Online Encyclopedia

Search over 40,000 articles from the original, classic Encyclopedia Britannica, 11th Edition.

RUDOLF FITTIG (1835– )

Online Encyclopedia
Originally appearing in Volume V10, Page 440 of the 1911 Encyclopedia Britannica.
Spread the word: del.icio.us del.icio.us it!

See also:

RUDOLF See also:FITTIG (1835– )  , See also:German chemist, was See also:born at See also:Hamburg on the 6th of See also:December 1835 . He studied See also:chemistry at See also:Gottingen, graduating as Ph.D. with a dissertation on See also:acetone in 1858 . He subsequently held several appointments at Gottingen, being privat docent (186o), and extraordinary See also:professor (1870) . In 187o he obtained the See also:chair at See also:Tubingen, and in 1876 that at See also:Strassburg, where the laboratories were erected from his designs . See also:Fittig's researches are entirely in organic chemistry, and See also:cover an exceptionally wide See also:field . The See also:aldehydes and See also:ketones provided material for his earlier See also:work . He observed that aldehydes and ketones may suffer reduction in neutral, alkaline, and sometimes See also:acid See also:solution to secondary and See also:tertiary See also:glycols, substances which he named pinacones; and also that certain pinacones when distilled with dilute sulphuric acid gave compounds, which he named pinacolines . The unsaturated acids, also received much See also:attention, and he discovered the See also:internal anhydrides of oxyacids, termed See also:lactones . In 1863 he introduced the reaction known by his name . In 1855 Adolph See also:Wurtz had shown that when See also:sodium acted upon alkyl iodides, the alkyl residues combined to See also:form more complex See also:hydrocarbons; Fittig See also:developed this method by showing that a mixture of an aromatic and alkyl haloid, under similar treatment, yielded homologues of See also:benzene . His investigations on See also:Perkin's reaction led him to an explanation of its mechanism which appeared to be more in accordance with the facts . The question, however, is one of much difficulty, and the exact course of the reaction appears to await solution .

These researches incidentally solved the constitution of See also:

coumarin, the odoriferous principle of woodruff . Fittig and See also:Erdmann's observation that phenyl isocrotonic acid readily yielded a-naphthol by loss of See also:water was of much importance, since it afforded valuable See also:evidence as to the constitution of See also:naphthalene . They also investigated certain hydrocarbons occurring in the high boiling point fraction of the See also:coal See also:tar distillate and solved the constitution of phenanthrene . We also owe much of our knowledge of the See also:alkaloid See also:piperine to Fittig, who in collaboration with Ira Remsen established its constitution in 1871 . Fittig has published two widely used See also:text-books; be edited several See also:editions of See also:Wohler's Grundriss der organischen Chemie (11th ed., 1887)and wrote an Unorganische Chemie (1st ed., 1872; 3rd, 1882) . His researches have been recognized by many scientific See also:societies and institutions, the Royal Society awarding him the See also:Davy See also:medal in 1906 .

End of Article: RUDOLF FITTIG (1835– )
[back]
FITCHBURG
[next]
MARY FITTON (c. 1578-1647)

Additional information and Comments

There are no comments yet for this article.
» Add information or comments to this article.
Please link directly to this article:
Highlight the code below, right click and select "copy." Paste it into a website, email, or other HTML document.