Online Encyclopedia

GROUP III

Online Encyclopedia
Originally appearing in Volume V21, Page 598 of the 1911 Encyclopedia Britannica.
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GROUP III  . Sulphides.—Some of the members of this
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group are liable to contain
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free
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sulphur, and some may give up this element to the metallic bases of other pigments . Thus cadmium yellow blackens
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emerald green, producing copper sulphide . Another pigment of this group,
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vermilion, is prone to a molecular change whereby the red form passes into the black variety . This change, frequent in
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water-colour drawings, is scarcely observable in
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works painted in oil . The sulphides comprise cadmium yellow (CdS), king's yellow (As2S2),
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realgar (As2S,), antimony, red (Sb2S3) and vermilion (HgS) . It is convenient to give places in the same group to the various kinds of
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ultramarine, blue, green, red,
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violet and native, for in all of them a
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part of the sulphur
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present occurs in the form of a sulphide . It may be stated that the sulphides of arsenic and antimony just named are dangerous and changeable pigments not suited for
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artistic
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painting .

End of Article: GROUP III
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