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DIOPSIDE , an important member of the See also: pyroxene See also: group of See also: rock-forming minerals
.
It is a calcium-magnesium metasilicate, CaMg (SiO3)2, and crystallizes in the See also: monoclinic See also: system
.
Usually some iron is See also: present replacing magnesium, and when this pre-dominates there is a passage to hedenbergite, CaFe(SiO3)2, a closely allied variety of monoclinic pyroxene
.
These are distinguished from See also: augite by containing little or no aluminium
.
Diopside is colourless, See also: white, pale
See also: green to dark green or nearly black in colour, the See also: depth of the colour depending on the amount of iron present
.
The specific gravity and See also: optical constants also vary with the chemical composition; the sp. gr. of diopside is 3.2, increasing to 3.6 in hedenbergite, and the angle of optical extinction in the See also: plane of symmetry varies between 38° and 47° in the two extremes of the series, Crystals are usually prismatic in habit with a rectangular See also: cross-section as shown in the figure: the angle between the prism faces m, parallel to which there are perfect cleavages, is 92° 50'
.
Several varieties, depending on differences in structure and
chemical composition, have been distinguished, viz. coccolite (from KoKKOS, a grain), a granular variety; salite or sahlite, from Sala in Sweden; malacolite; See also: diallage; violane, a lamellar variety of a dark See also: violet-blue colour; chrome-diopside, a bright green variety containing a small amount of chromium; and many others
.
Belonging to the same series with diopside and hedenbergite is a manganese pyroxene, known as schefierite, which has the composition (Ca, Mg) (Fe, Mn) (SiO3)2
.
Diopside is the characteristic pyroxene of metamorphic rocks, occurring especially in crystalline limestones, and often in association with garnet and See also: epidote
.
It is also an essential constituent of some
pyroxene-granites, diorites and a few other igneous rocks, but the characteristic pyroxene of this class of rocks is augite
.
See also: Fine transparent crystals of a pale green colour occur, with crystals of yellowish-red garnet (hessonite) and See also: chlorite, in See also: veins traversing See also: serpentine in the See also: Ala valley near See also: Turin in Piedmont: a crystal of this variety (" alalite ") is represented in the accompanying figure
.
These, as well as the long, transparent, bottle-green crystals from the Zillerthal in the Tyrol, have occasionally been cut as See also: gem-stones
.
See also: Good crystals have been found also at Achmatovsk near See also: Zlatoust in the Urals, Traversella near See also: Ivrea in Piedmont (" traversellite "), Nordmark in Sweden, See also: Monroe in New See also: York, See also: Burgess in See also: Lanark county, See also: Ontario, and several other places: at Nordmark the large, rectangular black crystals occur with See also: magnetite in the iron mines
.
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