Online Encyclopedia

CH2 CH

Online Encyclopedia
Originally appearing in Volume V22, Page 33 of the 1911 Encyclopedia Britannica.
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CH2 CH  = CH
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CH2 -- CH =CH CH2•CH2CH ,a -'
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des-methyl cyclo-octadiene granatanine Cyclo-octadiene, CSH12, as above prepared, is a strong-smelling oil which decolorizes potassium permanganate solution instantaneously . It readily polymerizes to a di-cyclo-octadiene and polymer (C8H12~„ (R . Willstatter, Ber., 1905, 38, pp . 1975, 1984; G . Ciamician and P . Silber, Ber., 1893, 26, p . 2750; A . Piccinini, Gaza., 1902, 32, I p . 260). i3-cyclo-octadiene has been prepared from methyl granatinine iodmethylate . Cyclo-octane, C3H18 is obtained by the reduction of the above unsaturated
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hydrocarbon by the Sabatier and Senderens's method . It is a liquid which boils at 146.3-148° C. and possesses a strong camphor odour . On oxidation it yields suberic acid (R .

Willstatter, Ber., 1907, 40, pp . 957) . O . Doebner (

Bee., 1902, 35, pp . 2129, 2538; 1903, 36, p . 4318) obtained compounds, which in all probability are cyclo-octadienes, by the distillation of p-vinylacrylic acid, sorbic .acid, and cinnamenyl acrylic acid with anhydrous baryta . Cyclo-nonane
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Group . According to N . Zelinsky (Bee., 1907, 40, p . 780) cyclononanone, C9H16O, a liquid boiling at 95-97° C., is formed on distilling sebacic acid with lime, and from this, by reduction to the corresponding secondary
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alcohol, conversion of the latter into the iodide, and subsequent reduction of this with
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zinc, cyclo-nonane, C,H18, a liquid boiling at 170-172° C. is obtained .

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