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ERYTHRITE , the name given to (I) a See also: mineral composed of a hydrated See also: cobalt arsenate, nd (2) in chemistry, a tetrahydric See also: alcohol
.
(I) The mineral erythrite has the See also: formula Co3(AsO4)2.8H2O, and crystallizes in the See also: monoclinic See also: system and is isomorphous with See also: vivianite
.
It sometimes occurs as beautiful radially-arranged See also: groups of blade-shaped crystals with a bright See also: crimson colour and brilliant lustre
.
On exposure to See also: light the colour and lustre deteriorate
.
There is a perfect cleavage parallel to the See also: plane of symmetry, on which the lustre is pearly
.
Cleavage flakes are soft (H=2), sectile and flexible; specific gravity 2.95
.
The mineral is, however, more often found as an earthy encrustation with a peach-blossom colour, and in this See also: form was early (1727) known as cobalt-See also: bloom ( Ger
.
Kobaltbliithe)
.
The name erythrite, from ipv0pbs, " red," was given by F
.
S
.
Beudant in 1382
.
Erythrite occurs as a product of alteration of See also: smaltite (CoAs2) and other cobaltiferous arsenides
.
The finest crystallized specimens are from See also: Schneeberg in See also: Saxony
.
The earthy variety has been found in Thuringia and See also: Cornwall and some other plates
.
(2) The alcohol erythrite has the constitutional formula HO•H2C•CH(OH)•CH(OH)•CH2OH; it is also known as erythrol, erythroglucin and phycite
.
It corresponds to tartaric acid, and, like this substance, it occurs in four stereo-isomeric forms
.
The internally compensated modification, i-erythrite, corresponding to mesotartaric acid, occurs See also: free in the See also: algae Protococcus vulgaris, and as the orsellinate, erythrin, C4H6(OH)2(O•C8H203)2, in many See also: lichens and algae, especially Roccella montagnei
.
It has a sweet taste, melts at 126°, and boils at 330
.
Careful oxidation withdilute nitric acid gives erythrose or tetrose, which is probably a mixture of a trioxyaldehyde and trioxyketone
.
Energetic oxidation gives erythritic acid and mesotartaric acid. i-Erythrite and the racemic mixture of the dextro and laevo varieties were synthesized by Griner in 1893 from divinyl
.
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