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atomic weight 195.7 GOLD [symbol Au (...

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Originally appearing in Volume V12, Page 200 of the 1911 Encyclopedia Britannica.
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atomic See also:

weight 195.7 See also:GOLD [See also:symbol Au (H = 1),197.2(0 =16)]  , a metallic chemical See also:element, valued from the earliest ages on See also:account of the permanency of its See also:colour and lustre . See also:Gold ornaments of See also:great variety and elaborate workmanship have been discovered on sites belonging to the earliest known civilizations; Minoan, See also:Egyptian, See also:Assyrian, See also:Etruscan (see See also:JEWELRY, See also:PLATE, See also:EGYPT, See also:CRETE, See also:AEGEAN See also:CIVILIZATION, See also:NUMISMATICS), and in See also:ancient literature gold is the universal See also:symbol of the highest purity and value (cf. passages in the Old Testament, e.g . Ps. xix. ro " More to be desired are they than gold, yea, than much See also:fine gold ") . With regard to the See also:history of the metallurgy of gold, it may be mentioned that, according to See also:Pliny, See also:mercury was employed in his See also:time both as a means of separating the See also:precious metals and for the purposes of See also:gilding . See also:Vitruvius also gives a detailed account of the means of recovering gold, by amalgamation, from See also:cloth into which it had been See also:woven . See also:Physical Properties:—Gold has a characteristic yellow colour, which is, however, notably affected by small quantities of other metals; thus the tint is sensibly lowered by small quantities of See also:silver, and heightened by See also:copper . When the gold is finely divided, as in " See also:purple of See also:Cassius," or when it is precipitated from solutions, the colour is See also:ruby-red, while in very thin leaves it transmits a greenish See also:light . It is nearly as soft as See also:lead and softer than silver . When pure, it is the most malleable of all metals (see See also:GOLDBEATING) . It is also extremely ductile; a single See also:grain may be See also:drawn into a See also:wire 500 ft. in length, and an See also:ounce of gold covering a silver wire is capable of being extended more than 1300 M . The presence of See also:minute quantities of See also:cadmium, lead, See also:bismuth, See also:antimony, See also:arsenic, See also:tin, See also:tellurium and See also:zinc rendersgold brittle, --y-oth See also:part of one of the three metals first named being sufficient to produce that quality . Gold can be readily welded See also:cold; the finely divided See also:metal, in the See also:state in which it is precipitated from See also:solution, may be compressed between See also:dies into disks or medals .

The specific gravity of gold obtained by precipitation from solution by ferrous sulphate is from 19.55 to 20.72 . The specific gravity of See also:

cast gold varies from 18.29 to 19.37, and by See also:compression between dies the specific gravity may be raised from 19.37 to 19.41; by See also:annealing, however, the previous See also:density is to some extent recovered, as it is then found to be 19.40 . The melting-point has been variously given, the See also:early values ranging from 1425° C. to 1035° C . Using improved methods, C . T . Heycock and F . H . See also:Neville determined it to be Io61'7° C.; See also:Daniel See also:Berthelot gives Io64° C., while Jaquerod and See also:Perrot give 1066.1-1067.4° C . At still higher temperatures it volatilizes, forming a reddish vapour . Macquer and See also:Lavoisier showed that when gold is strongly heated, fumes arise which gild a piece of silver held in them . Its volatility has also been studied by L . Elsner, and, in the presence of other metals, by See also:Napier and others .

The volatility is barely appreciable at Io75°; at 125o° it is four times as much as at ruoo°° . Copper and zinc increase the volatility far more than lead, while the greatest volatility is induced, according to T . See also:

Kirke See also:Rose, by tellurium . It has also been shown that gold volatilizes when a gold-See also:amalgam is distilled . Gold is dissipated by sending a powerful See also:charge of See also:electricity through it when in the See also:form of See also:leaf or thin wire . The electric conductivity is given by A . Matthiessen as 73 at o° C., pure silver being See also:loo; the value of this coefficient depends greatly on the purity of the metal, the presence of a few thousandths of silver lowering it by Io% . Its conductivity for See also:heat has been variously given as Io3 (C . M . Despretz), 98 (F . Crace-See also:Calvert and R . See also:Johnson), and 6o (G .

H . See also:

Wiedemann and R . See also:Franz), pure silver being loo . Its specific heat is between 0.0298 (See also:Dulong and See also:Petit) and 0.03244 (See also:Regnault) . Its coefficient of expansion for each degree between o° and roo° C. is 0.0000r466,, or for gold which has been annealed 0.000015136 (See also:Laplace and Lavoisier) . The spark spectrum of gold has been mapped by A . See also:Kirchhoff, R . Thalen, See also:Sir See also:William See also:Huggins and H . Kruss; the brightest lines are 6277, 5960, 5955 and 5836 in the See also:orange and yellow, and 5230 and 4792 in the See also:green and See also:blue . Chemical Properties.—Gold is permanent in both dry and moist See also:air at See also:ordinary or high temperatures . It is insoluble in hydrochloric, nitric and sulphuric acids, but dissolves in aqua regia—a mixture of hydrochloric and nitric acids—and when very finely divided in a heated mixture of strong sulphuric See also:acid and a little nitric acid; dilution with See also:water, however, precipitates the metal as a See also:violet or See also:brown See also:powder from this solution . The metal is soluble in solutions of See also:chlorine, See also:bromine, thiosulphates and cyanides; and also in solutions which generate chlorine, such as mixtures of hydrochloric acid with nitric acid, chromic acid, antimonious acid, peroxides and nitrates, and of nitric acid with a chloride .

Gold is also attacked when strong sulphuric acid is submitted to See also:

electrolysis with a gold See also:positive See also:pole . W . Skey showed that in substances which contain small quantities of gold the precious metal may be removed by the solvent See also:action of See also:iodine or bromine in water . ' See also:Filter See also:paper soaked with the clear. solution is burnt, and the presence of gold is indicated by the purple colour of the aslr . In solution minute quantities of gold may be detected by the formation of " purple of Cassius," a bluish-purple precipitate thrown down by a mixture of ferric and stannous chlorides . The atomic See also:weight of gold was first determined with accuracy by See also:Berzelius, who deduced the value 195.7 (H= I) from the amount of mercury necessary to precipitate it from the chloride, and 195.2 from the ratio between gold and See also:potassium chloride in potassium aurichloride, KAuC14 . Later determinations were made by Sir T . E . See also:Thorpe and A . P . Laurie, Kriiss and J . W .

See also:

Mallet . Thorpe and Laurie converted potassium auribromide into a mixture of metallic gold and potassium bromide by careful, See also:heating . The relation of the gold to the potassium bromide, as well as the amounts of silver and silver bromide which are See also:equivalent to the potassium bromide, were determined . The mean value thus adduced 'was 195.86 . Kruss worked with the same See also:salt, and obtained the value 195.65; while Mallet, by analyses of gold chloride and bromide, and potassium auribromide, obtained the value 195.77 . Occlusion of See also:Gas by Gold.—T . See also:Graham showed that gold is capable of occluding by See also:volume o-4.8% of See also:hydrogen, 0.20% of See also:nitrogen, 0.29% of See also:carbon monoxide, and o.16% of carbon dioxide . Varrentrapp pointed out that " cornets " from the assay of gold may retain gas if they are not strongly heated . Occurrence and See also:Distribution.—Gold is found in nature chiefly in the metallic state, i.e. as " native gold," and less frequently in See also:combination with tellurium, lead and silver . These are the only certain examples of natural combinations of the metal, the minute, though economically valuable, quantity often found in See also:pyrites and other sulphides being probably only See also:present in See also:mechanical suspension . The native metal crystallizes in the cubic See also:system, the See also:octahedron being the commonest form, but other and complex combinations have been observed . Owing to the softness of the metal, large crystals are rarely well defined, the points being commonly rounded .

In the irregular crystalline aggregates branching and See also:

moss-like forms are most See also:common, and in Transylvania thin plates or sheets with See also:diagonal structures are found . More characteristic, however, than the crystallized are the irregular forms,which, when large, are known as "nuggets" or " pepites," and when in pieces below 4 to oz. weight as gold dust, the larger sizes being distinguished as coarse or nuggety gold, and the smaller as gold dust proper . Except in the larger nuggets, which may be more or less angular, or at times even masses of crystals, with or without associated See also:quartz or other See also:rock, gold is generally found See also:bean-shaped or in some other flattened form, the smallest particles being scalps of scarcely appreciable thickness, which, from their small bulk as compared with their See also:surface, subside very slowly when suspended in water, and are therefore readily carried away by a rapid current . These form the " See also:float gold " of the miner . The physical properties of native gold are generally similar to that of the melted metal . Of the minerals containing gold the most important are See also:sylvanite or graphic tellurium (Ag, Au) Tee, with 24 to 26%; calaverite, AuTe2, with 42%; nagyagite or foliate tellurium (Pb, Au)i6 Sb,(S, Te)24, with 5 to 9% of gold; petzite, (Ag, Au)2Te, and See also:white tellurium . These are confined to a few localities, the See also:oldest and best known being those of Nagyag and Offenbanya in Transylvania; they have also been found at Red See also:Cloud, See also:Colorado, in Calaveras See also:county, See also:California, and at See also:Perth and See also:Boulder, See also:West See also:Australia . The minerals of the second class, usually spoken of as " auriferous," are comparatively numerous . Prominent among these are See also:galena and See also:iron pyrites, the former being almost invariably gold-bearing . Iron pyrites, however, is of greater See also:practical importance, being in some districts exceedingly See also:rich, and, next to the native metal, is the most prolific source of gold . Magnetic pyrites, copper pyrites, zinc See also:blende and arsenical pyrites are other and less important examples, the last constituting the gold ore formerly worked in See also:Silesia . A native gold amalgam is found as a rarity in California, and bismuth from See also:South See also:America is sometimes rich in gold .

Native arsenic and antimony are also very frequently found to contain gold and silver . The association and distribution of gold may be considered under two different heads, namely, as it occurs in See also:

mineral See also:veins—" See also:reef gold," and in alluvial or other superficial deposits which are derived from the See also:waste of the former—" alluvial gold." Four distinct types of reef gold deposits may be distinguished: (I) Gold may occur disseminated through metalliferous veins, generally with sulphides and more particularly with pyrites . These deposits seem to be the See also:primary See also:sources of native gold . (2) More common are the auriferous quartz-reefs—veins or masses of quartz containing gold in flakes visible to the naked See also:eye, or so finely divided as to be invisible . (3) The " See also:banket " formation, which characterizes the goldfields of South See also:Africa, consists of a See also:quartzite See also:conglomerate throughout which gold is very finely disseminated . (4) The siliceous See also:sinter at If' 194 See also:Mount See also:Morgan, See also:Queensland, which is obviously associated with hydrothermal action, is also gold-bearing . The See also:genesis of the last three types of See also:deposit is generally assigned to the simultaneous percolation of solutions of gold and See also:silica, the auriferous solution being formed during the disintegration of the gold-bearing metalliferous veins . But there is much uncertainty as to the mechanism of the See also:process; some authors hold that the soluble chloride is first formed, while others postulate the intervention of a soluble aurate . In the alluvial deposits the associated minerals are chiefly those of great density and hardness, such as See also:platinum, osmiridium and other metals of the platinum See also:group, tinstone, chromic, magnetic and brown iron ores, See also:diamond, ruby and See also:sapphire, See also:zircon, See also:topaz, See also:garnet, &c. which represent the more durable See also:original constituents of the rocks whose distintegration has furnished the detritus . See also:Statistics of Gold See also:Production.—The See also:supply of gold, and also its relation to the supply of silver, has, among civilized nations, always been of See also:paramount importance in the economic questions concerning See also:money (see MONEY and See also:BIMETALLISM); in this See also:article a See also:summary of the See also:modern gold-producing areas will be given, and for further details reference should be made to the articles on the localities named . The See also:chief sources of the See also:European supply during the See also:middle ages were the mines of See also:Saxony and See also:Austria, while See also:Spain also contributed . The supplies from See also:Mexico and See also:Brazil were important during the 16th and 17th centuries .

See also:

Russia became prominent in 1823, and for fourteen years contributed the bulk of the supply . The See also:United States (California) after 1848, and Australia after 1851, were responsible for enormous increases in the See also:total production, which has been subsequently enhanced by discoveries in See also:Canada, South Africa, See also:India, See also:China and other countries . The See also:average See also:annual See also:world's production for certain periods from 18oI to 188o in ounces is given in Table I . The average TABLE I . See also:Period . Oz . Period . Oz . 1801-1810 590,750 1856-186o 6,350,180 1811-1820 380,300 1861-1865 5,951,770 1821–1830 472,400 1866–1870 6,169,660 1831-1840 674,200 1871-1875 5,487,400 1841–1850 1,819,600 1876–188o 5,729,300 1851-1855 6,350,180 — — production of the five years 1881-1885 was the smallest since the Australian and Californian mines began to be worked in 1848-1849; the minimum 4,614,588 oz., occurred in 1882 . It was not until after 1885 that the annual output of the world began to expand . Of the total production in 1876, 5,016,488 oz., almost the whole was derived from the United States, See also:Australasia and Russia . Since then the proportion furnished by these countries has been greatly lowered by the supplies from South Africa, Canada, India and China .

The increase of production has not been See also:

uniform, the greater part having occurred most notably since 1895 . Among the regions not previously important as gold-producers which now contribute to the annual output, the most remarkable are the goldfields of South Africa (See also:Transvaal and See also:Rhodesia, the former of which were discovered in 1885) . India likewise has been added to the See also:list, its active production having begun at about the same time as that of South Africa . The average annual product of India for the period 1886 to 1899 inclusive was £698,208, and its present annual product averages about S50,000 oz., or about £2,200,000, obtained almost wholly from the See also:free-milling quartz veins of the Colar goldfields in See also:Mysore, See also:southern India . In 1900 the output was valued at £1,891,804, in 1905 at £2,450,536, and in 1908 at £2,270,000 . Canada, too, assumed an important See also:rank, having contributed in 1900 £5,583,300; but the output has since steadily declined to £1,973,000 in 1908 . The great increase during the few years preceding 1899 was due to the development of the 'goldfields of the See also:North-Western Territory, especially See also:British See also:Columbia., From the See also:district of See also:Yukon (See also:Klondike, &c.) £2,800,000 was obtained in 1899, wholly from alluvial workings, but the progress made since has been slower than was expected by sanguine See also:people . It is, however, probable that the North-Western Territory will continue to yield gold in important quantities for some time to come . The output of the United States increased from £7,050,000in 1881 to £16,085,567 in 1900, £17,916,000 in 1905, and to £20,065,000 in 1908 . This increase was chiefly due to the exploitation of new goldfields . The fall in the See also:price of silver stimulated the See also:discovery and development of gold deposits, and many states formerly regarded as characteristically silver districts have become important as gold producers . Colorado is a See also:case in point, its output having increased from about £600,000 in 188o to £6,o65,000 in 1900; it was £5,139,800 in 1905 .

Some-what more than one-See also:

half of the Colorado gold is obtained from the Cripple See also:Creek district . Other states also showed a largely augmented product . On the other See also:hand, the output of California, which was producing over £3,000,000 per annum in 1876, has fallen off, the average annual output from 1876 to 1900 being £2,800,000; in 1905 the yield was £3,839,000 . This decrease was largely caused by the practical suspension for many years of the See also:hydraulic See also:mining operations, in preparation for which millions of dollars had been expended in deep tunnels, flumes, &c., and the active continuance of which might have been expected to yield some £2,000,000 of gold annually . This interruption, due to the practical See also:prohibition of the See also:industry by the United States courts, on the ground that it was injuring, through the deposit of tailings, agricultural lands and navigable streams, was lessened, though not entirely removed, by compromises and regulations which permit, under certain restrictions, the renewed exploitation of the ancient See also:river-beds by the hydraulic method . On the other hand, the progressive reduction of mining and metallurgical See also:costs effected by improved transportation and machinery, and the use of high See also:explosives, compressed air, electric-See also:power transmission, &c., resulted in California (as elsewhere) in a notable revival of deep mining . This was especially the case on the " See also:Mother Lode," where highly promising results were obtained . Not only is vein-material formerly regarded as unremunerative now extracted at a profit, but in many instances increased gold-values have been encountered below zones of relative barrenness, and operators have been encouraged to make costly preparations for really deep mining —more than 3000 ft. below the surface . The gold product of California, therefore, may be fairly expected to maintain itself, and, indeed, to show an advance . See also:Alaska appeared in the list of gold-producing countries in 1886, and gradually increased its annual output until 1897, when the See also:country attracted much See also:attention with a production valued at over £500,000; the opening up of new workings has increased this figure immensely, from about £1,400,000 in 1901 to £3,006,500 in 1905 . The Alaska gold was derived almost wholly from the large See also:low-grade quartz mines of See also:Douglas See also:Island See also:prior to 1899, but in that See also:year an important district was discovered at Cape See also:Nome, on the north-western See also:coast . The result of a few months' working during that year was more than £500,000 of gold, and a very much larger annual output may reasonably be anticipated in the future; in 1905 it was about £900,000 .

The gold occurs in alluvial deposits designated as gulch-, See also:

bar-, See also:beach-, See also:tundra- and See also:bench-placers . The tundra is a coastal See also:plain, swampy and covered with under-growth and underlaid by See also:gravel . The most interesting and, thus far, the most productive are the beach deposits, similar to those on the coast of See also:Northern California . These occur in a See also:strip of comparatively fine gravel and See also:sand, 150 yds. wide, extending along the See also:shore . The gold is found in stratified layers, with " ruby " and See also:black sand . The " ruby " sand consists chiefly of fine garnets and magnetites, with a few rose-quartz grains . Further exploration of the interior will probably result in the discovery of additional gold districts . Mexico, from a gold production of £200,000 in 1891, advanced to about £1,881,800 in 1900 and to about £3,221,000 in 1905 . Of this increase, a considerable part was derived from gold-quartz mining, though much was also obtained as a by-product in the working of the ores of other metals . The product of See also:Colombia, See also:Venezuela, the Guianas, Brazil, See also:Uruguay, See also:Argentina, See also:Chile, See also:Bolivia, See also:Peru and See also:Ecuador amounted in 1900 to £2,481,000 and to £2,046,000 in 1905 . In 1876 Australasia produced £7,364,000, of which See also:Victoria contributed £3,984,000 . The annual output of Victoria declined until the year 1892, when it began to increase rapidly, but not to its former level, the values for 1900 and 1905 being £3,142,000 and £3,138,000 .

There has been an important increase in Queensland, which advanced from £1,696,000 in 1876 to £2,843,000 in 1900, and subsequently declined to £2,489,000 in 1905 . There has been no increase, and, indeed, no large fluctuation until quite recently in the output of New See also:

Zealand, which averaged £1,054,000 per annum from 1876 to 1898, but the production of the two years 1900and 1905 rose to £1,42 5,459 and £2,070,407 respectively . By far the most important addition to the Australasian product has come fromWestAustralia,which began its production in 1887 - about the time of the inception of mining at Witwatersrand ("the See also:Rand") in South Africa-and by continuous in-crease, which assumed large proportions towards the See also:close of the 19th See also:century, was £6,426,000 in 1899, £6,179,000 in 1900, and £8,212,000 in 1905 . The total Australasian production in 1908 was valued at £14,708,000 . Undoubtedly the greatest of the gold discoveries made in the latter half of the 19th century was that of the Witwatersrand district in the Transvaal . By See also:reason of its unusual See also:geological See also:character and great economic importance this district deserves a more extended description . The gold occurs in conglomerate beds, locally known as "banket." There are several See also:series of parallel beds, interstratified with quartzite and schist, the most important being the "See also:main reef" series . The gold in this See also:con-glomerate reef is partly of detrital origin and partly of the genetic character of ordinary vein-gold . The formation is noted for its regularity as regards both the thickness and the gold-See also:tenor of the ore-bearing reefs, in which respect it is unparalleled in the See also:geology of the auriferous formations . The gold carries, on an average, £2 per ton, and is worked by ordinary methods of gold-mining, See also:stamp-milling and cyaniding . In 1899, 5762 stamps were in operation, crushing 7,331,446 tons of ore, and yielding £15,134,000, equivalent to 25.5% of the world's production . Of this, 8o% came from within 12 M. of See also:Johannesburg .

After See also:

September 1899 operations were suspended, almost entirely owing to the See also:Boer See also:War, but on the 2nd of May 1901 they were started again . In 1905 the yield was valued at £20,802,074, and in 1909 at £30,925,788 . So certain is the ore-bearing formation that See also:engineers in estimating its auriferous contents feel justified in assuming, as a See also:factor in their calculations, a See also:vertical See also:extension limited only by the lowest depths at which mining is feasible . On such a basis they arrived at more than £600,000,000 as the available gold contained in the Witwatersrand conglomerates . This was a conservative estimate, and was made before the full extent of the reefs was known; in 1904 Lionel See also:Phillips stated that the main reef series had been proved for 61 m., and he estimated the gold remaining to be See also:mined to be See also:worth £2,500,000,000 . Deposits similar to the Witwatersrand banket occur in See also:Zululand, and also on the Gold Coast of Africa . In Rhodesia, the country lying north of the Transvaal, where gold occurs in well-defined quartz-veins, there is unquestionable See also:evidence of extensive ancient workings . The economic importance of the region generally has been fully proved . Rhodesia produced £386,148 in 1900 and £722,656 in 1901, in spite of the South See also:African War; the product for 1905 was valued at £1,480,449, and for 1908 at £2,526,000 . 195 The gold production of Russia has been remarkably See also:constant, averaging £4,899,262 per annum; the gold is derived chiefly from placer workings in See also:Siberia . The gold production of China was estimated for 1899 at £1,328,238 and for 1900 at £860,000; it increased in 1901 to about £1,700,000, to fall to £340,000 in 1905; in 1906 and 1907 it recovered to about £1,000,000 . See also:Alloys.-Gold forms alloys with most metals, and of these many are of great importance in the arts .

The alloy with mercury-gold amalgam-is so readily formed that mercury is one of the most powerful agents for extracting the precious metal . With to% of gold present the amalgam is fluid, and with 12.5 % pasty, while with 13 % it consists of yellowish-white crystals . Gold readily alloys with silver and copper to form substances in use from remote times for money, jewelry and plate . Other metals which find application in the metallurgy of gold by virtue of their See also:

property of extracting the gold as an alloy are lead, which combines very readily when molten, and which can afterwards be separated by cupellation, and copper, which is separated from the gold by solution in acids or by electrolysis; molten lead also extracts gold from the copper-gold alloys . The relative amount of gold in an alloy is expressed in two ways: (1) as " fineness," i.e. the amount of gold in See also:loot) parts of alloy; (2) as " carats," i.e. the amount of gold in 24 parts of alloy . Thus, pure gold is 1000 " fine " or 24 See also:carat . In See also:England the following See also:standards are used for plate and jewelry: 375, 500, 625, 750 and 916-6, corresponding to 9, 12, 15, 18 and 22 carats, the alloying metals being silver and copper in varying proportions . In See also:France three alloys of the following standards are used for jewelry, 920, 84o and 750 . A greenish alloy used by goldsmiths contains 70 % of silver and 30% of gold . " Blue gold " is stated to contain 75% of gold and 25 % of iron . The See also:Japanese use for See also:ornament an alloy of gold and silver, the See also:standard of which varies from 35o to 500, the colour of the precious metal being See also:developed by " pickling ' in a mixture of See also:plum-juice, See also:vinegar and copper sulphate . They may be said to possess a series of bronzes, in which gold and silver replace tin and zinc, all these alloys being characterized by See also:patina having a wonderful range of tint .

The common alloy, Shi-ya-ku-Do, contains 70% of copper and 30% of gold ; when exposed to air it becomes coated with a fine black patina, and is much used in See also:

Japan for See also:sword ornaments . Gold wire may be drawn of any quality, but it is usual to add 5 to 9 dwts. of copper to the See also:pound . The " solders " used for red gold contain r part of copper and 5 of gold; for light gold, 1 part of copper, r of silver and 4 of gold . Gold and Silver.-See also:Electrum is a natural alloy of gold and silver . Matthiessen observed that the density of alloys, the See also:composition of which varies from AuAgs to Au,Ag, is greater than that calculated from the densities of the constituent metals . These alloys are harder, more fusible and more sonorous than pure gold . The alloys of the formulae AuAg, AuAg2, AuAg4 and AuAg2o are perfectly homogeneous, and have been studied by Levol . Molten alloys containing more than 8o % of silver deposit on cooling the alloy AuAgs, little gold remaining in the mother liquor . Gold and Zinc.-When present in small quantities zinc renders gold Year . Australasia . Africa . Canada .

India . Mexico . Russia . United Totals .