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DIALYSIS (from the Gr. &0., through, Anew, to loosen) , in chemistry, aSee also: process invented by See also: Thomas
See also: Graham for separating colloidal and crystalline substances
.
He found that solutions could be divided into two classes according to their See also: action upon a porous diaphragm such as See also: parchment
.
If a solution, say of See also: salt, be placed in a drum provided with a parchment bottom, termed a " dialyser," and the drum and its contents placed in a larger vessel of See also: water, the salt will pass through the membrane
.
If the salt solution be replaced by one of glue, See also: gelatin or gum, it will be found that the membrane is impermeable to these solutes
.
To the first class Graham gave the name " crystalloids," and to the second " colloids." This method is particularly effective in the preparation of silicic acid
.
By adding hydrochloric acid to a dilute solution of an alkaline silicate, no precipitate will fall and the solution will contain hydrochloric acid, an alkaline chloride, and silicic acid
.
If the solution be transferred to a dialyser, the hydrochloric acid and alkaline chloride will pass through the parchment, while the silicic acid will be retained
.
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