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atomic weight x-oo8 HYDROGEN [symbol ...

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Originally appearing in Volume V14, Page 114 of the 1911 Encyclopedia Britannica.
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atomic See also:

weight x-oo8 See also:HYDROGEN [See also:symbol H (0=16)]  , one of the chemical elements . Its name is derived from Gr. uSwp, See also:water, and ryevvaew, to produce, in allusion to the fact that water is produced when the See also:gas See also:burns in See also:air . See also:Hydrogen appears to have been recognized by See also:Paracelsus in the 16th See also:century; the combustibility of the gas was noticed by Turquet de See also:Mayenne in the 17th century, whilst in 1700 N . See also:Lemery showed that a mixture of hydrogen and air detonated on the application of a See also:light . The first definite experiments concerning the nature of hydrogen were made in 1766 by H . See also:Cavendish, who showed that it was formed when various metals were acted upon by dilute sulphuric or hydrochloric acids . Cavendish called it " in-flammable air," and for some See also:time it was confused with other inflammable gases, all of which were supposed to contain the same inflammable principle, " phlogiston," in See also:combination with varying amounts of other substances . In 1781 Cavendish showed that water was the only substance produced when hydrogen was burned in air or See also:oxygen, it having been thought previously to this date that other substances were formed during the reaction, A . L . See also:Lavoisier making many experiments with the See also:object of finding an See also:acid among the products of See also:combustion . Hydrogen is found in the See also:free See also:state in some volcanic gases, in fumaroles, in the carnallite of the See also:Stassfurt potash mines (H . Precht, Ber., 1886, 19, p .

2326), in some meteorites, in certain stars and nebulae, and also in the envelopes of the See also:

sun . In combination it is found as a constituent of water, of the gases from certain See also:mineral springs, in many minerals, and in most See also:animal and See also:vegetable tissues . It may be prepared by the See also:electrolysis of acidulated water, by the decomposition of water by various metals or metallic hydrides, and by the See also:action of many metals on acids or on bases . The See also:alkali metals and alkaline See also:earth metals decompose water at See also:ordinary temperatures; See also:magnesium begins to react above 7o° C., and See also:zinc at a dull red See also:heat . The decomposition of See also:steam by red hot See also:iron has been studied by H . Sainte-Claire Deville (Comptes rendus, 1870, 70, p . 1105) and by H . Debray (ibid., 1879, 88, p . 1341), who found that at about 1500° C. a See also:condition of See also:equilibrium is reached . H . See also:Moissan (See also:Bull. See also:soc. chim., 1902, 27, p . 1141) has shown that See also:potassium hydride decomposes See also:cold water, with See also:evolution of hydrogen, KH+See also:H2O= KOH -•- H2 .

See also:

Calcium hydride or hydrolite, prepared by passing hydrogen over heated calcium, decomposes water similarly, 1 See also:gram giving 1 litre of gas; it has been proposed as a commercial source (Prats Aymerich, Abst . J.C.S., 1907, ii. p . 543), as has also See also:aluminium turnings moistened with potassium See also:cyanide and mercuric chloride, which decomposes water regularly at 70°, I gram giving 1.3 litres of gas (Mauricheau-Beaupre, Comptes rendus, 1908, 147, p . 310) . See also:Strontium hydride behaves similarly . In preparing the gas by the action of metals on acids, dilute sulphuric or hydrochloric acid is taken, and the metals commonly used are zinc or iron . So obtained, it contains many impurities, such as See also:carbon dioxide, See also:nitrogen, oxides of nitrogen, phosphoretted hydrogen, arseniuretted hydrogen, &c., the removal of which is a See also:matter of See also:great difficulty (see E . W . See also:Morley, Amer . Chem . Journ., 189o, 12; p . 460) .

When prepared by the action of metals on bases, zinc or aluminium and See also:

caustic soda or caustic potash are used . Hydrogen may also be obtained by the action of zinc on ammonium salts (the nitrate excepted) (Lorin, Comptes rendus, 1865, 6o, p . 945) and by See also:heating the alkali formates or oxalates with caustic potash or soda, Na2C204+2NaOH = H2+2Na2CO3 . Technically it is prepared by the action of superheated steam on incandescent See also:coke (see F . Hembert and See also:Henry, Comptes rendus, 1885, 1o1, p . 997; A . See also:Naumann and C . Pistor, Ber., 1885, 18, p . 1647), or by the electrolysis of a dilute See also:solution of caustic soda (C . Winssinger, Chem . Zeit., 1898, 22, p . 609; " See also:Die Elektrizitats-Aktiengesellschaft," Zeit. f .

Elektrochem., 1901, 7, p . 857) . In the latter method a 15 % solution of caustic soda is used, and the electrodes are made of iron; the See also:

cell is packed in a wooden See also:box, surrounded with See also:sand, so that the temperature is kept at about 7o° C.; the solution is replenished, when necessary, with distilled water . The purity of the gas obtained is about 97%• Pure hydrogen is a tasteless, colourless and odourless gas of specific gravity 0.06947 (air =1) (See also:Lord See also:Rayleigh, Proc . See also:Roy . Soc., 1893, p . 319) . It may be liquefied, the liquid boiling at -252.68° C. to -252.84°C., and it has also been solidified, the solid melting at—264° C . (J . See also:Dewar, Comptes rendus, 1899, 129, p . 451; Chem . See also:News, 1901, 84, p .

49; see also LIQUID GASES) . The specific heat of gaseous hydrogen (at See also:

constant pressure) is 3.4041 (water =1), and the ratio of the specific heat at constant pressure to the specific heat at constant See also:volume is 1.3852 (W . C . See also:Rontgen, Fogg . See also:Ann., 1873, 148, p . 580) . On the spectrum see See also:SPECTROSCOPY . Hydrogen is only very slightly soluble in water . It diffuses very rapidly through a porous membrane, and through some metals at a red heat (T . See also:Graham, Proc . Roy . Soc., 1867, 15, p .

223; H . Sainte-Claire Deville and L . Troost, Comptes rendus, 1863, 56, p . 977) . See also:

Palladium and some other metals are capable of absorbing large volumes of hydrogen (especially when the See also:metal is used as a See also:cathode in a water electrolysis apparatus) . L . Troost and P . Hautefeuille (Ann. chim. phys., 1874, (5) 2, p . 279) considered that a palladium hydride of See also:composition Pd2H was formed, but the investigations of C . Hoitsema (Zeit. phys . Chem., 1895, 17, p . 1), from the standpoint of the phase See also:rule, do not favour this view, Hoitsema being of the See also:opinion that the occlusion of hydrogen by palladium is a See also:process of continuous absorption .

Hydrogen burns with a See also:

pale See also:blue non-luminous See also:flame, but will not support the combustion of ordinary combustibles . It forms a highly explosive mixture with air or oxygen, especially when in the proportion of two volumes of hydrogen to one volume of oxygen . H . B . See also:Baker (Proc . Chem . Soc., 1902, 18, p . 40) has shown that perfectly dry hydrogen will not unite with perfectly dry oxygen . Hydrogen combines with See also:fluorine, even at very See also:low temperatures, with great violence; it also combines with carbon, at the temperature of the electric arc . The alkali metals when warmed in a current of hydrogen, at about 36o° C., See also:form hydrides of composition RH(R=Na, K, Rb, Cs), (H . Moissan, Bull. soc. chim., 1902, 27, p . 1141); calcium and strontium similarly form hydrides CaH2, SrH2 at a dull red heat (A .

Phoenix-squares

Guntz, Comptes rendus, 1901, 133, p . 1209) . Hydrogen is a very powerful reducing See also:

agent; the gas occluded by palladium being very active in this respect, readily reducing ferric salts to ferrous salts, nitrates to nitrites and See also:ammonia, See also:chlorates to chlorides, &c . For determinations of the volume ratio with which hydrogen and oxygen combine, see J . B . See also:Dumas, Ann. chim. phys., 1843 (3), 8, p 189; O . See also:Erdmann [and R . F . Marchand, ibid. p . 212; E . H . Keiser, Ber., 1887, 20, p .

2323; J . P . See also:

Cooke and T . W . See also:Richards, Amer . Chem . Journ., 1888, 10, p . 191; Lord Rayleigh, Chem . News, 1889, 59, p . 147; E . W . Morley, Zeit. phys .

Chem., 189o, 20, p . 417; and S . A . Leduc, Comptes rendus, 1899, 128, p . 1158 . Hydrogen combines with oxygen to form two definite compounds, namely, water (q.v.), H2O, and hydrogen peroxide, 11202, whilst the existence of a third See also:

oxide, ozonic acid, has been indicated . Hydrogen peroxide, H2O2, was discovered by L . J . See also:Thenard in 1818 (Ann. chim. phys., 8, p . 306) . It occurs in small quantities in the See also:atmosphere . It may be prepared by passing a current of carbon dioxide through See also:ice-cold water, to which small quantities of See also:barium peroxide are added from time to time (F .

Duprey, Comptes rendus, 1862, 55, p . 736; A . J . See also:

Balard, ibid., p . 758), BaO2+See also:CO2+H2O=H202+BaCO3 . E . See also:Merck (Abst . J.C.S., 1907, ii., p . 859) showed that barium percarbonate, BaCO4, is formed when the gas is in excess; this substance readily yields the peroxide with an acid . Or barium peroxide may be decomposed by hydrochloric, hydrofluoric, sulphuric or silicofluoric acids (L . Crismer, Bull. soc. chim., 1891 (3), 6, p . 24; •See also:Hanriot, Comptes rendus, 1885, too, pp .

56, 172), the peroxide being added See also:

HYDROGRAPHY- -=HYI ROLYSIS . benzoic and other organic acids are readily oxidized in the presence of ferrous sulphate (H . J . H . See also:Fenton, See also:Jaw . Chem . Soc., 1900, 77, p . 69), and sugars are readily oxidized in the presence of ferric chloride (O . See also:Fischer and M . See also:Busch; Bcr., 1891, 24, p . 1871) . It is sought to explain these oxidation processes by assuming that the hydrogen peroxide unites with the See also:compound undergoing oxidation to form an addition compound; which subsequently decomposes (J .

H . Kastle and A . S . Loevenhart, Amer . Chun . Jaurn., 1903, 29, pp . 397, 517)• Hydrogen peroxide can also react as a reducing agent, thus See also:

silver oxide is reduced with a rapid evolution of oxygen . The course of this reaction can scarcely be considered as definitely settled; M . See also:Berthelot considers that a higher oxide of silver is formed, whilst A . See also:Baeyer and V .. Villiger are of opinion that reduced silver is obtained [see Comptes rendus, 1901, 133, p . 555; Ann .

Chim . Phys., 1897 (7), I I, p . 217, and Ber., 19o1, 34, p• 2769] . Potassium' permanganate, in the presence of dilute sulphuric acid, is rapidly reduced by hydrogen peroxide, oxygen being given off, 2KMn04-1-3H,SO4+5IJ2O2 = K2SO4+2MnSO4+8H20+502 . See also:

Lead peroxide is reduced to the monoxide . Hypochlorous acid and its salts, together with the corresponding See also:bromine and See also:iodine compounds, liberate oxygen violently from hydrogen peroxide, giving hydrochloric, hydrobromic and hydriodic acids (S . Tanatar, Ber., 1899, 32,p . 1013) . On the constitution of hydrogen peroxide see C . F . See also:Schonbein, Jour. See also:peak . Chem., 1858–1868; M .

Traube, Ber., 1882–1889; J . W . Briihl, See also:

Bert; 1895, 28, p . 2847; 1900, 33, p . 1709; S . Tanatar, Ber., 1903, 36, p . 1893 . Hydrogen peroxide finds application as a See also:bleaching agent, as an antiseptic, for the removal of the last traces of See also:chlorine and See also:sulphur dioxide employed in bleaching, and for various quantitative separations in See also:analytical See also:chemistry . (P . Jannasch, Ber., 1893, 26, p.2908) . It may be estimated by titration with potassium permanganate in acid solution; with potassium ferricyanide, in alkaline solution, 2K,Fe(CN)s+2KOFI+H202 2K4Pe(CN)6+2H20+02;orbyoxidizing arsenious acid in alkaline solution, with the peroxide and back titration of the excess of arsenious acid with See also:standard iodine (B . Grtitzner, See also:Arch. der Pharm., 1899, 237, p .

705) . It may be recognized by the See also:

violet coloration it gives when added to a very dilute solution of potassium bichromate in the presence of hydrochloric acid ; by the See also:orange-red See also:colour it gives with a solution ' of See also:titanium dioxide in concentrated sulphuric acid; and by the precipitate. of Prussian blue formed when it is added to a. solution containing ferric chloride and potassium ferricyanide . Ozonic Acid, H204 . By the action of See also:ozone on a 4o% •solution of potassium hydroxide, placed in a freezing mixture, an orange-See also:brown substance is obtained, probably K204, which A . Baeyer and V . Villiger (Ber., 1902, 35, p . 3038) think is derived from ozonic acid, produced according to the reaction 03+1120 = H2O4 .

End of Article: atomic weight x-oo8 HYDROGEN [symbol H (0=16)]
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