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CLAY (from O. Eng. claeg, a word comm...

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Originally appearing in Volume V06, Page 474 of the 1911 Encyclopedia Britannica.
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CLAY (from O. Eng. claeg, a word See also:common in various forms to See also:Teutonic See also:languages, cf. Ger. Klei)  , commonly defined as a See also:fine-grained, almost impalpable substance, very soft, more or less coherent when dry, plastic and retentive of See also:water when wet; it has an " earthy " odour when breathed upon or moistened, and consists essentially of hydrous See also:aluminium silicate with various impurities . Of See also:clay are formed a See also:great number of rocks, which collectively are known as " clay-rocks " or " pelitic rocks "(from Gr. rrrlXos, clay), e.g. mudstone, shale, See also:slate: these exhibit in greater or less perfection the properties above described according to their freedom from impurities . In nature, See also:clays are rarely See also:free from See also:foreign ingredients, many of which can be detected with the unaided See also:eye, while others may be observed by means of the See also:microscope . The commonest impurities are: (1) organic See also:matter, humus, &c . (exemplified by clay-soils with an admixture of See also:peat, oil shales, carbonaceous shales); (2) fossils (such as See also:plants in the shales of the See also:Lias and See also:Coal See also:Measures, shells in clays of all See also:geological periods and in fresh water marls); (3) carbonate of See also:lime (rarely altogether absent, but abundant in marls, See also:cement-stones and argillaceous limestones); (4) sulphide of See also:iron, as pyrite or See also:marcasite (when finely diffused, giving the clay a dark See also:grey-See also:blue See also:colour, which weathers to See also:brown--e.g . See also:London Clay; also as nodules and concretions, e.g . See also:Gault); (5) oxides of iron (staining the clay See also:bright red when ferric See also:oxide, red ochre; yellow when hydrous, e.g. yellow ochre); (6) See also:sand or detrital See also:silica (forming loams, arenaceous clays, argillaceous sandstones, &c.) . Less frequently See also:present are the following:—See also:rock See also:salt (Triassic clays, and marls of See also:Cheshire, &c.); See also:gypsum (London Clay, Triassic clays); See also:dolomite, phosphate of lime, See also:vivianite (phosphate of iron), oxides of See also:manganese, See also:copper ores (e.g . Kupferschiefer), See also:wavellite and See also:amber . As the impurities increase in amount the clay rocks pass gradually into argillaceous sands and sandstones, argillaceous limestones and See also:dolomites, shaly coals and clay ironstones . Natural clays, even when most ,pure, show a considerable range of See also:composition, and hence cannot be regarded as consisting of a single See also:mineral; clay is a rock, and has that variability which characterizes all rocks . Of the essential properties of clay some are merely See also:physical, and depend on the See also:minute See also:size of the particles .

If any rock be taken (even a piece of pure See also:

quartz) and crushed to a very fine See also:powder, it will show some of the peculiarities of clays; for example, it will be plastic, retentive of moisture, impermeable to water, and will shrink to some extent if the moist See also:mass be kneaded, and then allowed to dry . It happens, however, that many rocks are not disintegrated to this extreme degree by natural processes, and weathering invariably accompanies disintegration . Quartz, for example, has little or no cleavage, and is not attacked by the See also:atmosphere . It breaks up into fragments, which become rounded by See also:attrition, but after they reach a certain minuteness are See also:borne along by currents of water or See also:air in a See also:state of suspension, and are not further reduced in size . Hence sands are more coarse grained than clays . A great number of rock-forming minerals, however, possess a See also:good cleavage, so that when bruised they split into thin fragments; many of these minerals decompose somewhat readily, yielding secondary minerals, which are comparatively soft and have a scaly See also:character, with eminently perfect cleavages, which facilitate splitting into exceedingly thin plates . The See also:principal substances of this description are See also:kaolin, See also:muscovite and See also:chlorite . Kaolin and muscovite are formed principally after See also:felspar (and the felspars are the commonest minerals of all crystalline rocks); also from See also:nepheline, See also:leucite, See also:scapolite and a variety of other rock-forming minerals . Chlorite arises from See also:biotite, See also:augite and See also:hornblende . See also:Serpentine, which may be fibrous or scaly, is a secondary product of See also:olivine and certain pyroxenes . Clays consist essentially of the above ingredients (although serpentine is not known to take See also:part in them to any extent, it is closely allied to chlorite) . At the same See also:time other substances are produced as decomposition goes on .

They are principally finely divided quartz, See also:

epidote, See also:zoisite, See also:rutile, See also:limonite, See also:calcite, See also:pyrites, and very small particles of these are rarely absent from natural clays . These fine-grained materials are at first mixed with broken and more or less weathered rock fragments and coarser mineral particles in the See also:soil and subsoil, but by the See also:action of See also:wind and See also:rain they are swept away and deposited in distant situations . " See also:Loess " is a fine calcareous clay, which has been wind-borne, and subsequently laid down on the margins of dry See also:steppes and deserts . Most clays are water-borne, having been carried from the See also:surface of the See also:land by rain and transported by the See also:brooks and See also:rivers into lakes or the See also:sea . In this state the fine particles are known as " mud." They are deposited where the currents are checked and the water becomes very still . If temporarily laid down in other situations they are ultimately lifted again and removed . A little clay, stirred up with water in a See also:glass See also:vessel, takes See also:hours to See also:settle, and even after two or three days some remains in suspension; in fact, it has been suggested that in such cases the clay forms a sort of "colloidal See also:solution" in the water . Traces of dissolved salts, such as See also:common salt, gypsum or See also:alum, greatly accelerate deposition . For these reasons the principal gathering places of fine pure clays are deep, still lakes, and the sea bottom at considerable distances from the See also:shore . The coarser materials settle nearer the land, and the shallower portions of the sea See also:floor are strewn with See also:gravel and sand, except in occasional depressions and near the mouths of rivers where mud may gather . Farther out the great mud deposits begin, extending from 50 to 200 M. from the land, according to the amount of sediment brought in, and the See also:rate at which the water deepens . A See also:girdle of mud accumulations encircles all the continents .

These sediments are fine and tenacious; their principal components, in addition to clay, being small grains of quartz, See also:

zircon, See also:tourmaline, hornblende, felspar and iron compounds . Their typical colour is blackish-blue, owing to the abundance of sulphuretted See also:hydrogen; when fresh they have a sulphurous odour, when weathered they are brown, as their iron is present as hydrous oxides (limonite, &c.) . These deposits are tenanted by numerous forms of marine See also:life, and the See also:sulphur they contain is derived from decomposing organic matter . Oecasionally water-logged plant debris is mingled with the mud . In a few places a red colour prevails, the iron being mostly oxidized; elsewhere the muds are See also:green owing to abundant See also:glauconite . Traced landwards the muds become more sandy, while on their See also:outer margins they grade into the abysmal deposits, such as the See also:globigerina See also:ooze (see OCEAN AND OCEANOGRAPHY) . Near volcanoes they contain many volcanic minerals, and around See also:coral islands they are often in large part calcareous . Microscopic sections of some of the more coherent clays and shales may be prepared by saturating them with See also:Canada See also:balsam by See also:long boiling, and slicing the resultant mass in the same manner as one of the harder rocks . They show that clay rocks contain abundant very small grains of quartz (about o•or to 0.05 mm. in See also:diameter), with often felspar, tourmaline, zircon, epidote, rutile and more or less calcite . These may See also:form more than one-third of an See also:ordinary shale; the greater part, however, consists of still smaller scales of other minerals (o•or mm. in diameter and less than this) . Some of these are recognizable as See also:pale yellowish and See also:white See also:mica; others seem to be chlorite, the See also:remainder is perhaps kaolin, but, owing to the minute size of the flakes, they yield very indistinct reactions to polarized See also:light . They are also often stained with iron oxide and organic substances, and in consequence their true nature is almost impossible to determine .

It is certain, however, that the finer-grained rocks are richest in alumina, and in combined water; hence the inference is clear that kaolin or some other hydrous aluminium silicate is the dominating constituent . These results are confirmed by the See also:

mechanical See also:analysis of clays . This See also:process consists in finely pulverizing the soil or rock, and levigating it in vessels of water . A See also:series of powders is obtained progressively finer according to the time required to settle to the bottom of the vessel . The clay is held to include those particles which have less than 0•005 mm. diameter, and contains a higher percentage of alumina than any of the other ingredients . As might be inferred from the See also:differences they exhibit in other respects, clay rocks vary greatly in their chemical composition . Some of them contain much iron (yellow, blue and red clays); others contain abundant See also:calcium carbonate (calcareous clays and marls) . Pure clays, however, may be found almost quite free from these substances . Their silica ranges from about 6o to 45%, varying in accordance with the amount of quartz and See also:alkali-felspar present . It is almost always more than would be the See also:case if the rock consisted of kaolin mixed with muscovite . Alumina is high in the finer clays (18 to 3o%), and they are the most aluminous of all sediments, except See also:bauxite . See also:Magnesia is never absent, though its amount may be less than r %; it is usually contained in minerals of the chlorite See also:group, but partly also in dolomite .

Phoenix-squares

The alkalis are very interesting; often they form 5 or to% of the whole rock; they indicate abundance of white micas or of undecomposed particles of felspar . Some clays, however, such as fireclays, contain very little potash or soda, while they are See also:

rich in alumina; and it is a See also:fair inference that hydrated aluminous silicates, such as kaolin, are well represented in these rocks . There are, in fact, a few clays which contain about 45 % of alumina, that is to say, more than in pure kaolin . It is probable that these are related to bauxite and certain kinds of See also:laterite . A few of the most important clay rocks, such as See also:china-clay, See also:brick-clay, red-clay and shale, may he briefly described here . China-clay is white, friable and earthy . It occurs in regions of See also:granite, See also:porphyry and See also:syenite, and usually occupies See also:funnel-shaped cavities of no great superficial See also:area, but of considerable See also:depth . It consists of very fine scaly kaolin, larger, shining plates of white mica, grains of quartz and particles of semi-decomposed felspar, tourmaline, zircon and other minerals, which originally formed part of the granite . These clays are produced by the decomposition of the granite by See also:acid vapours, which are discharged after the igneous rock has solidified (" See also:fumarole or pneumatolytic action") . See also:Fluorine and its compounds are often supposed to have been among the agencies which produce this See also:change, but more probably carbonic acid played the principal role . The felspar decomposes into kaolin and quartz; its alkalis are for the most part set free and removed in solution, but are partly retained in the white mica which is constantly found in crude china-clays . Semi-decomposed varieties of the granite are known as china-See also:stone .

The kaolin may be washed away from its See also:

original site, and deposited in hollows or lakes to form beds of white clay, such as See also:pipe-clay; in this case it is always more or less impure . Yellow and pinkish varieties of china-clay and pipe-clay contain a small quantity of oxide of iron . The best known localities for china-clay are See also:Cornwall, See also:Limoges (See also:France), See also:Saxony, Bohemia and China; it. is found also in See also:Pennsylvania, N . Carolina and elsewhere in the See also:United States . See also:Fire-clays include all those varieties of clay which are very refractory to See also:heat . They must contain little alkalis, lime, magnesia and iron, but some of them are comparatively rich in silica . Many of the clays which pass under this designation belong to the Carboniferous See also:period, and are found underlying seams of coal . Either by rapid growth of vegetation, or by subsequent percolation of organic solutions, most of the alkalis and the lime have been carried away . Any argillaceous material, which can be used for the manufacture of bricks, may be called a brick-clay . In See also:England, Kimmeridge Clay, Lias clays, London Clay and pulverized shale and slate are all employed for this purpose . Each variety needs See also:special treatment according to its properties . The true brick-clays, however, are superficial deposits of See also:Pleistocene or See also:Quaternary See also:age, and occur in hollows, filled-up lakes and deserted stream channels .

Many of them are derived from the glacial See also:

boulder-clays, or from the washing away of the finer materials contained in older clay formations . They are always very impure . The red-clay is an abysmal formation, occurring in the sea bottom in the deepest part of the oceans . It is estimated to See also:cover over fifty millions of square See also:miles, and is probably the most extensive See also:deposit which is in course of See also:accumulation at the present See also:day . In addition to the reddish or brownish argillaceous See also:matrix it contains fresh or decomposed crystals of volcanic minerals, such as felspar, augite, hornblende, olivine and pumiceous or palagonitic rocks . These must either have been ejected by submarine volcanoes or drifted by the wind from active vents, as the fine ash discharged by See also:Krakatoa was wafted over the whole globe . Larger rounded lumps of See also:pumice, found in the clay, have probably floated to their present situations, and sank when decomposed, all their cavities becoming filled with sea water . Crystals of See also:zeolites (See also:phillipsite) form in the red-clay as radiate, nodular See also:groups . Lumps of manganese oxide, with a See also:black, shining outer surface, are also characteristic of this deposit, and frequently encrust pieces of pumice or See also:animal remains . The only fossils of the clay are See also:radiolaria, sharks' See also:teeth and the See also:ear-bones of whales, precisely those parts of the See also:skeleton of marine creatures which are hardest and can longest survive exposure to sea-water . Their See also:comparative abundance shows how slowly the clay gathers . Small rounded spherules of iron, believed by some to be meteoric dust, have also been obtained in some See also:numbers .

Among the rocks of the continents nothing exactly the same as this remarkable deposit is known to occur, though fine dark clays, with manganese nodules, are found in many localities, accompanied by other rocks which indicate deep-water conditions of deposit . Another type of red-clay is found in caves, and is known as See also:

cave-See also:earth or red-earth (terra rossa) . It is fine, tenacious and bright red, and represents the insoluble and thoroughly weathered impurities which are See also:left behind when the calcareous matter is removed in solution by carbonated See also:waters . Similar residual clays sometimes occur on the surface of areas of See also:limestone in hollows and fissures formed by weathering . Boulder-clay is a coarse unstratified deposit of fine clay, with more or less sand, and boulders of various sizes, the latter usually marked with glacial striations . Some clay rocks which have been laid down by water are very See also:uniform through their whole thickness, and are called mud-stones . Others split readily into fine leaflets or laminae parallel to their bedding, and this structure is accentuated by the presence of films of other materials, such as sand or See also:vegetable debris . Laminated clays of this sort are generally known as shales; they occur in many formations but are very common in the Carboniferous . Some of them contain much organic debris, and when distilled yield See also:paraffin oil, See also:wax, compounds of See also:ammonia, &c . In these oil-shales there are clear, globular, yellow bodies which seem to be resinous . It has been suggested that the admixture of large quantities of decomposed fresh-water See also:algae among the original mud is the origin of the paraffins . In New See also:South See also:Wales, See also:Scotland and several parts of See also:America such oil-shales are worked on a commercial See also:scale .

Many shales contain great numbers of ovoid or rounded septarian nodules of clay ironstone . Others are rich in pyrites, which, on oxidation, produces sulphuric acid; this attacks the aluminous silicates of the clay and forms aluminium sulphate (alum shales) . The lias shales of See also:

Whitby contain blocks of semi-mineralized See also:wood, or See also:jet, which is black with a resinous lustre, and a fibrous structure . The laminated structure of shales, though partly due to successive very thin sheets of deposit, is certainly de-pendent also on the See also:vertical pressure exerted by masses of super-See also:incumbent rock; it indicates a transition to the fissile character of clay slates . (J . S .

End of Article: CLAY (from O. Eng. claeg, a word common in various forms to Teutonic languages, cf. Ger. Klei)
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