Online Encyclopedia

DIOPSIDE

Online Encyclopedia
Originally appearing in Volume V08, Page 289 of the 1911 Encyclopedia Britannica.
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DIOPSIDE  , an important member of the

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pyroxene
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group of rock-forming minerals . It is a calcium-magnesium metasilicate, CaMg (SiO3)2, and crystallizes in the
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monoclinic
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system . Usually some iron is
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present replacing magnesium, and when this pre-dominates there is a passage to hedenbergite, CaFe(SiO3)2, a closely allied variety of monoclinic pyroxene . These are distinguished from
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augite by containing little or no aluminium . Diopside is colourless, white, pale green to dark green or nearly black in colour, the
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depth of the colour depending on the amount of iron present . The specific gravity and
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optical constants also vary with the chemical composition; the sp. gr. of diopside is 3.2, increasing to 3.6 in hedenbergite, and the angle of optical extinction in the
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plane of symmetry varies between 38° and 47° in the two extremes of the series, Crystals are usually prismatic in habit with a rectangular
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cross-section as shown in the figure: the angle between the prism faces m, parallel to which there are perfect cleavages, is 92° 50' . Several varieties, depending on differences in structure and chemical composition, have been distinguished, viz. coccolite (from KoKKOS, a grain), a granular variety; salite or sahlite, from Sala in Sweden; malacolite;
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diallage; violane, a lamellar variety of a dark
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violet-blue colour; chrome-diopside, a bright green variety containing a small amount of chromium; and many others . Belonging to the same series with diopside and hedenbergite is a manganese pyroxene, known as schefierite, which has the composition (Ca, Mg) (Fe, Mn) (SiO3)2 . Diopside is the characteristic pyroxene of metamorphic rocks, occurring especially in crystalline limestones, and often in association with garnet and
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epidote . It is also an essential constituent of some pyroxene-granites, diorites and a few other igneous rocks, but the characteristic pyroxene of this class of rocks is augite .
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Fine transparent crystals of a pale green colour occur, with crystals of yellowish-red garnet (hessonite) and
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chlorite, in
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veins traversing
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serpentine in the
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Ala valley near
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Turin in Piedmont: a crystal of this variety (" alalite ") is represented in the accompanying figure . These, as well as the long, transparent, bottle-green crystals from the Zillerthal in the Tyrol, have occasionally been cut as gem-stones .

Good crystals have been found also at Achmatovsk near
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Zlatoust in the Urals, Traversella near Ivrea in Piedmont (" traversellite "), Nordmark in Sweden, Monroe in New York, Burgess in
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Lanark county, Ontario, and several other places: at Nordmark the large, rectangular black crystals occur with
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magnetite in the iron mines . (L . J .

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