Online Encyclopedia

DIALLAGE

Online Encyclopedia
Originally appearing in Volume V08, Page 156 of the 1911 Encyclopedia Britannica.
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DIALLAGE  , an important

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mineral of the
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pyroxene
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group, distinguished by its thin foliated structure and bronzy lustre . The chemical composition is the same as
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diopside, Ca Mg (SiO3)2, but it sometimes contains the molecules (Mg, Fe") (Al, Fe"')2 SiO6 and Na Fe"' (SiO3)2 in addition, when it approaches to
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augite in composition . Diallage is in fact an altered form of these varieties of pyroxene; the particular kind of alteration which they have undergone being known as "schillerization." This, as described by Prof . J . W . Judd, consists in the development of a
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fine lamellar structure or parting due to secondary twinning and the separation of secondary products along these and other planes. of chemical weakness (" solution planes ") in the crystal . The secondary products-consist of mixtures of various hydrated oxides—opal,
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gothite, limonite, &c.—and appear as microscopic inclusions filling or partly filling cavities, which have definite outlines with respect to the enclosing crystal and are known as negative crystals . It is to the reflection and interference of
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light from these minute inclusions that the
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peculiar bronzy sheen or " schiller " of the mineral is due . The most pronounced lamination is that parallel to the orthopinacoid; another, less distinct, is parallel to the basal
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plane, and a third parallel to the plane of symmetry; these planes of secondary parting are in addition to the ordinary prismatic cleavage of allpyroxenes . Frequently the material is interlaminated with a rhombic pyroxene (
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bronzite) or with an
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amphibole (smaragdite or uralite), the latter being an alteration product of the diallage . Diallage is usually greyish-green or dark green, sometimes brown, in colour, and has a pearly to metallic lustre or schiller on the laminated surfaces . The hardness is 4, and the specific gravity 3.2 to 3'35 .

It does not occur in distinct crystals with definite outlines, but only as lamellar masses in deep-seated igneous rocks, principally

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gabbro, of which it is an essential constituent . It occurs also in some peridotites and serpentines, and rarely in volcanic rocks (
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basalt) and crystalline schists . Masses of considerable
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size are found in the coarse-grained gabbros of the Island of
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Skye, Le Prese near Bornio in Valtellina,
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Lombardy,
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Prato near Florence, and many other localities . The name diallage, from BcaXXayi7, " difference," in allusion to the dissimilar cleavages and planes of fracture, as originally applied by R . J . Haiiy in 18or, included other minerals (the orthorhombic pyroxenes
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hypersthene, bronzite and bastite, and the smaragdite variety of
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hornblende) which exhibit the same peculiarities of schiller structure; it is now limited. to the
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monoclinic pyroxenes with this structure . Like the minerals of similar appearance just mentioned, it is sometimes cut and polished for ornamental purposes . (L . J .

End of Article: DIALLAGE
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