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See also:BORAX (See also:sodium pyroborate or sodium biborate)
, Na2B4O7, a substance which appears in See also:commerce under two forms, namely " See also:common " or prismatic See also:borax, Na2B4O7.10H2O, and " jewellers' " or octahedral borax, Na2B4O7.5H2O
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It is to be noted that the See also:term " borax " was used by the alchemists in a very vague manner, and is therefore not to be taken as meaning the substance now specifically known by the name
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Prismatic borax is found widely distributed as a natural product (see below, See also:Mineralogy) in See also:Tibet, and in See also:Canada, See also:Peru and Transylvania, while the See also:bed of Borax See also:Lake, near Clear Lake in See also:California, is occupied by a large See also:mass of crystallized borax, which is See also:fit for use by the assayer without undergoing any preliminary See also:purification
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The See also:supply of borax is, however, mainly derived from the boric See also:acid of See also:Tuscany, which is fused in a reverberatory See also:furnace with See also:half its See also:weight of See also:sodium carbonate, and the mass after cooling is extracted with warm See also:water
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An alternative method is to dissolve sodium carbonate in See also:lead-lined See also:steam-heated pans, and add the boric acid gradually; the See also:solution then being concentrated until the borax crystallizes
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Borax is also prepared from the naturally occurring See also:calcium borate, which is mixed in a finely divided See also:condition with the requisite quantity of soda ash; the mixture is fused, extracted with water and concentrated until the solution commences to crystallize
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From a supersaturated aqueous solution of borax, the pentahydrate, Na2B407.5H20, is deposited when evaporation takes See also:place at somewhat high temperatures
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The same See also:hydrate can be prepared by dissolving borax in water until the solution has a specific gravity of 1.246 and then allowing the solution to cool
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The pentahydrate is deposited between 79° C. and 56° C.; below this temperature the decahydrate or',See also:ordinary borax, Na,B407.10H20, is deposited
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Crystals of ordinary borax swell up to a very See also:great extent on See also:heating, losing their water of See also:crystallization and melting to a clear See also: Its use in soldering depends on the fact that See also:solder only adheres to the See also:surface of an untarnished See also:metal, and consequently a little borax is placed on the surface of the metal and heated by the soldering See also:iron in See also:order to remove any superficial film of See also:oxide . It is also used for See also:glazing pottery, in glass-making and the glazing of See also:linen . Boric acid (q.v.) being only a weak acid, its salts readily undergo hydrolytic See also:dissociation in aqueous solution, and this See also:property can be readily shown with a concentrated aqueous solution of borax, for by adding See also:litmus and then just sufficient acetic acid to turn the litmus red, the addition of a large See also:volume of water to the solution changes the See also:colour back to See also:blue again . The boric acid being scarcelyionized gives only a very small quantity of See also:hydrogen ions, whilst the See also:base (sodium hydroxide) produced by the See also:hydrolysis occasioned by the dilution of the solution, being a " strong base," is highly ionized and gives a comparatively large amount of hydroxyl ions . In the solution, therefore, there is now an excess of hydroxyl ions; consequently it has an alkaline reaction and the litmus turns blue . Mineralogy.—The Tibetan See also:mineral deposits have been known since very See also:early times, and formerly the crude material was exported to See also:Europe, under the name of tincal, for the preparation of pure borax and other See also:boron salts . The most See also:westerly of the Tibetan deposits are in the lake-See also:plain of Pugha on the Rulangchu, a tributary of the See also:Indus, at an See also:elevation of 15,000 ft.: here the impure borax (sohaga) occurs over an See also:area of about 2 sq. m., and is covered by a saline efflorescence; successive crops are obtained by the See also:action of See also:rain and See also:snow and subsequent evaporation . Deposits of purer material (chit 'See also:sale or water borax) occur at the lakes of See also:Rudok, situated to the See also:east of the Pugha See also:district; also still farther to the east at the great lakes Tengri Nor, See also:north of See also:Lhasa, and several other places . More recently, the extensive deposits of borates (chiefly, however, of calcium; see See also:COLEMANITE) in the See also:Mohave See also:desert on the See also:borders of California and See also:Nevada, and in the See also:Atacama desert in See also:South See also:America, have been the See also:chief commercial See also:sources of boron compounds . The boron contained in solution in the See also:salt lakes has very probably been supplied by hot springs and solfataras of volcanic origin, such as those which at the See also:present See also:day See also:charge the See also:waters of the lagoons in Tuscany with boric acid . The deposits formed by evaporation from these lakes and marshes or salines, are mixtures of borates, various alkaline salts (sodium carbonate, sulphate, chloride), See also:gypsum, &c . In the mud of the lakes and in the surrounding marshy See also:soil See also:fine isolated crystals of borax are frequently found . For example, crystals up to 7 in. in length and weighing a See also:pound each have been found in large See also:numbers at Borax Lake in Lake See also:county, and at Borax Lake in See also:San Bernardino county, both in California . Borax crystallizes with ten molecules of water, the See also:composition of the crystals being Na2B4O7+10H2O . The crystals belong to the See also:monoclinic See also:system, and it is a curious fact that in See also:habit and angles they closely resemble See also:pyroxene (a silicate of calcium, See also:magnesium and iron) . There is a perfect cleavage parallel to the orthopinacoid and less perfect cleavages parallel to the faces of the See also:prism . The mineral is transparent to opaque and white, sometimes greyish, bluish or greenish in colour . Hardness 2–21; sp. gr . 1.69-1.72 . The See also:optical characters are interesting, because of the striking crossed See also:dispersion of the optic axes, of which phenomenon borax affords the best example . The optic figure seen in convergent polarized See also:light through a See also:section cut parallel to the See also:plane of symmetry of a borax crystal is symmetrical only with respect to the central point . The plane of the optic axes for red light is inclined at 2° to that for blue light, and the See also:angle between the optic axes themselves is 3° greater for red than for blue light . |
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