GYPSUM
, a See also:common See also:mineral consisting of hydrous See also:calcium sulphate, named from the Gr. yb 'os, a word used by See also:Theophrastus to denote not only the raw mineral but also the See also:pro-duct of its calcination, which was employed in See also:ancient times, as it still is, as a See also:plaster
.
When crystallized, gypsum is often called selenite, the cre rIYLT c of Dioscorides, so named from aeX$v1i, " the See also:- MOON (a common Teutonic word, cf. Ger. Mond, Du. maan, Dan. maane, &c., and cognate with such Indo-Germanic forms as Gr. µlip, Sans. ma's, Irish mi, &c.; Lat. uses luna, i.e. lucna, the shining one, lucere, to shine, for the moon, but preserves the word i
- MOON, SIR RICHARD, 1ST BARONET (1814-1899)
moon," probably in allusion to the soft moon-like reflection of See also:light from some of its faces, or, according to a See also:legend,. because it is found at See also:night when the moon is on the increase
.
The granular, See also:marble-like gypsum is termed See also:alabaster (q.v.)
.
Gypsum crystallizes in the See also:monoclinic See also:system, the See also:habit of the crystals being usually either prismatic or See also:tabular; in the latter See also:case the broad planes are parallel to the faces of the clinopinacoid
.
The crystals may become lenticular by curvature of certain faces
.
In the characteristic type represented in fig
.
1, f represents the See also:prism, 1 the hemi-See also:pyramid and P the clinopinacoid
.
Twins are common, as in
fig
.
2, forming in some cases arrow-headed and See also:swallow-tailed crystals
.
Cleavage is perfect parallel to the clinopinacoid, yielding thin plates, often See also:diamond-shaped, with pearly lustre; these flakes are usually flexible, but may be brittle, as in the gypsum of Montmartre
.
Two other cleavages are recognized, but they are imperfect
.
Crystals of gypsum, when occurring
in See also:clay, may enclose much muddy See also:matter; in other cases a large proportion of See also:sand may be mechanically entangled in the crystals without serious disturbance of See also:form; whilst certain crystals occasionally enclose cavities with liquid and an See also:air-bubble
.
Gypsum not infrequently becomes fibrous
.
This variety occurs in See also:veins, often See also:running through gypseous marls, with the See also:fibres disposed at right angles to the direction of the vein
.
Such gypsum when cut and polished has a pearly opalescence, or satiny sheen, whence it is called satin-spar (q.v.)
.
Gypsum is so soft as to be scratched even by the See also:finger-See also:nail (H= 5 to 2)
.
Its specific gravity is about 2.3
.
The mineral is slightly soluble in See also:water, one See also:part of gypsum being soluble, according to G
.
K
.
See also:Cameron, in 372 parts of pure water at 26' C
.
See also:Waters percolating through gypseous strata, like the See also:Keuper marls, dissolve the calcium sulphate and thus become permanently hard or " selenitic." Such water has See also:special value for See also:brewing See also:pale See also:ale, and the water used by the See also:Burton breweries is of this See also:character; hence the artificial dissolving of gypsum in water for brewing purposes is known as " burtonization." Deposits of gypsum are formed in boilers using selenitic water
.
Pure gypsum is colourless or See also:- WHITE
- WHITE, ANDREW DICKSON (1832– )
- WHITE, GILBERT (1720–1793)
- WHITE, HENRY KIRKE (1785-1806)
- WHITE, HUGH LAWSON (1773-1840)
- WHITE, JOSEPH BLANCO (1775-1841)
- WHITE, RICHARD GRANT (1822-1885)
- WHITE, ROBERT (1645-1704)
- WHITE, SIR GEORGE STUART (1835– )
- WHITE, SIR THOMAS (1492-1567)
- WHITE, SIR WILLIAM ARTHUR (1824--1891)
- WHITE, SIR WILLIAM HENRY (1845– )
- WHITE, THOMAS (1628-1698)
- WHITE, THOMAS (c. 1550-1624)
white, but it is often tinted, especially in the alabaster variety, See also:grey, yellow or See also:pink
.
Gypsum crystallizes with two molecules of water, equal to about 21 % by
See also:weight, and consequently has the See also:formula CaSO4•2H20
.
By exposure to strong See also:heat all the water may be expelled, and the substance then has the See also:composition of See also:anhydrite (q.v.)
.
When the calcination, however, is conducted at such a temperature that only about 75% of the water is lost, it yields a white pulverulent substance, known as " plaster of See also:Paris," which may readily be caused to recombine with water, forming a hard See also:cement
.
The gypsum quarries of Montmartre, in the See also:north of Paris, were worked in See also:Tertiary strata, See also:rich in fossils
.
Gypsum is largely quarried in See also:England for See also:conversion into plaster of Paris, whence it is sometimes known as " plaster See also:- STONE
- STONE (0. Eng. shin; the word is common to Teutonic languages, cf. Ger. Stein, Du. steen, Dan. and Swed. sten; the root is also seen in Gr. aria, pebble)
- STONE, CHARLES POMEROY (1824-1887)
- STONE, EDWARD JAMES (1831-1897)
- STONE, FRANK (1800-1859)
- STONE, GEORGE (1708—1764)
- STONE, LUCY [BLACKWELL] (1818-1893)
- STONE, MARCUS (184o— )
- STONE, NICHOLAS (1586-1647)
stone," and since much is sent to the See also:Staffordshire See also:potteries for making moulds it is also termed " See also:potter's stone." The See also:chief workings are in the Keuper marls near See also:Newark in See also:Nottinghamshire, Fauld in Staffordshire and Chellaston in See also:Derbyshire
.
It is also worked in See also:Permian beds in See also:Cumberland and See also:Westmorland, and in Purbeck strata near See also:Battle in See also:Sussex
.
Gypsum frequently occurs in association with See also:rock-See also:salt, having been deposited in shallow basins of salt water
.
Much of the calcium in See also:sea-water exists as sulphate; and on evaporation of a drop of sea-water under the See also:microscope this sulphate is deposited as acicular crystals of gypsum
.
In salt-lagoons the deposition of the gypsum is probably effected in most cases by means of micro-organisms
.
Waters containing sulphuretted See also:hydrogen, on exposure to the air in the presence of See also:limestone, may yield gypsum by the formation of sulphuric See also:acid and its interaction with the calcium carbonate
.
In volcanic districts gypsum is produced by the See also:action of sulphuric acid, resulting from the oxidation of sulphurous vapours, on See also:lime-bearing minerals, like See also:labradorite and See also:augite, in the volcanic rocks: hence gypsum is common around solfataras
.
Again, by the oxidation of See also:iron-See also:pyrites and the action of the resulting sulphuric acid on limestone or on shells, gypsum may be formed; whence its origin in most See also:clays
.
Gypsum is also formed in some cases by the hydration of anhydrite, the See also:change being accompanied by an increase of See also:volume to the extent of about 6o%
.
Conversely gypsum may, under certain conditions, be dehydrated or reduced to anhydrite
.
Some of the largest known crystals of selenite have been found in See also:southern See also:Utah, where they occur in huge geodes, or crystal-lined cavities, in deposits from the old salt-lakes
.
See also:Fine crystals, sometimes curiously See also:bent, occur in the Permian rocks of See also:Friedrichroda, near See also:Gotha, where there is a grotto called the Marienglashohle, See also:close to Rheinhardsbrunn
.
Many of the best localities for selenite are in the New Red See also:Sandstone formation (Trias and Permian), notably the salt-mines of See also:- HALL
- HALL (generally known as SCHWABISCH-HALL, tc distinguish it from the small town of Hall in Tirol and Bad-Hall, a health resort in Upper Austria)
- HALL (O.E. heall, a common Teutonic word, cf. Ger. Halle)
- HALL, BASIL (1788-1844)
- HALL, CARL CHRISTIAN (1812–1888)
- HALL, CHARLES FRANCIS (1821-1871)
- HALL, CHRISTOPHER NEWMAN (1816—19oz)
- HALL, EDWARD (c. 1498-1547)
- HALL, FITZEDWARD (1825-1901)
- HALL, ISAAC HOLLISTER (1837-1896)
- HALL, JAMES (1793–1868)
- HALL, JAMES (1811–1898)
- HALL, JOSEPH (1574-1656)
- HALL, MARSHALL (1790-1857)
- HALL, ROBERT (1764-1831)
- HALL, SAMUEL CARTER (5800-5889)
- HALL, SIR JAMES (1761-1832)
- HALL, WILLIAM EDWARD (1835-1894)
Hall and Hallein, near See also:Salzburg, and of Bex in See also:Switzerland
.
Excellent crystals, usually of a brownish See also:colour arranged in See also:groups, are often found in the brine-See also:chambers and the launders used in salt-See also:works
.
Selenite also occurs in fine crystals in the See also:sulphur-bearing marls of See also:Girgenti and other Sicilian localities; whilst in See also:Britain very bold crystals are yielded by the Kimeridge clay of Shotover See also:- HILL
- HILL (0. Eng. hyll; cf. Low Ger. hull, Mid. Dutch hul, allied to Lat. celsus, high, collis, hill, &c.)
- HILL, A
- HILL, AARON (1685-175o)
- HILL, AMBROSE POWELL
- HILL, DANIEL HARVEY (1821-1889)
- HILL, DAVID BENNETT (1843–1910)
- HILL, GEORGE BIRKBECK NORMAN (1835-1903)
- HILL, JAMES J
- HILL, JOHN (c. 1716-1775)
- HILL, MATTHEW DAVENPORT (1792-1872)
- HILL, OCTAVIA (1838– )
- HILL, ROWLAND (1744–1833)
- HILL, SIR ROWLAND (1795-1879)
Hill near See also:- OXFORD
- OXFORD, EARLS OF
- OXFORD, EDWARD DE VERE, 17TH EARL
- OXFORD, JOHN DE VERE, 13TH EARL OF (1443-1513)
- OXFORD, PROVISIONS OF
- OXFORD, ROBERT DE VERE, 9TH EARL OF (1362-1392)
- OXFORD, ROBERT HARLEY, 1ST
Oxford
.
See also:Twisted crystals and rosettes of gypsum found in the See also:Mammoth See also:Cave, See also:Kentucky, have been called " oulopholites " (ovXos, " woolly "; qSwXe6s, " cave ")
.
In addition to the use of gypsum in cement-making, the mineral finds application as an agricultural See also:agent in dressing See also:land, and it has also been used in the manufacture of See also:porcelain and See also:glass
.
Formerly it was employed, in the form of thin cleavage-plates, for See also:glazing windows, and seems to have been, with See also:mica, called lapis specularis
.
It is still known in See also:Germany as Marienglas and Fraueneis
.
Delicate cleavage-plates of gypsum are used in microscopic petrography for the determination of certain See also:optical constants in the rock-forming minerals
.
(F
.
W
.
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