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ROBERT WILHELM VON BUNSEN (1811-1899)

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Originally appearing in Volume V04, Page 801 of the 1911 Encyclopedia Britannica.
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ROBERT WILHELM VON See also:BUNSEN (1811-1899)  , See also:German chemist, was See also:born at See also:Gottingen on the 31st of See also:March 1811, his See also:father, See also:Christian See also:Bunsen, being See also:chief librarian and See also:professor of See also:modern See also:philology at the university . He himself entered the university in 1828, and in 1834 became Privat-docent . In 1836 he became teacher of See also:chemistry at the See also:Polytechnic School of See also:Cassel, and in 1839 took up the See also:appointment of professor of chemistry at See also:Marburg, where he remained till 1851 . In 1852, after a brief See also:period in See also:Breslau, he was appointed to the See also:chair of chemistry at See also:Heidelberg, where he spent the See also:rest of his See also:life, in spite of an urgent invitation to migrate to See also:Berlin as successor to E . See also:Mitscherlich . He retired from active See also:work in 1889, and died at Heidelberg on the 16th of See also:August 1899 . The first re-See also:search by which See also:attention was See also:drawn to Bunsen's abilities was concerned with the cacodyl compounds (see See also:ARSENIC), though he had already, in 1834, discovered the virtues of freshly precipitated hydrated ferric See also:oxide as an antidote to arsenical poisoning . It was begun in 1837 at Cassel, and during the six years he spent upon it he not only lost the sight of one See also:eye through an See also:explosion, but nearly killed himself by arsenical poisoning . It represents almost his only excursion into organic chemistry, and apart from its accuracy and completeness it is of See also:historical See also:interest in the development of that See also:branch of the See also:science as being the forerunner of the fruitful investigations on the organo-metallic compounds subsequently carried out by his See also:English See also:pupil, See also:Edward See also:Frankland . Simultaneously with his work on cacodyl, he was studying the See also:composition of the gases given off from blast furnaces . He showed that in German furnaces nearly See also:half the See also:heat yielded by the See also:fuel was being allowed to See also:escape with the See also:waste gases, and when he came to See also:England, and in See also:conjunction with See also:Lyon See also:Playfair investigated the conditions obtaining in English furnaces, he found the waste to amount to over 8o% . These researches marked a See also:stage in the application of scientific principles to the manufacture of See also:iron, and they led also to the elaboration of Bunsen's famous methods of measuring gaseous volumes, &c., which See also:form the subject of the only See also:book he ever published (Gasometrische Method en, 1857) .

In 1841 he invented the See also:

carbon-See also:zinc electric See also:cell which is known by his name, and which conducted him to several important achievements . He first employed it to produce the electric arc, and showed that from 44 cells a See also:light equal to 11713 candles could be obtained with the See also:consumption of one See also:pound of zinc per See also:hour . To measure this light he designed in 1844 another See also:instrument, which in various modifications has come into extensive use—the grease-spot photometer . In 1852 he began to carry out electrolytical decompositions by the aid of the See also:battery . By means of a very ingenious arrangement he obtained See also:magnesium for the first See also:time in the metallic See also:state, and studied its chemical and See also:physical properties, among other things demonstrating the brilliance and high actinic qualities of the See also:flame it gives when burnt in See also:air . From 1855 to 1863 he published with See also:Roscoe a See also:series of investigations on photochemical measurements, which W . Ostwald has called the " classical example for all future researches in physical chemistry." Perhaps the best known of the contrivances which the See also:world owes to him is the " Bunsen burner " which he devised in 1855 when a See also:simple means of burning See also:ordinary See also:coal See also:gas with a hot smokeless flame was required for the new laboratory at Heidelberg . Other appliances invented by him were the See also:ice-calorimeter (187o), the vapour Iv . 26VON -See also:BUNTER 8 o r calorimeter (1887), and the See also:filter See also:pump (1868), which was worked out in the course of a See also:research on the separatidn of the See also:platinum metals . Mention must also be made of another piece of work of a rather different See also:character . Travelling was one of his favourite relaxations, and in 1846 he paid a visit to See also:Iceland . There he investigated the phenomena of the geysers, the composition of the gases coming off from the fumaroles, their See also:action on the rocks with which they .came into contact, &c., and on his observations was founded a noteworthy contribution to See also:geological theory .

But the most far-reaching of his achievements was the elaboration, about 1859, jointly with G . R . See also:

Kirchhoff, of spectrum See also:analysis, which has put a new weapon of extra-ordinary See also:power into the hands both of chemists and astronomers . It led Bunsen himself almost immediately to the See also:isolation of two new elements of the See also:alkali See also:group, See also:caesium and See also:rubidium . Having noticed some unknown lines in the spectra of certain salts he was examining, he set to work to obtain the substance or substances to which these were due . To this end he evaporated large quantities of the See also:Durkheim See also:mineral See also:water, and it says much both for his perseverance and See also:powers of manipulation that he dealt with 40 tons of the water to get about 17 grammes of the mixed chlorides of the two substances, and that with about one-third of that quantity of caesium chloride was able to prepare the most important compounds of the See also:element and determine their characteristics, even making goniometrical measurements of their crystals . Bunsen founded no school of chemistry; that is to say, no See also:body of chemical See also:doctrine is associated with his name . Indeed, he took little or no See also:part in discussions of points of theory, and, although he was conversant with the trend of the chemical thought of his See also:day, he preferred to spend his energies in the collection of experimental data . One fact, he used to say,properly proved is See also:worth all the theories that can be invented . But as a teacher of chemistry he was almost without See also:rival, and his success is sufficiently attested by the scores of pupils who flocked from every part of the globe to study under him, and by the number of those pupils who afterwards made their See also:mark in the chemical world . The See also:secret of this success See also:lay largely in the fact that he never delegated his work to assistants, but was constantly See also:present with his pupils in the laboratory, assisting each with See also:personal direction and See also:advice . He was also one of the first to appreciate the value of See also:practical work to the student, and he instituted a See also:regular practical course at Marburg so far back as 184o .

Though alive to the importance of applied science, he considered truth alone to be the end of scientific research, and the example he set his pupils was one of single-hearted devotion to the See also:

advancement of knowledge . See See also:Sir See also:Henry Roscoe's " Bunsen Memorial Lecture," Trans . Chem . See also:Soc., 1900, which is reprinted (in German) with other obituary notices in an edition of Bunsen's collected See also:works published by Ostwald and Bodenstein in 3 vols. at See also:Leipzig in 1904 .

End of Article: ROBERT WILHELM VON BUNSEN (1811-1899)
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