammonia by ozone . The amount of nitric acid varies from place to place; See also:rain-water, collected in the country, has been found to contain an See also:average of 0•5 parts in a million, but town rain-water contains more, the greater amounts being present in the more densely populated districts .

Ammonia is also present, but in very varying amounts, ranging from 135 to 0•1 parts (calculated as carbonate) in a million parts of air . Ammonia is carried back to the See also:

soil by means of rain, and there plays an important See also:part in. providing nitrogenous See also:matter which is after-wards assimilated by See also:vegetable See also:life . The average See also:volume composition of the gases of the atmosphere may be represented (in parts per 1o,000) as follows: Oxygen . . . . 2065.94 Ozone . . . 0.015 Nitrogen . . 7711.60 Aqueous vapour 140.00 Argon (about) . . 79.00 Nitric acid . . o•o8 Carbon dioxide . 3.36 Ammonia . . 0.005 In addition to these gases, there are always present in the atmosphere many micro-organisms or bacteria (see See also:BACTERIOLOGY); another invariable constituent is dust (q.v.), which plays an important'part in meteorological phenomena .

Reference should be made to the articles See also:

BAROMETER, See also:CLIMATE and See also:METEOROLOGY for the measurement and variation of the pressure of the atmosphere, and the discussion of other properties .

End of Article: ATMOSPHERE (Gr. fir µ6r, vapour; orkaipa, a sphere)
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ATMOLYSIS (Gr. arµos, vapour: XGecv, to loosen)
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