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See also:GUM (Fr. gomme, See also:Lat. gommi, Gr. Kµµ1, possibly a Coptic word; distinguish " gum," the fleshy covering of the See also:base of a tooth, in O. Eng. gbma, See also:palate, cf. Ger. Gaumen, roof of the mouth; the ultimate origin is probably the See also:root gha, to open wide, seen in Gr. xaivety, to gape, cf . "yawn"), the generic name given to a See also:group of amorphous See also:carbo-hydrates of the See also:general See also:formula (C5H1005),,, which exist in the juices of almost all See also:plants, and also occur as exudations from stems, branches and fruits of plants . They are entirely soluble or soften in See also:water, and See also:form with it a thick glutinous liquid or See also:mucilage . They yield mucic and oxalic acids when treated with nitric See also:acid . In'structure the gums are quite amorphous, being neither organized like See also:starch nor crystallized like See also:sugar . They are odourless and tasteless, and some yield clear aqueous solutions—the real gums—while others swell up and will not percolate See also:filter See also:paper—the See also:vegetable mucilages . The acacias and the See also:Rosaceae yield their gums most abundantly when sickly and in an abnormalstate, caused by a fulness of See also:sap in the See also:young tissues, whereby the new cells are softened and finally disorganized; the cavities thus formed fill with liquid, which exudes, dries and constitutes the See also:gum . Gum arabic may be taken as the type of the gums entirely soluble in water . Another variety, obtained from the Prosopis dulcis, a leguminous plant, is called gum See also:mesquite or mezquite; it comes from western See also:Texas and See also:Mexico, and is yellowish in See also:colour, very brittle and quite soluble in water . Gum arabic occurs in pieces of varying See also:size, and some kinds are full of See also:minute cracks . The specific gravity of See also:Turkey picked gum (the purest variety) is 1.487, or, when dried at too° C., 1.525 . It is soluble in water to an indefinite extent; boiled with dilute sulphuric acid it is converted into the sugar galactose .
Moderately strong nitric acid changes it into mucic, saccharic, tartaric and oxalic acids
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Under the See also:influence of yeast it does not enter into the alcoholic See also:fermentation, but M
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See also:Berthelot, by digesting with See also:chalk and See also:cheese, obtained from it 12 % of its See also:weight of See also:alcohol, along with See also:calcium lactate, but no appreciable quantity of sugar
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Gum arabic may be regarded as a See also:potassium and calcium See also:salt of gummic or arabic acid
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See also:Graham (Chemical and See also:Physical Researches) recommended See also:dialysis as the best mode of preparing gummic acid, and stated that the See also:power of gum to penetrate the See also:parchment septum is 400 times less than that of See also:sodium chloride, and, further, that by mixing the gum with substances of the crystalloid class the diffusibility is lowered, and may be even reduced to nothing
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The mucilage must be acidulated with hydrochloric acid before dialysing, to set See also:free the gummic acid
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By adding alcohol to the See also:solution, the acid is precipitated as a See also: When solutions of gum arabic and See also:gelatin are mixed, oily drops of a See also:compound of the two are precipitated, which on See also:standing form a nearly colourless jelly, melting at 25° C., or by the See also:heat of the See also:hand . This substance can be washed without decomposition . Gummic acid is soluble in water; when well dried at See also:Ioo° C., it becomes transformed into metagummic acid, which is insoluble, but swells up in water like gum tragacanth . Gum arabic, when heated to 15o' C. with two parts of acetic anhydride, swells up to a mass which, when washed with boiling water, and then with alcohol, gives a white amorphous insoluble See also:powder called acetyl arabin C6H8(C2H30)205 . It is saponified by alkalies, with See also:reproduction of soluble gum . Gum arabic is not precipitated from solution by See also:alum, stannous chloride, sulphate or nitrate of See also:copper, or neutral See also:lead acetate; with basic lead acetate it forms a white jelly, with ferric chloride it yields a stiff clear gelatinoid mass, and its solutions are also precipitated by See also:borax . The finer varieties are used as an emollient and demulcent in See also:medicine, and in the manufacture of See also:confectionery; the commoner qualities are used as an adhesive See also:paste, for giving lustre to See also:crape, See also:silk, &c., in See also:cloth See also:finishing to stiffen the See also:fibres, and in See also:calico-See also:printing . For labels, &c., it is usual to mix sugar or See also:glycerin with it to prevent it from cracking . Gum See also:senegal, a variety of gum arabic produced by See also:Acacia Verek, occurs in pieces generally rounded, of the size of a See also:pigeon's See also:egg, and of a reddish or yellow colour, and specific gravity 1.436 . It gives with water a somewhat stronger mucilage than gum arabic, from which it is distinguished by its clear interior, fewer cracks and greater toughness . It is imported from the See also:river See also:Gambia, and from Senegal and See also:Bathurst . Chagual gum, a variety brought from See also:Santiago, See also:Chile, resembles gum senegal . About 75% is soluble in water . Its solution is not thickened by borax, and is precipitated by neutral lead acetate; and dilute sulphuric acid converts it into d-See also:glucose . Gum tragacanth, familiarly called gum See also:dragon, exudes from the See also:stem, the See also:lower See also:part especially, of the various See also:species of Astragalus, especially A. gummifer, and is collected in See also:Asia See also:Minor, the See also:chief See also:port of shipment being See also:Smyrna . Formerly only what exuded spontaneously was gathered; this was often of a brownish colour; but now the flow of the gum is aided by incisions cut near the See also:root, and the product is the See also:fine, white, flaky variety so much valued in See also:commerce . The chief flow of gum takes See also:place during the See also:night, and hot and dry See also:weather is the most favourable for its See also:production . In colour gum tragacanth is of a dull white; it occurs in horny, flexible and tough, thin, See also:twisted flakes, translucent, and with See also:peculiar wavy lines on the See also:surface . When dried at temperatures under too° C. it loses about 14% of water, and is then easily powdered . Its specific gravity is 1.384 . With water it swells by absorption, and 716 with even fifty times its weight of that liquid forms a thick mucilage . Part of it only is soluble in water, and that resembles gummic acid in being precipitated by alcohol and ammonium oxalate, but differs from it in giving a precipitate with neutral lead acetate and none with borax . The insoluble part of the gum is a calcium salt of bassorin (C12H200,o), which is devoid of See also:taste and See also:smell, forms a gelatinoid mass with water, but by continued boiling is rendered soluble . Gum tragacanth is used in calico-printing as a thickener of See also:colours and mordants; in medicine as a demulcent and vehicle for insoluble powders, and as an excipient in pills; and for setting and mending beetles and other See also:insect specimens . It is medicinally See also:superior to gum acacia, as it does not undergo acetous fermentation . The best pharmacopeial preparation is the Mucilago Tragacanthae . The compound powder is a useless preparation, as the starch it contains is very liable to ferment . Gum kuteera resembles in See also:appearance gum tragacanth, for which the See also:attempt has occasionally been made to substitute it . It is said to be the product of Sterculia urens, a plant of the natural See also:order Sterculiaceae . See also:Cherry See also:tree gum is an exudation from trees of the genera Prunus and Cerasus . It occurs in shiny reddish lumps, resembling the commoner kinds of gum arabic . With water, in which it is only partially soluble, it forms a thick mucilage . Sulphuric acid converts it into l-arabinose; and nitric acid oxidizes it to oxalic acid (without the intermediate formation of mucic acid as in the See also:case of gum arabic) . Gum of Bassora, from Bassora or Bussorah in Asia, is some-times imported into the See also:London See also:market under the name of the hog tragacanth . It is insipid, crackles between the See also:teeth, occurs in variable-sized pieces, is tough, of a yellowish-white colour, and opaque, and has properties similar to gum tragacanth . Its specific gravity is 1.36 . It contains only 1% of soluble gum or arabin . Under the name of Caramania gum it is mixed with inferior kinds of gum tragacanth before exportation . Mucilage.—Very many seeds, roots, &c., when infused in boiling water, yield mucilages which, for the most part, consist of bassorin . See also:Linseed, See also:quince See also:seed and marshmallow root yield it in large quantity . In their reactions the different kinds of mucilage See also:present See also:differences; e.g. quince seed yields only oxalic acid when treated with nitric acid, and with a solution of See also:iodine in See also:zinc iodide it gives, after some See also:time, a beautiful red tint . Linseed does not give the latter reaction; by treatment with boiling nitric acid it yields mucic and oxalic acids . Gum Resins.—This See also:term is applied to the inspissated milky juices of certain plants. which consist of gum soluble in water, See also:resin and essential oil soluble in alcohol, other vegetable See also:matter and a small amount of See also:mineral matter . They are generally opaque and solid, and often brittle . When finely powdered and rubbed down with water they form emulsions, the undissolved resin being suspended in the gum solution . Their chief uses are in medicine . Examples are See also:ammoniacum, asafetida, See also:bdellium, See also:euphorbium, See also:gamboge, See also:myrrh, sagapanum and See also:scammony . |
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