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CYANOGEN (Gr. ebavos, blue 'yevvav, t...

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Originally appearing in Volume V07, Page 680 of the 1911 Encyclopedia Britannica.
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CYANOGEN (Gr. ebavos, See also:blue 'yevvav, to produce), C2N2  , in See also:chemistry, a See also:gas composed of See also:carbon and See also:nitrogen . The name was suggested by Prussian See also:blue, the earliest known See also:compound of See also:cyanogen . It was first isolated in 1815 by J . See also:Gay-Lussac, who obtained it by See also:heating See also:mercury or See also:silver See also:cyanide; this See also:discovery is of considerable See also:historical importance, since it recorded ' the See also:isolation of a " compound See also:radical." It may also be prepared by heating ammonium oxalate; by passing See also:induction See also:sparks between carbon points inan See also:atmosphere of nitrogen (see H. von Wartenburg, Abs . J.C.S., 1907, i. p . 299), or by the addition of a concentrated See also:solution of See also:potassium cyanide to one of See also:copper sulphate, the mixed solutions being then heated . It also occurs in blast-See also:furnace gases . When cyanogen is prepared by heating mercuric cyanide, a See also:residue known as See also:para-cyanogen, (CN)=, is See also:left; this is to be regarded as a polymer of cyanogen . It is a brownish amorphous solid, which is insoluble in See also:water . Cyanogen is a colourless gas, possessing a See also:peculiar characteristic See also:smell, and is very poisonous . It See also:burns with a See also:purple See also:flame, forming carbon dioxide and nitrogen; and may be condensed (by cooling to -25° C.) to a colourless liquid, and further to a solid, which melts at -34.4 C . (M .

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Faraday, See also:Ann., 1845, 56, p, 158) . It dissolves readily in water and the aqueous solution decomposes on See also:standing; a dark-See also:brown flocculent precipitate of azulmic See also:acid, C4H5Ns0, separating whilst ammonium oxalate, See also:urea and hydrocyanic acid are found in the solution . In many respects it resembles See also:chlorine in its chemical behaviour, a circumstance noted by Gay-Lussac; it combines directly with See also:hydrogen (at sod' to 550 C.) to See also:form hydrocyanic acid, and with chlorine, See also:bromine, See also:iodine and See also:sulphur, to form cyanogen chloride, &c.; it also combines directly with See also:zinc, See also:cadmium and See also:iron to form cyanides of these metals . It combines with sulphuretted hydrogen, in. the presence of water, to form the compound C2N2•H2S, and in the presence of See also:alcohol, to form the compound C2N2.2H2S . Concentrated hydrochloric acid converts it into oxamide . Potash solution converts it into a mixture of potassium cyanide and cyanate . When heated with hydriodic acid (specific gravity 1.96) it forms amino-acetic acid, and with See also:tin and hydrochloric acid it yields See also:ethylene diamine .

End of Article: CYANOGEN (Gr. ebavos, blue 'yevvav, to produce), C2N2
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