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HELIUM (from Gr. i)Xcor, the sun)

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Originally appearing in Volume V13, Page 234 of the 1911 Encyclopedia Britannica.
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HELIUM (from Gr. i)Xcor, the See also:sun)  , a gaseous chemical See also:element, the See also:modern See also:discovery of which followed closely on that of See also:argon (q.v.) . The investigations of See also:Lord See also:Rayleigh and See also:Sir See also:William See also:Ramsay had shown that indifference to chemical reagents did not sufficiently characterize an unknown See also:gas as See also:nitrogen, and it became necessary to reinvestigate other cases of the occurrence of "nitrogen" in nature . H . Miers See also:drew Ramsay's See also:attention to the See also:work of W F . See also:Hillebrand, who had noticed, in examining the See also:mineral uraninite, that an inert gas was evolved when the mineral was decomposed with See also:acid . Ramsay, repeating these experiments, found that the inert gas emitted refused to oxidize when sparked with See also:oxygen, and on examining it spectroscopically he saw that the spectrum was not that of argon, but was characterized by a See also:bright yellow See also:line near to, but not identical with, the D line of See also:sodium . This was after-wards identified with the D3 line of the See also:solar See also:chromosphere, observed in 1868 by Sir J . See also:Norman See also:Lockyer, and ascribed by him to a hypothetical element See also:helium . This name was adopted for the new gas . Helium is relatively abundant in many minerals, all of which are radioactive, and contain See also:uranium or See also:thorium as important constituents . (For the significance of this fact see RADIOAcT1~1TY.) The richest known source is See also:thorianite, which consists mainly of thorium See also:oxide, and contains 9.5 cc. of helium per See also:gram . See also:Monazite, a phosphate of thorium and other rare earths, contains on the See also:average about r cc. per gram .

Cleveite, samarskite and fergusonite contain a little more than monazite . The gas also occurs in See also:

minute quantities in the See also:common minerals of the See also:earth's crust . In this See also:case too it is associated with radio-active See also:matter, which is almost ubiquitous . In two cases, how-ever, it has been found in the See also:absence of appreciable quantities of uranium and thorium compounds, namely in See also:beryl, and in sylvine (See also:potassium chloride) . Helium is contained almost universally in the gases which bubble up with the See also:water of thermal springs . The proportion varies greatly . In the hot springs of See also:Bath it amounts to about one-thousandth See also:part of the gas evolved . Much larger percentages have been recorded in some See also:French springs (Compt. rend., 1906, 143, p . 795, and 146, p . 435), and considerable quantities occur in some natural gas (Journ . Amer . Chem .

See also:

Soc . 29, p . 1524) . R . J . See also:Strutt has suggested that helium in hot springs may be derived from the disintegration of common rocks at See also:great depths . Helium is See also:present in the See also:atmosphere, of which it constitutes four parts in a million . It is conspicuous by its absorption spectrum in many of the See also:white stars . Certain stars and pebulae show a bright line helium spectrum . Much the best See also:practical source of helium is thorianite, a mineral imported from See also:Ceylon for the manufacture of thoria . It dissolves readily in strong nitric acid, and the helium contained is thus liberated . The gas contains a certain amount of See also:hydrogen and oxides of See also:carbon, also traces of nitrogen .

In See also:

order to get rid of hydrogen, some oxygen is added to the helium, and the mixture exploded by an electric spark . All remaining impurities, including the excess of oxygen, can then be taken out of the gas by Sir See also:James See also:Dewar's ingenious method of absorption with See also:charcoal cooled in liquid See also:air . Helium alone refuses to be absorbed, and it can be pumped off from the charcoal in a See also:state of See also:absolute purity . In the absence of liquid air the helium must he purified by the methods employed for argon (q.v.) . If thorianite cannot be obtained, monazite, which is more abundant, may be utilized . A part of the helium contained in minerals can be extracted by See also:heat or by grinding (J . A . See also:Gray, Proc . See also:Roy . Soc., 1909, 82A, p . 301) . Properties.--All attempts to make helium enter into See also:stable chemical See also:union have hitherto proved unsuccessful .

Phoenix-squares

The gas is in all See also:

probability only mechanically retained in the minerals in which it is found . Jacquerod and See also:Perrot have found that See also:quartz-See also:glass is freely permeable to helium below a red-heat (Comps. rend., 1904, 139, p . 789) . The effect is even perceptible at a temperature as See also:low as 220 C . Hydrogen, and, in a much less degree, oxygen and nitrogen, will also permeate See also:silica, but only at higher temperatures . They have made this observation the basis of a practical method of separating helium from the other inert gases . M . Travers has suggested that it may explain the liberation of helium from minerals by heat, the gas being enabled to permeate the siliceous materials in which it is enclosed . Thorianite, however, contains no silica, and until it is shown that metallic oxides behave in the same way this explanation must be accepted with reserve . The See also:density of helium has been determined by Ramsay and Travers as 1.98 . Its ratio of specific heats has very nearly the ideal value 1.666, appropriate to a monatomic See also:molecule . The accepted atomic See also:weight is accordingly See also:double the density, i.e.approximately four times that of hydrogen .

The refractivity of helium is 0.1238 (air= 1) . The solubility in water is the lowest known, being, at 18.2°, only •0093 vols. per unit See also:

volume of water . The viscosity is .96 (air= I) . The spectrum of helium as observed in a See also:discharge See also:tube is distinguished by a moderate number of brilliant lines, distributed over the whole visual spectrum . The following are the approximate See also:wave-lengths of the most brilliant lines: Red . . .. 7066 Red .. . . 6678 Yellow . . . 5876 See also:Green . . .

4922 See also:

Blue . . . . 4472 See also:Violet .. . . . 4026 When the discharge passes through helium at a pressure of several millimetres, the yellow line 5876 is prominent . At See also:lower pressures the green line 4922 becomes more conspicuous . At atmospheric pressure the discharge is able to pass through a far greater distance in helium than in the common gases . M . Travers, G . Senter and A . Jacquerod (Phil . Trans .

A . 1903, 200, p . 105) carefully examined the behavour of a See also:

constant volume gas thermometer filled with helium . For the pressure coefficient per degree, between o° and See also:roe C., they give the value •00366255, when the initial pressure is 700 mm . This value is indistinguishable from that which they find for hydrogen . Thus at high temperatures a helium thermometer is of no See also:special See also:advantage . At low temperatures, on the other See also:hand, they find, using an initial pressure of r000 mm., that the temperatures on the helium See also:scale are measurably higher than on the hydrogen scale, owing to the more perfectly gaseous See also:condition of helium . This difference amounts to about i1b at the temperature of liquid oxygen, and about *° at that of liquid hydrogen . The liquefaction of helium was achieved by H . Kamerlingh Onnes at See also:Leiden in 1908 . According to him its boiling point is 4.3° abs . (–268.7° C.), the density of the liquid 0.154, the See also:critical temperature 5° abs., and the critical pressure 2.3 atmospheres (Communications from the See also:Physical Laboratory at Leiden, No. ro8; see also LIQUID GASES) .

End of Article: HELIUM (from Gr. i)Xcor, the sun)
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