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See also:INDIUM (See also:symbol In, atomic See also:weight 114.8) , a metallic chemical See also:element, included in the sub-See also:group of the periodic See also:classification of the elements containing See also:aluminium, See also:gallium and See also:thallium . It was first discovered in 1863 by F . Reich and Th . See also:Richter (Journ. fitr prak . Chem., 1863, 89, p . 444) by means of its spectrum . It occurs' naturally in very small quantities in See also:zinc See also:blende, and is best obtained from metallic zinc (which contains a small quantity of See also:indium) by treating it with such an amount of hydrochloric See also:acid that a little of the zinc remains undissolved; when on See also:standing for some See also:time the indium is precipitated on the undissolved zinc . The crude product is freed from basic zinc salts, dissolved in nitric acid and the nitric acid removed by evaporation with sulphuric acid, after which it is precipitated by addition of See also:ammonia . The precipitated indium hydroxide is converted into a basic sulphite by boiling with excess of See also:sodium bisulphite, and then into the normal sulphite by dissolving in hot sulphurous acid . This See also:salt on strong ignition leaves a See also:residue of the trioxide, which can be converted into the See also:metal by See also:heating in a current of See also:hydrogen, or by See also:fusion with sodium (C . Winkler, Journ. See also:fur prak . Chem., 1867, 102, p .
273)
.
Indium is a soft malleable metal, melting at 155° C
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Its specific gravity is 7.421 and its specific See also:heat 0.05695 (R
.
See also:Bunsen)
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Indium See also:oxide, In203, is a yellow See also:powder which is formed on ignition of the hydroxide
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It is readily reduced on heating with See also:carbon or hydrogen, and does not pass into an insoluble See also:form when ignited
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The hydroxide, In(OH)a, is prepared, as a gelatinous precipitate, by adding ammonia to any soluble indium salt
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It is readily soluble in See also:caustic potash, but insoluble in ammonia
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Three chlorides of indium are known: the trichloride, InCla, a deliquescent salt, formed by heating a mixture of the oxide arid carbon in a current of See also:chlorine; the dichloride, InCl2, obtained by heating the metal in hydrochloric acid See also:gas; and the monochloride, InCl, which is prepared by distilling the vapour of the dichloride over metallic indium
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The mono- and di-chlorides are decomposed by See also:water with the formation of the trichloride, and separation of metallic indium
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Indium Sulphate, In,(S03)3, is obtained as a See also: An indium ammonium See also:alum, In,(SO4),.(NH4)2SO4.24H,0 is known . The atomic See also:weight of indium has been determined by C . Winkler and by R . Bunsen by converting the metal into its oxide . Thiel (Ber., 1904, 37, p . 1135) obtained the values 115•o8 and 114.81 from analyses of the chloride and bromide, whilst F . C . Mathers (Abst . J.C.S., 1907, ii . 352) obtained 114.88 and 114.86 . Indium salts can be recognized by the dark See also:blue See also:colour they give in the See also:flame of the Bunsen burner; and by the white beads of metal and the yellow incrustation formed when heated on See also:charcoal with sodium carbonate . |
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