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See also:CYANOGEN (Gr. ebavos, See also:blue 'yevvav, to produce), C2N2 , in See also:chemistry, a See also:gas composed of See also:carbon and See also:nitrogen . The name was suggested by Prussian See also:blue, the earliest known See also:compound of See also:cyanogen . It was first isolated in 1815 by J . See also:Gay-Lussac, who obtained it by See also:heating See also:mercury or See also:silver See also:cyanide; this See also:discovery is of considerable See also:historical importance, since it recorded ' the See also:isolation of a " compound See also:radical." It may also be prepared by heating ammonium oxalate; by passing See also:induction See also:sparks between carbon points inan See also:atmosphere of nitrogen (see H. von Wartenburg, Abs . J.C.S., 1907, i. p . 299), or by the addition of a concentrated See also:solution of See also:potassium cyanide to one of See also:copper sulphate, the mixed solutions being then heated . It also occurs in blast-See also:furnace gases . When cyanogen is prepared by heating mercuric cyanide, a See also:residue known as See also:para-cyanogen, (CN)=, is See also:left; this is to be regarded as a polymer of cyanogen . It is a brownish amorphous solid, which is insoluble in See also:water . Cyanogen is a colourless gas, possessing a See also:peculiar characteristic See also:smell, and is very poisonous . It See also:burns with a See also:purple See also:flame, forming carbon dioxide and nitrogen; and may be condensed (by cooling to -25° C.) to a colourless liquid, and further to a solid, which melts at -34.4 C . (M .
See also:Faraday, See also:Ann., 1845, 56, p, 158)
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It dissolves readily in water and the aqueous solution decomposes on See also:standing; a dark-See also: |
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