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BLEACHING
, the See also:process of whitening or depriving See also:objects of See also:colour, an operation incessantly in activity in nature by the See also:influence of See also:light, See also:air and moisture
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The See also:art of bleaching, of which we have here to treat, consists in inducing the rapid operation of whitening agencies, and as an See also:industry it is mostly directed to See also:cotton, See also:linen, See also:silk, See also:wool and other textile See also:fibres, but it is also applied to the whitening of See also:paper-pulp, bees'-See also:wax and some See also:oils and other substances
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The See also:term bleaching is derived from the A.-S. blaesan, to bleach, or to fade, from which also comes the cognate See also:German word bleichen, to whiten or render See also:pale
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Bleachers, down to the end of the 18th See also:century, were known in See also:England as " whitsters," a name obviously derived from the nature of their calling
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The operation of bleaching must from its very nature be of the same antiquity as the See also:work of washing textures of linen,cotton or other See also:vegetable fibres
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Clothing repeatedly washed, and exposed in the open air to dry, gradually assumes a whiter and whiter See also:hue, and our ancestors cannot have failed to See also:notice and take See also:advantage of this fact
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Scarcely anything is known with certainty of the art of bleaching as practised by the nations of antiquity
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See also:Egypt in See also:early ages was the See also:great centre of textile manufactures, and her See also:
In See also:modern times, down to the See also:middle of the 18th century, the Dutch possessed almost a See also:monopoly of the bleaching See also:trade although we find mention of bleach-See also:works at See also:Southwark near See also:London as early as the middle of the 17th century
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It was customary to send all the See also: The cloth was then steeped for some days in sour milk, washed clean and crofted . These processes were repeated, diminishing every time the strength of the alkaline lye, till the linen had acquired the requisite whiteness . For the first improvement in this tedious process, which was faithfully copied from the Dutch bleachfields, manufacturers were indebted to Dr See also:Francis See also:Home of See also:Edinburgh, to whom the Board of Trustees paid £See also:loo for his experiments in bleaching . He proposed to substitute See also:water acidulated with sulphuric See also:acid for the sour milk previously employed, a See also:suggestion made in consequence of the new mode of preparing sulphuric acid; contrived some time before by Dr John See also:Roebuck, which reduced the See also:price of that acid to less than one-third of what it had formerly been . When this See also:change was first adopted by-,the bleachers, there was the same outcry against its corrosive effects as arose when See also:chlorine was substituted for crofting . A great advantage was found to result from the use of sulphuric acid, which was that a souring with sulphuric acid required at the longest only twenty-four See also:hours, and often not more than twelve; whereas, when sour milk was employed, six weeks, or even two months, were requisite, according to the See also:state of the See also:weather . In consequence of this, improvement, the process of bleaching was shortened from eight months to four, which enabled the merchant to dispose of his goods so much the sooner; and consequently to trade with less See also:capital . No further modification of consequence was introduced in the art till the year 1787, when a most important change was • initiated by the use of chlorine (q.v.), an See also:element which had been discovered by C . W . See also:Scheele in See also:Sweden about thirteen years before . The See also:discovery that this See also:gas possesses the See also:property of destroying vegetable See also:colours, led Berthollet to suspect that it might be introduced with advantage into the art of bleaching, and that it would enable See also:practical bleachers greatly to shorten their processes . In a paper on. chlorine or oxygenated muriatic acid, read before the See also:Academy of Sciences at See also:Paris in See also:April 1785, and published in the See also:Journal de Physique for May of the same year (vol .
'See also:xxvi. p
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325), he mentions that he had tried the effect of the gas in bleaching cloth, and found that it answered perfectly
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This See also:idea is still further See also:developed in a paper on the same substance, published in the Journal de Physique for 1786
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In 1786 he exhibited the experiment to James See also:Watt, who, immediately upon his return to England, commenced a practical examination of the subject, and was accordingly the See also:person who first introduced the new method of bleaching into Great See also:Britain
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We find from Watt's own testimony that chlorine was practically employed in the bleachfield of his See also:father-in-See also:law, Mr See also:Macgregor, in the neighbourhood of See also:Glasgow, in March 1787
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Shortly thereafter the method was introduced at See also:Aberdeen by Messrs See also:Gordon, Barron & Co., on See also:information received from De See also:Saussure through See also:Professor See also:Patrick See also:Copland of Aberdeen
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See also: Bleaching of Cotton . Cotton is bleached in the raw state, as See also:yarn and in the piece . In the raw state, and as yarn, the only impurities present are those which are naturally contained in the fibres and which include cotton wax, fatty acids, pectic substances, colouring matters, albuminoids and See also:mineral See also:matter, amounting in all to some 5 % of the weight of the material . Both in the raw state and in the manufactured See also:condition cotton also contains small See also:black particles which adhere firmly to the material and are technically known as " motes." These consist of fragments of the cotton See also:seed husk, which cannot be completely removed by See also:mechanical means . The bleaching of cotton pieces is more complicated, since the bleacher is called upon to remove the sizing materials with which the manufacturer strengthens the warp before See also:weaving (see below) . In principle, the bleaching of cotton is a comparatively See also:simple process in which three See also:main operations are involved, viz . (1) boiling with an alkali; (2) bleaching the organic colouring matters by means of a hypochlorite or some other oxidizing See also:agent; (3) souring, i.e. treating with weak hydrochloric or sulphuric acid . For loose cotton and , yarn these three operations are sufficient, but for piece goods a larger number of operations is usually necessary in See also:order to obtain a satisfactory result . Loose Cotton.—The bleaching of loose or raw cotton previous to See also:spinning is only carried' out to a very limited extent, and consists essentially irr first steeping the material in a warm solution of soda for some hours, after which it is washed and treated with a solution of bleaching powder or See also:sodium hypochlorite . It is then again washed, soured with weak sulphuric or hydrochloric acid, and ultimately washed free from acid . Careful treatment is necessary inorder to avoid any undue See also:matting of the fibres, while any drastic treatment, such as See also:heating with See also:caustic soda and See also:soap, as used for other cotton materials, cannot be employed, since the natural wax would thereby be removed, and this would detract from the spinning qualities of the fibre . ' In See also:case the cotton is not intended tO be spun, but is to serve for cotton wool or for the manufacture of See also:gun cotton, more drastic treatment can be employed, and is, in fact, desirable . Thus, cotton waste is first extracted with See also:petroleum spirit or some other suitable solvent, in order to remove any mineral oil or grease which may be present . It is then boiled with dilute caustic soda and See also:resin soap, washed, bleached white with bleaching-powder, washed, soured and finally washed free from acid . In these operations, a certain amount of matting is unavoidable, and it is consequently necessary to open out the material after drying, in scutchers . Cotton Yarn.—Cotton yarn is bleached in the form of cops, hanks or warps . In principle the processes employed are the same in each case, but the machinery necessarily differs . Most yarn is bleached in the hank, and it will suffice to give an See also:account of this process only . The sequence of operations is the same as in the bleaching of cotton waste, and these can be conducted for small lots in an See also:ordinary rectangular wooden vat as used in See also:dyeing, in which the , yarn is suspended in the liquor from poles which See also:rest with their ends on the two longer sides of the vat . For bleaching See also:yam in bulk, however, this mode of procedure would involve so much See also:manual labour that the process would become too expensive . It is, therefore, mainly with the See also:object of See also:economy that machinery has been introduced, by means of which large quantities can be dealt with at a time . The first operation, viz. that of boiling in alkali, is carried out in a " kier," a large, See also:egg-ended, upright cylindrical See also:vessel, constructed of See also:boiler-See also:plate and capable of treating, from one to three tons of yarn at a time . In construction, the kiers used for yarn bleaching are similar in construction to those used for pieces (see below) . The yarn to he bleached is evenly packed in the kier, and is then boiled by means of See also:steam with the alkaline lye (3–4 % of soda ash or z % caustic soda on the weight of the cotton being usually employed) for periods varying from six to twelve hours .
It is essential that a thorough circulation of the liquor should be maintained during the boiling, and this is effected either by means of a steam See also:injector, or in other ways
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As a See also:rule See also:low pressure kiers (working up to io lb pressure) are employed for yarn bleaching, though some bleachers prefer to use high pressure kiers for the purpose
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When the boiling has continued for the requisite time (6--8 hours), the steam is shut off, and the kier liquor blown off, when the yarn is washed in the kier by filling the latter with water and then See also:running off, this operation being repeated two or three times
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The hanks are, now transferred to a See also: The bleaching of cotton yarn is a very straightforward process, and it is very seldom that either complications or faults arise, providing that reasonable care and supervision are exercised . The raison d'etre of the various operations is comparatively simple . The effect of boiling with alkali is to remove the pectic acid, the fatty acids, part of the cotton wax and the bulk of the colouring matter, while the albuminoids are destroyed and the motes swelled up . If soap be used along with the alkali, the whole of the wax is removed by emulsification . In the operation of bleaching proper, the See also:calcium hypochlorite of the chloride of lime through coming into contact with the carbonic acid of the See also:atmosphere suffers decomposition according to the See also:equation, Ca(OCI)2+See also:CO2+See also:H2O-CaCO3+2HOC1, and the hypochlorous acid thus liberated destroys the colouring matter still remaining from the first operation, by oxidation . At the same time the motes which were swelled up by the alkali are broken up into small fragments and are thus removed . In the operation of souring, the lime which has been deposited on the fibres during the treatment with bleaching powder is dissolved, while at the same time any other metallic oxides (See also:iron, See also:copper, &c.) are removed . Cotton Pieces.—By far the largest bulk of cotton is bleached in the piece, as it can be more conveniently and more economically dealt with in this form than in any other . Though similar in principle to yarn bleaching, the process of piece bleaching is somewhat more complex because the pieces contain in addition to the natural impurities of the cotton a considerable amount of See also:foreign matter in the form of See also:size which has been incorporated with the Warp before weaving, with the object of strengthening it . This size consists essentially of See also:starch (See also:farina), with additions of See also:tallow, See also:zinc chloride, and occasionally other substances such as See also:paraffin wax, See also:magnesium chloride, soap, &c., all of which.must be removed if a perfect bleach is to result . Besides, mineral oil stains from the machinery of the weaving-See also:shed are of common occurrence in piece goods . Cotton pieces are bleached either for whites, for prints or for dyed goods . The processes employed for these different classes vary but slightly and only in detail . The most drastic bleach is that required for goods which are subsequently to be printed . For dyed goods, the main object is not so much to obtain a perfect white as to remove any impurities which might interfere with the dyeing, while avoiding the formation of any oxycellulose . In bleaching for whites (" See also:market bleaching ") it is essential that the white should be as perfect as possible, and such goods are consequently invariably blued after bleaching . For small lots (I-2o pieces) the bleaching can be conducted on very simple machinery . Thus many small piece dyers conduct the whole of their bleaching on the jigger, a simple form of dyeing See also:machine on which most cotton piece goods are dyed (see DYEING) . For muslins, laces and other very light fabrics, which will not stand rough handling, the operations are conducted mainly by See also:hand, washing being effected in the dash-See also:wheel (fig . I), which consists of a cylindrical See also:box, revolv- See also:ing on its See also:axis . It has four divisions, as shown by the dotted lines, and an opening into each See also:division . A number of pieces are put into each, abundance of water is admitted be- See also:hind, and the knocking of the pieces as they alternately dash from one See also:side of the division to the other during the revolution of the wheel effects the washing . The process lasts from four to six minutes . For velveteens, See also:cor- duroys, heavy drills, pocketings and other fabrics in which creasing has to be avoided as much as possible, the so-called " open bleach " is resorted to, which differs from the ordinary process chiefly in that the goods are treated throughout at full width . The great bulk of cotton pieces is bleached in rope form, i.e. stitched together end to end and laterally collapsed, so that they will pass through a See also:ring of 4 to 5 in. in See also:diameter . The first operation which the goods undergo on arriving in the See also:grey-See also:room of the bleachworks is that of stamping with See also:tar or some other indelible material in order that they may be identified after passing through the whole process . They are then stitched together end to end by means of See also:special sewing See also:machines, the stitch being of such a nature (See also:chain stitch) that the See also:thread can be ripped out at one pull at the end of the operations . Singeing.—In the condition in which the pieces leave the See also:loom and come into the hands of the bleacher, the See also:surface of the fabric is seen to be covered with a See also:nap of projecting fibres which gives it a downy See also:appearance . For some classes of goods this is not a disadvantage, but in the See also:majority of cases, especially for prints where a clean surface is essential, the nap is removed before bleaching . This is usually effected by running the pieces at full width over a couple of.arched copper plates heated to a full red See also:heat by See also:direct See also:fire . An arrangement of the See also:kind is shown in fig . 2, in which the singe-plates, a and b, are mounted over the flues of a See also:coal fire . The plate b is most highly heated, a being at the end of the flue farthestremoved from the fire . The cloth enters over a See also:rail A, and in passing over the plate a is thoroughly dried and prepared for the singeing it receives when it comes to the highly-heated plate b . A See also:block d, carrying two rails in the space between the plates, can be. raised or lowered so as to increase or lessen the pressure of the cloth against the plates, or, if necessary, to lift it quite free of contact with them . The pieces on leaving the singeing machine are passed either through a water trough or through a steam box with the object of extinguishing See also:sparks, and are then plaited down . The See also:speed at which the pieces travel over the singe plates is necessarily considerable and varies with different classes of material.' In lieu of plates, a See also:cast-iron See also:cylinder is sometimes employed (" See also:roller singeing "), the heating being effected by causing the See also:flame of the fire to be drawn through the roller, which is carried on two small rollers at each end and revolves slowly in the See also:reverse direction to that followed by the piece, thus exposing continuously a freshly heated surface and avoiding uneven cooling . For figured pieces which have an uneven surface, it is obvious that plate or roller singeing would only affect the portions which project most, leaving the rest untouched . For such goods, " gas singeing " is employed, which consists in running the pieces over a non-luminous gas flame, the breadth of which slightly exceeds that of the piece, or in See also:drawing the flame right through the piece.2 The construction of an ordinary gas singeing apparatus is seen in See also:section in fig . 3 . Coal gas mixed with air is sent under pressure through pipe a mo the burners b, b, where the mixture See also:burns with an intense heat . The cloth travels in the direction of the arrows, and in passing over the small nap rollers c comes into contact with the flame four times in See also:succession before leaving the machine . Gas singeing is also used for See also:plain goods, and being cleaner and under better See also:control has largely replaced plate singeing . At this stage the goods which have been browned on the surface by singeing are ready for the bleaching operations . A great many innovations have been introduced in See also:recent years in the bleaching of See also:calico, but although it is generally admitted that in point of view of time and economy many of these processes offer considerable advantages, the old process, in which a lime See also:boil precedes the other operations, is still the one which is most largely employed by bleachers in England . In this, the sequence of operations is the following— . Grey Washing.—This operation (which is sometimes omitted) simply consists in running the pieces through an ordinary washing machine (as shown in fig . 5) through water in order to wet them out . On leaving the machine they are piled in a heap and See also:left over See also:night, when See also:fermentation sets in, which results in the starch being to a large extent hydrolysed and rendered soluble in water . Lime Boil.—In this operation, which is also known as bowking (Ger. beuchen), the pieces are first run through milk of lime contained in an ordinary washing machine and of such a-strength ' Besides being used for cotton goods, plate singeing is also employed for certain classes of worsted goods (alpacas, See also:bunting, &c.), and for most uniongoods (cotton warp and worsted weft) . - 2 A machine working on this principle has been constructed by F . Binder, and the makers of the machine (Messrs See also:Mather & See also:Platt, Ltd.) claim that it does better service than the machines constructed on the older principle . hillllllll~Ili1'I IIJ J 00IIIIIIIIOIIII IIIIlllh Int\lijpryVliR . See also:Ili~l I'i l l i, l !III l t1f ilIuluaultrouaoiIuuuIliniuN 4pq' !'dli that they take up about 4% of their weight of lime (CaO) . They are then run over winches and guided through smooth See also:porcelain rings (" pot-eyes ") into the kier, where they are evenly packed by boys who enter the vessel through the manhole at the top . It is of the greatest importance that the goods should be evenly packed, for, if channels or loosely-packed places are left, the liquor circulating through the kier, when boiling is subsequently in progress, will follow the line of least resistance, and the result is an uneven treatment . Of the numerous forms of kier in use, the injector kier is the one most generally adopted . This consists of an egg-ended cylindrical vessel constructed of stout boiler plate and shown in sectional See also:elevation in fig . 4 . The kier is from t0 to I2 ft. in height and from 6 to 7 ft. in diameter, and stands on three iron legs riveted to the sides, but not shown in the figure . The bottom exit pipe E is covered with a See also:shield-shaped false bottom of boiler plate, or (and this is more usual) the whole bottom of the kier is covered with large rounded stones from the See also:river See also:bed, the object in either case being simply to provide space for the See also:accumulation of liquor and to prevent the pipe E being blocked . The cloth is evenly packed up to within about 3 to 4 ft. of the manholes M, when lime water is run in through the liquor pipe until the level of the liquid reaches within about 2 ft. of the top of the goods . The manholes are now closed, and steam is turned on at the injector J by opening the See also:valve v . The effect of this is to suck the liquor through E, and to force it up through pipe P into the top of the kier, where it dashes against the See also:umbrella-shaped shield U and is distributed over the pieces, through which it percolates, until on arriving at E it is again carried to the top of the kier, a continuous circulation being thus effected . As the circulation proceeds, the steam condensing in the liquor rapidly heats the latter to the boil, and as soon as, in the See also:opinion of the fore-See also:man, all air has been expelled, the See also:blow-through tap is closed and the boiling is continued for periods varying from six to twelve hours under 20-60 lb pressure . Steam is now |