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CH2 CH = CH CH2 -- CH =CH CH2•CH2CH ,a -'See also: des-methyl cyclo-octadiene granatanine
Cyclo-octadiene, CSH12, as above prepared, is a strong-smelling oil which decolorizes potassium permanganate solution instantaneously
.
It readily polymerizes to a di-cyclo-octadiene and polymer (C8H12~„ (R
.
Willstatter, Ber., 1905, 38, pp
.
1975, 1984; G
.
Ciamician and P
.
Silber, Ber., 1893, 26, p
.
2750; A
.
Piccinini, Gaza., 1902, 32, I p
.
260). i3-cyclo-octadiene has been prepared from methyl granatinine iodmethylate
.
Cyclo-octane, C3H18 is obtained by the reduction of the above unsaturated See also: hydrocarbon by the See also: Sabatier and Senderens's method
.
It is a liquid which boils at 146.3-148° C. and possesses a strong camphor odour
.
On oxidation it yields suberic acid (R
.
Willstatter, Ber., 1907, 40, pp . 957) . O . Doebner ( Bee., 1902, 35, pp . 2129, 2538; 1903, 36, p . 4318) obtained compounds, which in all probability are cyclo-octadienes, by theSee also: distillation of p-vinylacrylic acid, sorbic .acid, and cinnamenyl acrylic acid with anhydrous baryta
.
Cyclo-nonane See also: Group
.
According to N
.
Zelinsky (Bee., 1907, 40, p
.
780) cyclononanone, C9H16O, a liquid boiling at 95-97° C., is formed on distilling sebacic acid with lime, and from this, by reduction to the corresponding secondary See also: alcohol, conversion of the latter into the iodide, and subsequent reduction of this with See also: zinc, cyclo-nonane, C,H18, a liquid boiling at 170-172° C. is obtained
.
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