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CALORESCENCE (from the Lat. calor, heat)

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Originally appearing in Volume V05, Page 60 of the 1911 Encyclopedia Britannica.
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CALORESCENCE (from the See also:Lat. calor, See also:heat)  , a See also:term invented by See also:John See also:Tyndall to describe an See also:optical phenomenon, the essential feature of which is the See also:conversion of rays belonging to the dark infra-red portion of the spectrum into the more refrangible visible rays, i.e. See also:heat rays into rays of See also:light . Such a transformation had not previously been observed, although the converse phenomenon, i.e. the conversion of See also:short waves of light into longer or less refrangible waves, had been shown by See also:Sir G . G . See also:Stokes to occur in fluorescent bodies . Tyndall's experiments, however, were carried out on quite different lines, and have nothing to do with See also:fluorescence (q.v.) . His method was to sift out the See also:long dark waves which are associated with the short visible waves constituting the light of the See also:sun or of the electric arc and to concentrate the former to a See also:focus . If the See also:eye was placed at the focus, no sensation of light was observed, although small piecesto incandescence, thus giving rise to visible rays . The experiment is more easily carried out with the electric light than with sunlight, as the former contains a smaller See also:pro-portion of visible rays . According to Tyndall, 90% of the See also:radiation from the electric arc is non-luminous . The arc being struck in the usual way between two carbons, a See also:concave See also:mirror, placed See also:close behind it, caused a large See also:part of the radiation to be directed through an See also:aperture in the See also:camera and concentrated to a focus outside . In front of the aperture were placed a See also:plate of transparent See also:rock-See also:salt, and a See also:flat See also:cell of thin See also:glass containing a See also:solution of See also:iodine in See also:carbon bisulphide . Both rock-salt and carbon 'bisulphide are extremely transparent to the luminous and also to the infra-red rays The iodine in the solution, however, has the See also:property of absorbing the luminous rays, while transmitting the infra-red rays copiously, so that in sufficient thicknesses the solution appears nearly See also:black .

Owing to the inflammable nature of carbon bisulphide, the plate of rock-salt was found to be hardly a sufficient See also:

protection, and Tyndall surrounded the iodine cell with an See also:annular See also:vessel through which See also:cold See also:water was made to flow . Any small See also:body which was a goqd absorber of dark rays was rapidly heated to redness when placed at the focus . Platinized See also:platinum (platinum See also:foil upon which a thin film of platinum had been deposited electrolytically) and See also:charcoal were rendered incandescent, black See also:paper and matches immediately inflamed, See also:ordinary See also:brown paper pierced and burned, while thin See also:white blotting-paper, owing to its transparency to the invisible rays, was scarcely tinged . A simpler arrangement, also employed by Tyndall, is to cause the rays to be reflected outwards parallel to one another, and to concentrate them by means of a small See also:flask, containing the iodine solution and used as a See also:lens, placed some distance from the camera . The rock-salt and cold water circulation can then be dispensed with . Since the rays used by Tyndall in these experiments are similar to those emitted bya heated body which is not hot enough to be luminous, it might be thought that the radiation, say from a hot See also:kettle, could be concentrated to a focus and employed to render a small body luminous . It would, however, be impossible by such means to raise the receiving body to a higher temperature than the source of radiation . For it is easy to see that if, by means of lenses of rock-salt or mirrors, we focused all or nearly all the rays from a small See also:surface on to another surface of equal See also:area, this would not raise the temperature of the second surface above that of the first; and we could not obtain a greater concentration of rays from a large heated surface, since we could not have all parts of the surface simultaneously in focus . The desired result could be obtained if it were possible, by reflection or otherwise, to cause two different rays to unite without loss and pursue a See also:common path . Such a result must be regarded as impossible of attainment, as it would imply the possibility of heat passing from one body to another at a higher temperature, contrary to the second See also:law of See also:thermodynamics (q.v.) . Tyndall used the dark rays from a luminous source, which are emitted in a highly concentrated See also:form, so that it was possible to obtain a high temperature, which was, however, much See also:lower than that of the source . A full See also:account of Tyndall's experiments will be found in his Heat, a Mode of See also:Motion .

(J . R .

End of Article: CALORESCENCE (from the Lat. calor, heat)
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CHARLES ALEXANDRE DE CALONNE (1734-1802)
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