Online Encyclopedia

Search over 40,000 articles from the original, classic Encyclopedia Britannica, 11th Edition.

HIPPURIC ACID (Gr. iazros, horse, ovp...

Online Encyclopedia
Originally appearing in Volume V13, Page 523 of the 1911 Encyclopedia Britannica.
Spread the word: del.icio.us del.icio.us it!

HIPPURIC See also:

ACID (Gr. iazros, See also:horse, ovpov, urine)  , benzoyl glycocoll or benzoyl amidoacetic See also:acid, C9H9NO3 or C6H5CO NH•See also:CH2See also:CO2H, an organic acid found in the urine of horses and other herbivorae . It is excreted when many aromatic compounds, such as benzoic acid and See also:toluene, are taken internally . J. v . See also:Liebig in 1829 showed that it differed from benzoic acid, and in 1839 determined its constitution, while in 18J3 V . Dessaignes (See also:Ann . 87, p . 325) synthesized it by acting with benzoyl chloride on See also:zinc glycocollide . It is also formed by See also:heating benzoic anhydride with glycocoll (Th . See also:Curtius, Ber., 1884, 17, p . 1662), and by heating benzamide with monochloracetic acid . It crystallizes in rhombic prisms which are readily soluble in hot See also:water, melt at 187° C. and decompose at about 2400 C . It is readily hydrolysed by hot See also:caustic alkalis to benzoic acid and glycocoll .

Nitrous acid converts it into benzoyl glycollic acid, See also:

C6H,CO.O•CH2•CO2H . Its See also:ethyl ester reacts with See also:hydrazine to See also:form hippuryl hydrazine, C6H5CO•NH•CH2•CO•NH•See also:NH2, which was used by Curtius for the preparation of See also:azoimide (q.v.) .

End of Article: HIPPURIC ACID (Gr. iazros, horse, ovpov, urine)
[back]
HIPPOPOTAMUS (" river-horse," Gr. lames, horse and ...
[next]
HIPURNIAS

Additional information and Comments

There are no comments yet for this article.
» Add information or comments to this article.
Please link directly to this article:
Highlight the code below, right click and select "copy." Paste it into a website, email, or other HTML document.