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See also:FLUORENE (a-diphenylene methane), C13H16 or .(See also:C6H4)2CH2, a See also:hydrocarbon found in See also:coal-See also:tar . It is obtained from the higher boiling fractions, after separation of See also:naphthalene and See also:anthracene, by fractional See also:distillation, the portion boiling between 290—340° C. being taken . The See also:fluorene is separated from this by placing it in a freezing mixture, and is then redistilled or crystallized from glacial acetic See also:acid, or purified by means of its picrate . It may be prepared by distilling diphenylene ketone over See also:zinc dust, or by See also:heating it with hydriodic acid and See also:phosphorus to 1 50—16o° C.; and also by passing the vapour of See also:diphenyl methane through a red hot See also:tube . It crystallizes in colourless plates, possessing a See also:violet See also:fluorescence, melting at 112—113° and boiling at 293—295° C . By oxidation with chromic acid in glacial acetic acid See also:solution, it is converted into diphenylene ketone (CsH4)z•CO; whilst on heating with hydriodic acid and phosphorus to 250—260° C. it gives a hydro derivative of See also:composition C13H22 . |
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