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CHI3 See also:IODOFORM , a valuable antiseptic discovered by G . S . Serullas in 1822; in 1834 J . B . See also:Dumas showed than it contained See also:hydrogen . It is formed by the See also:action of See also:iodine and aqueous potash on See also:ethyl See also:alcohol, See also:acetone, acetaldehyde and from most compounds containing the grouping See also:CH3•CO•C– . Its formation from alcohol may be represented thus: C2H5OH+ 412+6KHO= CHI3+KHCO2+5KI+5H20 . It crystallizes in yellow hexagonal plates, melting at 119-1200 C., and is readily soluble in alcohol and See also:ether, but is insoluble in See also:water . It has a characteristic odour and is volatile in See also:steam . On reduction with hydriodic See also:acid, it yields methylene iodide, CH2I2 . More recently, See also:iodoform has been prepared by the See also:electrolysis of a See also:solution of See also:potassium iodide in the presence of alcohol or acetone, the electrolytic See also:cell being fitted with a See also:diaphragm, in See also:order to prevent the hydrogen which is formed at the same See also:time from reducing the iodoform, or from combining with the iodine to See also:form hydriodic acid . K . See also:Ellis uses a solution of potassium iodide and See also:sodium carbonate in water, which with the necessary alcohol is contained in a porous cell fitted with a See also:lead anode, whilst the See also:cathode compartment contains a solution of See also:caustic soda and a See also:nickel electrode . The electrolysis is carried out at a temperature of 7o° C., and a current See also:density of one See also:ampere per square decimetre is used . At the end of three See also:hours a yield of 7o 04, of the theoretical quantity is obtained . |
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[back] IODINE (symbol I, atomic weight '26.92) |
[next] IOLA |
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