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See also: element isolated by C
.
G
.
Mosander from cerite (1839-1841)
.
In 1879, however, Lecoq de Boisbaudran showed that Mosander's "See also: didymium " contained samarium; while the residual " didymium," after removal of samarium, was split by Auer v
.
Welsbach (Monats. f
.
Chem'ie, 1885, 6, 477) into two components (known respectively as neodymium and praseodymium) by repeated fractional See also: crystallization of the See also: double nitrate of ammonium and didymium in nitric acid
.
Neodymium (Nd) forms the chief portion of the old " didymium
.
" Its salts are reddish See also: violet in colour, and give a characteristic absorption spectrum
.
It forms oxides of composition Nd203 and Nd205, the latter being obtained by ignition of the nitrate (B
.
Brauner)
.
The atomic See also: weight of neodymium is 143.6 (B
.
Brauner, Proc
.
Chem . See also: Soc., 1897-1898, p
.
70)
.
Praseodymium (Pr) forms oxides of composition Pr203, Pr206,xH2O (B
.
Brauner), and Pr407
.
The peroxide, Pr407, forms a dark See also: brown powder, and is obtained by ignition of the oxalate or nitrate
.
The sesquioxide, Pr203, is obtained as a greenish
See also: white mass by the reduction of the peroxide
.
The salts of praseodymium are
See also: green in colour, and give a characteristic spark spectrum
.
The atomic weight of praseodymium is 140'5
.
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