Online Encyclopedia

GREENOCKITE

Online Encyclopedia
Originally appearing in Volume V12, Page 549 of the 1911 Encyclopedia Britannica.
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GREENOCKITE  , a rare

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mineral composed of cadmium sulphide, CdS, occurring as small, brilliant, honey-yellow crystals or as a canary-yellow powder . Crystals are hexagonal with
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hemimorphic development, being differently terminated at the two ends . The faces of the hexagonal prism and of the numerous hexagonal pyramids are deeply striated horizontally . The crystals are translucent to transparent, and have an adamantine to resinous lustre; hardness 3-31; specific gravity 4.9 . Crystals have been found only in Scotland, at one or two places in the neighbourhood of
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Glasgow, where they occur singly on
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prehnite in the amygdaloidal cavities of basaltic igneous rocks—a rather unusual mode of occurrence for a metallic sulphide . The first, and largest crystal (about 1 in. across) was found, about the
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year 181o, in the dolerite
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quarry at Bowling in Dumbartonshire, but this was thought to be blende . A larger number of crystals, but of smaller
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size, were found in 184o during the cutting of the Bishopton tunnel on the Glasgow &
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Greenock railway; they were detected by Lord Greenock, afterwards the and
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earl of Cathcart, after whom the mineral was named . A third locality is the Boyleston quarry near
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Barrhead . At all other localities—Przibram in Bohemia, Laurion in
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Greece,
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Joplin in
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Missouri, &c . —the mineral is represented only as a powder dusted over the
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surface of
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zinc minerals, especially blende and
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calamine, which contain a small amount of cadmium replacing zinc . Isomorphous with greenockite is the hexagonal zinc sulphide (ZnS) known as wurtzite . Both minerals have been prepared artificially, and are not uncommon as
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furnace products .

Previous to the

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recent
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discovery in Sardinia of cadmium
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oxide as small octahedral crystals, greenockite was the only known mineral containing cadmium as an essential constituent . (L . J . S.) .

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