Online Encyclopedia

Search over 40,000 articles from the original, classic Encyclopedia Britannica, 11th Edition.

THOMAS GRAHAM (1805-1869)

Online Encyclopedia
Originally appearing in Volume V12, Page 319 of the 1911 Encyclopedia Britannica.
Spread the word: del.icio.us del.icio.us it!

See also:

THOMAS See also:GRAHAM (1805-1869)  , See also:British chemist, See also:born at See also:Glasgow on the loth of See also:December 1805, was the son of a See also:merchant of that See also:city . In 1819 he entered the university of Glasgow with the intention of becoming a See also:minister of the Established See also:Church . But under the See also:influence of See also:Thomas See also:Thomson (1773-1852), the See also:professor of See also:chemistry, he See also:developed a See also:taste for experimental See also:science and especially for molecular physics, a subject which formed his See also:main preoccupation throughout his See also:life . After graduating in 1824, he spent two years in the laboratory of Professor T . C . See also:Hope at See also:Edinburgh, and on returning to Glasgow gave lessons in See also:mathematics, and subsequently chemistry, until the See also:year 1829, when he was appointed lecturer in the See also:Mechanics' See also:Institute . In 183o he succeeded Dr See also:Andrew Ure (1778—1857) as professor of chemistry in the Andersonian Institution, and in 1837, on the See also:death of Dr See also:Edward See also:Turner, he was transferred to the See also:chair of chemistry in University See also:College, See also:London . There he remained till 1855, when he succeeded See also:Sir See also:John See also:Herschel as See also:Master of the See also:Mint, a See also:post he held until his death on the 16th of See also:September 1869 . The onerous duties his See also:work at the Mint entailed severely tried his energies, and in quitting a purely scientific career he was subjected to the cares of See also:official life, for which he was not fitted by temperament . The researches, however, which he conducted between 1861 and 1869 were as brilliant as any of those in which he engaged . See also:Graham was elected a See also:fellow of the Royal Society in 1836, and a corresponding member of the Institute of See also:France in 1847, while See also:Oxford made him a D . C .

L. in 1855 . He took ' eading See also:

part in the See also:foundation of the London Chemical and See also:Cavendish See also:societies, and served as first See also:president of both, is 1 and 1846 . Towards the See also:close of his life the See also:presidency of t Val Society was offered him, but his failing See also:health cause' ;to decline the See also:honour . Graham's work is remarkable at once for finality and for the simplicity of the methods employed 'ining most important results . He communicated papers t `losophical Society of Glasgow before the work of that so( 's recorded in Transactions, but his first published See also:paper, he Absorp- tion of Gases by Liquids," appeared in the An See also:Philosophy for 1826 . The subject with which his name i :ominently associated is the See also:diffusion of gases . In his per on this subject (1829) he thus summarizes the kno' experiment had afforded as to the See also:laws which regulate ovement of gases . " Fruitful as the miscibility of gase. peen in in- teresting speculations, the experimental infor i we possess on the subject amounts to little more than the well-established fact that gases of a different nature when brought into contact do not arrange themselves according to their See also:density, but they spontaneously diffuse through each other so as to remain in an intimate See also:state of mixture for any length of See also:time." For the fissured See also:jar of J . W . See also:Dobereiner he substituted a See also:glass See also:tube closed by a plug of See also:plaster of See also:Paris, and with this See also:simple appliance he developed the See also:law now known by his name " that the diffusion See also:rate of gases is inversely as the square See also:root of their density." (See DIFFUSION.) He further studied the passage of gases by transpiration through See also:fine tubes, and by effusion through a See also:minute hole in a See also:platinum disk, and was enabled to show that See also:gas may enter a vacuum in three different ways: (1) by the molecular See also:movement of diffusion, in virtue of which a gas penetrates through the pores of a disk of compressed See also:graphite; (2) by effusion through an orifice of sensible dimensions in a platinum disk the relative times of the effusion of gases in See also:mass being similar to those of the molecular diffusion, although a gas is usually carried by the former See also:kind of impulse with a velocity many thousand times as See also:great as is demonstrable by the latter; and (3) by the See also:peculiar rate of passage due to transpiration through fine tubes, in which the ratios appear to be in See also:direct relation with no other known See also:property of the same gases—thus See also:hydrogen has exactly See also:double the transpiration rate of See also:nitrogen,'the relation of those gases as to density being as 1 :14 . He subsequently examined the passage of gases through septa or partitions of indiarubber, unglazed earthenware and plates of metals, such as See also:palladium, and proved that gases pass through these septa neither by diffusion nor effusion nor by transpiration, but in virtue of a selective absorption which the septa appear to exert on the gases in contact with them . By this means (" See also:atmolysis ") he was enabled partially to See also:separate See also:oxygen from See also:air .

His See also:

early work on the movements of gases led him to examine the spontaneous movements of liquids, and as a result of the experiments he divided bodies into two classes—crystalloids, such as See also:common See also:salt, and colloids, of which See also:gum-arabic is a type —the former having high and the latter See also:low diffusibility . He also proved that the See also:process of liquid diffusion causes partial decomposition of certain chemical compounds, the See also:potassium sulphate, for instance, being separated from the See also:aluminium sulphate in See also:alum by the higher diffusibility of the former salt . He also extended his work on the transpiration of gases to liquids, adopting the method of manipulation devised by J . L . M . Poiseuille . He found that dilution with See also:water does not effect proportionate alteration in the transpiration velocities of different liquids, and a certain determinable degree of dilution retards the transpiration velocity . With regard to Graham's more purely chemical work, in 1833 he showed that phosphoric anhydride and water See also:form three distinct acids,- and he thus established the existence of polybasic acids, in each of which one or more equivalents of hydrogen are replaceable by certain metals (see See also:Anna) . In 1835 he published the results of an examination of the properties of water of See also:crystallization as a constituent of salts . Not the least interesting part of this inquiry was the See also:discovery of certain definite salts with See also:alcohol analogous to hydrates, to which the name of alcoholates was given . A brief paper entitled " Speculative Ideas on the Constitution of See also:Matter " (1863) possesses See also:special See also:interest in connexion with work done since his death, because in it he ex-pressed the view that the various kinds of matter now recognized as different elementary substances may possess one and the same ultimate or atomic See also:molecule in different conditions of movement . Graham's Elements of Chemistry, first published in 1833, went through. several See also:editions, and appeared also in See also:German, remodelled, under J .

See also:

Otto's direction . His Chemical and See also:Physical Researches were collected by Dr See also:James See also:Young and Dr See also:Angus See also:Smith, and 'printed " for presentation only " at Edinburgh in 1876, Dr Smith contributing to the See also:volume a valuable See also:preface and See also:analysis of its contents . See also T . E .

End of Article: THOMAS GRAHAM (1805-1869)
[back]
SYLVESTER GRAHAM (1794-1851)
[next]
JAMES GRAHAME

Additional information and Comments

There are no comments yet for this article.
» Add information or comments to this article.
Please link directly to this article:
Highlight the code below, right click and select "copy." Paste it into a website, email, or other HTML document.