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See also:HYDRAZINE (DIAMIDOGEN), N2H4 or H2 N•See also:NH2, a See also:compound of See also:hydrogen and See also:nitrogen, first prepared by Th . See also:Curtius in 1887 from diazo-acetic ester, N2CH•CO2C2H5 . This ester, which is obtained by the See also:action of See also:potassium nitrate on the hydrochloride of amidoacetic ester, yields on See also:hydrolysis with hot concentrated potassium hydroxide an See also:acid, which Curtius regarded as CIH3N6(See also:CO2H)a, but which A . Hantzsch and 0 . Silberrad (Ber., 190o, 33, p . 58) showed to be C2H2N4(CO2H)2, bisdiazoacetic acid . On digestion of its warm aqueous See also:solution with warm dilute sulphuric acid, See also:hydrazine sulphate and oxalic acid are obtained . C . A . Lobry de Bruyn (Ber., 1895, 28, p . 3085) prepared See also:free hydrazine by dissolving its hydrochloride in methyl See also:alcohol and adding See also:sodium methylate; sodium chloride was precipitated and the residual liquid afterwards fractionated under reduced pressure . |
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