Online Encyclopedia

CRYSTALLITE

Online Encyclopedia
Originally appearing in Volume V07, Page 569 of the 1911 Encyclopedia Britannica.
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CRYSTALLITE  . In

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media which, on account of their viscosity, offer considerable resistance to those molecular movements which are necessary for the
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building and growth of crystals, rudimentary or imperfect forms of crystallization very frequently occur . Such media are the volcanic rocks when they are rapidly cooled, producing various kinds of pitchstone,
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obsidian, &c . When examined under the microscope these rocks consist largely of a perfectly amorphous or glassy
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base, through which are scattered
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great numbers of very minute crystals (microliths), and other bodies, termed crystallites, which seem to be stages in the formation of crystals . Crystallites may also be produced by allowing a solution of
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sulphur in carbon disulphide mixed with
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Canada balsam to evaporate slowly, and their development may be watched on a microscopic slide . Small globules appear (globulites), spherical and non-crystalline (so far as can be ascertained) . They may coalesce or may arrange themselves into rows like strings of beads—margarites—(Gr. papyapIrgs, a pearl) or into groups with a somewhat radiate arrangement—globospherites . Occasionally they take elongated shapes—longulites and baculites (
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Lat. baculus, a staff) . The largest may become crystalline, changing suddenly into polyhedral bodies with evident double refraction and the
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optical properties belonging to crystals . Others become long and thread-like—trichites (Gr . Opii , rptx6r, hair)—and these are often curved, and a
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group of them may be implanted on the
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surface of a small crystal . All these forms are found in vitreous igneous rocks .

H . P . J . Vogelsang, who was the first to

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direct much attention to them, believes that the globulites are pre. liminary stages in the formation of crystals . Microliths, as distinguished from crystallites, have crystalline properties, and evidently belong to definite minerals or salts . When sufficiently large they are often recognizable, but usually they are so small, so opaque, or so densely crowded together that this is impossible . In igneous rocks they are usually felspar,
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augite,
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enstatite, and iron oxides, and are found in abundance only where there is much uncrystallized glassy base; in contact-altered sediments, slags, &c., microlithic forms of garnet,
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spinel,
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sillimanite, cordierite, various lime silicates, and many other substances have been observed . Their form varies greatly, e.g. thin fibres (sillimanite, augite), short prisms or rods (felspar, enstatite, cordierite), or equidimensional grains (augite, spinet,
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magnetite) . Occasionally they are perfectly shaped though minute crystals; more frequently they appear rounded (magnetite, &c.), or have brush-like terminations (augite, felspar, &c.) . The larger microliths may contain enclosures of glass, and it is very
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common to find that the prisms have hollow, funnel-shaped ends, which are filled with vitreous material . These microliths, under the influence of crystalline forces, may rank themselves .side by side to make up
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skeleton crystals and networks, or feathery and arborescent forms, which obey more or less closely the
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laws of crystallization of the substance to which they belong . They bear a very close resemblance to the arborescent frost flowers seen on window panes in winter, and to the stellate snow crystals .

In magnetite the growths follow three axes at right angles to one another; in augite this is nearly, though not exactly, the

case; in
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hornblende an angle of 57° may frequently be observed, corresponding to the prism angle of the fully-
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developed crystal . The interstices of the network may be partly filled up by a later growth . In other cases the crystalline arrangement of the microliths is less perfect, and branching, arborescent or feathery groupings are produced (e.g. felspar, augite, hornblende) . Spherulites may be regarded as radiate aggregates of such microliths (mostly felspar mixed with
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quartz or
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tridymite) . If larger porphyritic crystals occur in the rock, the microliths of the vitreous base frequently grow outwards from their faces; in some cases a definite parallelism exists between the two, but more frequently the early crystal has served merely as a centre, or nucleus, from which the microliths and spherulites have spread in all directions . (J . S .

End of Article: CRYSTALLITE
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