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GLUE (from the O. Fr. glu, bird-lime,...

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Originally appearing in Volume V12, Page 144 of the 1911 Encyclopedia Britannica.
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GLUE (from the O. Fr. glu, See also:bird-See also:lime, from the See also:Late See also:Lat. See also:gluten, glus, glue)  , a valuable agglutinant, consisting of impure See also:gelatin and widely used as an adhesive See also:medium for See also:wood, See also:leather, See also:paper and similar substances . Glues and gelatins See also:merge into one another by imperceptible degrees . The difference is conditioned by the degree of purity: the more impure See also:form is termed See also:glue and is only used as an adhesive, the purer forms, termed gelatin, have other applications, especially in culinary operations and See also:confectionery . Referring to the See also:article GELATIN for a See also:general See also:account of this substance, it is only necessary to See also:state here that gelatigenous or glue-forming tissues occur in the bones, skins and intestines of all animals, and that by extraction with hot See also:water these agglutinating materials are removed, and the See also:solution on evaporating and cooling yields a jelly-like substance —gelatin or glue . Glues may be most conveniently classified according to their See also:sources: See also:bone glue, skin glue and See also:fish glue; these may be regarded severally as impure forms of bone gelatin, skin gelatin and See also:isinglass . Bone Glue.—For the manufacture of glue the bones are supplied fresh or after having been used for making soups; See also:Indian and See also:South See also:American bones are unsuitable, since, by See also:reason of their previous treatment with See also:steam, both their fatty and glue-forming constituents have been already removed (to a See also:great extent) . On the See also:average, fresh bones contain about 50% of See also:mineral See also:matter, mainly See also:calcium and See also:magnesium See also:phosphates, about 12% each of moisture and See also:fat, the See also:remainder being other organic matter . The mineral matter reappears in See also:commerce chiefly as artificial manure; the fat is employed in the See also:candle, See also:soap and See also:glycerin See also:industries, while the other organic matter supplies glue . The separation of the fat, or " de-greasing of the bones " is effected (1) by boiling the bones with water in open vessels; (2) by treatment with steam under pressure; or (3) by means of solvents . The last See also:process is superseding the first two, which give a poor return of fat—a valuable See also:consideration—and also involve the loss of a certain amount of glue . Many solvents have_ been proposed; the greatest commercial success appears to attend Scottish shale oil and natural See also:petroleum (See also:Russian or American) boiling at about See also:ioo° C . The vessels in which theextraction is carried out consist of upright cylindrical boilers, provided with manholes for charging, a false bottom on which the bones See also:rest, and with two steam coils—one for See also:heating only, the other for leading in " live " steam .

There is a See also:

pipe from the See also:top of the See also:vessel leading to a condensing plant . The vessels are arranged in batteries . In the actual operation the See also:boiler is charged with bones, solvent is run in, and the mixture gradually heated by means of the dry coil; the spirit distils over, carrying with it the water See also:present in the bones; and after a See also:time the extracted fat is run off from See also:discharge cocks in the bottom of the extractor.' A fresh See also:charge of solvent is introduced, and the See also:cycle repeated; this is repeated a third and See also:fourth time, after which the bones contain only about 0.2% of fat, and a little of the solvent, which is removed by blowing in live steam under qo to 8o lb pressure . The de-greased bones are now cleansed from all dirt and flesh by rotation in a See also:horizontal cylindrical See also:drum covered with stout See also:wire See also:gauze . The See also:attrition accompanying this See also:motion suffices to remove- the loosely adherent matter, which falls through the meshes of the gauze; this See also:meal contains a certain amount of glue-forming matter, and is generally .passed through a finer mesh, the residuum being worked up in the glue-See also:house, and the See also:flour which passes through being sold as a bone-meal, or used as a manure . The bones, which now contain 5 to 6% of glue-forming See also:nitrogen and about 6o % of calcium phosphate, are next treated for glue . The most economical process consists in steaming the bones under pressure (15 lb to start with, afterwards 5 lb) in upright cylindrical boilers fitted with false bottoms . The glue-liquors collect beneath the false bottoms, and when of a strength equal to about 20% dry glue they are run off to the clarifiers . The first runnings contain about 65 to 7o% of. the See also:total glue; a second steaming extracts another 25 to 30% . For clarifying the solutions, See also:ordinary See also:alum is used, one See also:part being used for zoo parts of dry glue . The alum is added to the hot liquors , and the temperature raised to roo°; it is then allowed to See also:settle, and the See also:surface scum removed by filtering through coarse See also:calico or See also:fine wire filters . The clear liquors are now concentrated to a strength of about 32 % dry glue in See also:winter and 35 % in summer .

This is invariably effected in vacuum pans—open boiling yields a dark-coloured and inferior product . Many types of vacuum plant are in use; the Yaryan form, invented by H . T . Yaryan, is perhaps the best, and the See also:

double effect See also:system is the most efficient . After concentration the liquors are bleached by blowing in See also:sulphur dioxide, manufactured by burning sulphur; by this means the See also:colour can be lightened to any desired degree . The liquors are now run into galvanized See also:sheet-See also:iron troughs, 2 ft. See also:long, 6 in. wide and 5 in. deep, where they congeal to a See also:firm jelly, which is subsequently removed by cutting See also:round the edges, or by warming with hot water, and turning the cake out . The cake is sliced to sheets of convenient thickness, generally by means of a wire See also:knife, i.e. a piece of wire placed in a See also:frame . See also:Mechanical slicers acting on this principle are in use . Instead of allowing the solution to congeal in troughs, it may be " See also:cast " on sheets of See also:glass, the bottoms of which are cooled by See also:running water . After congealing, the tremulous jelly is dried; this is an operation of great nicety: the See also:desiccation must be slow and is generally effected by circulating a rapid current of See also:air about the cakes supported on nets set in frames; it occupies from four to five days, and the cake contains on the average from to to 13 % of water . Skin Glue.—In the preparation of skin glue the materials used are the parings and cuttings of hides from tan-yards, the ears of oxen and See also:sheep, the skins of rabbits, See also:hares, See also:cats, See also:dogs and other animals, the parings of tawed leather, See also:parchment and old gloves, and many other See also:miscellaneous scraps of See also:animal matter . Much experience is needed in See also:order to prepare a See also:good ' This fat contains a small quantity of solvent, which is removed by heating with steam, when the solvent distils off .

Hot water is then run in to melt the fat, which rises to the surface of the water and is floated off . Another boiling with water, and again floating off, frees the fat from dirt and mineral matter, and the product is ready for tasking . glue from such heterogeneous materials; one blending may be a success and another a failure . The raw material has been divided into three great divisions: (I) sheep pieces and fleshings (ears, &c.); (2) ox fleshings and trimmings; (3) OR hides and pieces; the best glue is obtained from a mixture of the hide, See also:

ear and See also:face clippings of the ox and See also:calf . The raw material or " stock " is first steeped for from two to ten See also:weeks, according to its nature, in wooden vats or pits with See also:lime water, and after-wards carefully dried and stored . The See also:object of the lime steeping is to remove any See also:blood and flesh which may be attached to the skin, and to form a lime soap with the fatty matter present . The " scrows " or glue pieces, which may be kept a long time without undergoing See also:change, are washed with a dilute hydrochloric See also:acid to remove all lime, and then very thoroughly with water; they are now allowed to drain and dry . The skins are then placed in See also:hemp nets and introduced into an open boiler which has a false bottom, and a tap by which liquid may be run off . As the boiling proceeds test quantities of liquid are from time to time examined, and when a See also:sample is found on cooling to form a stiff jelly, which happens when it contains about 32 % dry glue, it is ready to draw off . The solution is then run to a clarifier, in which a temperature sufficient to keep it fluid is maintained, and in this way any impurity is permitted to subside . The glue solution is then run into wooden troughs or coolers in which it sets to a firm jelly . The cakes are removed as in the See also:case of bone glue (see above), and, having been placed on nets, are, in the Scottish practice, dried by exposure to open air .

Phoenix-squares

This See also:

primitive method has many disadvantages: on a hot See also:day the cake may become unshapely, or melt and slip through the See also:net, or dry so rapidly as to crack; a See also:frost may produce fissures, while a See also:fog or mist may precipitate moisture on the surface and occasion a mouldy See also:appearance . The surface of the cake, which is generally dull after drying, is polished by washing with water . The practice of boiling, clarification, cooling and drying, which has been already described in the case of bone glue, has been also applied to the separation of skin glue . Fish Glue.—Whereas isinglass, a very pure gelatin, is yielded by the sounds of a limited number of fish, it is found that all fish offals yield a glue possessing considerable adhesive properties . The manufacture consists in thoroughly washing the See also:offal with water, and then discharging it into extractors with live steam . After digestion, the liquid is run off, allowed to stand, the upper oily layer removed, and the See also:lower gluey solution clarified with alum . The liquid is then filtered, concentrated in open vats, and bleached with sulphur dioxide.1 Fish glue is a See also:light-See also:brown viscous liquid which has a distinctly disagreeable odour and an acrid See also:taste; these disadvantages to its use are avoided if it be boiled with a little water and 1% of See also:sodium phosphate, and 0'025% of saccharine added . Properties of Glue.—A good quality of glue should be See also:free from all specks and grit, have a See also:uniform, light brownish-yellow, transparent appearance, and should break with a glassy fracture . Steeped for some time in See also:cold water it softens and swells up without dissolving, and when again dried it ought to resume its See also:original properties . Under the See also:influence of See also:heat it entirely dissolves in water, forming a thin syrupy fluid with a not disagreeable See also:smell . The adhesiveness of different qualities of glue varies considerably; the best adhesive is formed by steeping the glue, broken in small pieces, in water until they are quite soft, and then placing them with just sufficient water to effect solution in the glue-pot . The hotter the glue, the better the See also:joint; remelted glue is not so strong as the freshly prepared; and newly manufactured glue is inferior to that which has been long in stock .

It is therefore seen that many factors enter into the determination of the cohesive See also:

power of glue; a well-prepared joint may, under favourable conditions, withstand a pull of about 700 lb per sq. in . The following table, after Kilmarsch, shows the holding power of glued See also:joints with various kinds of See also:woods . 1 The See also:residue in the extractors is usually dried in steam-heated vessels, and mixed with See also:potassium and magnesium salts; the product is then put on the See also:market as fish-potash See also:guano . lb per sq. in . Wood . With See also:grain . Across grain . See also:Beech . . 852 434'5 See also:Maple . . 484 346 See also:Oak 704 302 See also:Fir 605 132 See also:Special Kinds of Glues, Cements, &'c.—By virtue of the fact that the word " glue " is frequently used to denote many adhesives, which may or may not contain gelatin, there will now be given an account of some special preparations . These may be conveniently divided into: (1) liquid glues, mixtures containing gelatin which do not jelly at ordinary temperatures but still possess adhesive properties; (2) water-See also:proof glues, including mixtures containing gelatin, and also the " marine glues," which contain no glue; (3) glues or cements for special purposes, e.g. for cementing glass, pottery, leather, &c., for cementing dissimilar materials, such as paper or leather to iron . Liquid Glues.—The demand for liquid glues is mainly due to the disadvantages—the See also:necessity of dissolving and using while hot—of ordinary glue .

They are generally prepared by adding to a warm glue solution some reagent which destroys the See also:

property of gelatinizing . The reagents in See also:common use are acetic acid; magnesium chloride, used for a glue employed by printers; hydrochloric acid and See also:zinc sulphate; nitric acid and See also:lead sulphate; and phosphoric acid and ammonium carbonate . Water-proof Glues.—Numerous recipes for water-proof glues have been published; glue, having been swollen by soaking in water, dissolved in four-fifths its See also:weight of See also:linseed oil, furnishes a good water-proof adhesive; linseed oil See also:varnish and litharge, added to a glue solution, is also used; See also:resin added to a hot glue solution in water, and afterwards diluted with See also:turpentine, is another See also:recipe; the best glue is said to be obtained by dissolving one part of glue in'one and a See also:half parts of water, and then adding one-fiftieth part of potassium bichromate . Alcoholic solutions of various gums, and also tannic acid, confer the same property on glue solutions . The " marine glues " are solutions of See also:india-See also:rubber, shellac or asphaltum, or mixtures of these substances, in See also:benzene or See also:naphtha . See also:Jeffrey's marine glue is formed by dissolving india-rubber in four parts of benzene and adding two parts of shellac; it is extensively used, being easily applied and drying rapidly and hard . Another water-proof glue which contains no gelatin is obtained by heating linseed oil with five parts of quicklime; when cold it forms a hard See also:mass, which melts on heating like ordinary glue . Special Glues.—There are innumerable recipes for adhesives specially applicable to certain substances and under certain conditions . For repairing glass, See also:ivory, &c. isinglass (q.v.), which may be replaced by fine glue, yields valuable cements; bookbinders employ an elastic glue obtained from an ordinary glue solution and glycerin, the water being expelled by heating; an efficient See also:cement for mounting photographs is obtained by dissolving glue in ten parts of See also:alcohol and adding one part of glycerin; portable or mouth glue—so named because it melts in the mouth—is prepared by dissolving one part of See also:sugar in a solution of four parts of glue . An india-rubber substitute is obtained by adding sodium tungstate and hydrochloric acid to a strong glue solution; this preparation may be rolled out when heated to 6o° . For further details see See also:Thomas See also:Lambert, Glue, Gelatine and their Allied Products (See also:London, 1905) ; R . L .

Fernbach, Glues and Gelatine (1907); H . C . Standage, Agglutinants of all Kinds for all Purposes (1907) .

End of Article: GLUE (from the O. Fr. glu, bird-lime, from the Late Lat. gluten, glus, glue)
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