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0=16] atomic weight 14.01 NITROGEN [s...

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Originally appearing in Volume V19, Page 714 of the 1911 Encyclopedia Britannica.
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0=16] atomic See also:

weight 14.01 See also:NITROGEN [See also:symbol N.  . A non-metallic chemical See also:element, first isolated in 1772 by D . See also:Rutherford, who showed that on removing See also:oxygen from See also:air a See also:gas remained, which was incapable of supporting See also:combustion or respiration . See also:Nitrogen forms approximately 79% by See also:volume (or 77% by See also:weight) of the See also:atmosphere; actual values are: % by volume—79.07 (See also:Regnault), 79.20 (See also:Dumas); %by weight—76.87 (Regnault), 77.00 (Dumas), 77.002 (Levey), 76.900 (See also:Stas), 77.010 (See also:Marignac) . No absolutely accurate determinations appear to have been made recently . See also:Free nitrogen is also found in some natural See also:waters and has been recognized in certain nebulae . In the combined See also:state nitrogen is fairly widely distributed, being found in See also:nitre, See also:Chile See also:saltpetre, ammonium salts and in various See also:animal and See also:vegetable tissues and liquids . It is invariably See also:present in soils, where compounds are formed by nitrifying bacteria . Nitrogen may be obtained from the atmosphere by the removal of the oxygen with which it is there mixed . This may be effected by burning See also:phosphorus in a confined volume of air, by the See also:action of an alkaline See also:solution of See also:pyrogallol on air, by passing air over heated See also:copper, or by the action of copper on air in the presence of ammoniacal solutions . It is also prepared by See also:heating ammonium nitrite (or a mixture of See also:sodium nitrite and ammonium chloride): NH4NO2=2H20+N2; by heating a mixture of ammonium nitrate and chloride (the See also:chlorine which is simultaneously produced being absorbed by See also:milk of See also:lime orby a solution of sodium hydroxide) : 4NH4NO3+2NH4CI =5N2 +C12+12H20; by heating ammonium dichromate (or a mixture of ammonium chloride and See also:potassium dichromate) : (NH4)5Cr2O7 =Cr203+4H2O+N2; by passing chlorine into a concentrated solution of See also:ammonia (which should be present in considerable excess) : 8NH3+3C12=6NH4Cl+N2; by the action of hypochlorites or hypobromites on ammonia: 3NaOl3r±2NH3=3NaBr+3H20+N2; and by the action of See also:manganese dioxide on ammonium nitrate at 180-200° C . It is also formed by the reduction of nitric and nitrous oxides with See also:hydrogen in the presence of platinized See also:asbestos at a red See also:heat (G. v .

Knorre and K . See also:

Arndt, Ber., 1899, 32, p . 2136) ; by the oxidation of See also:hydroxylamine (ibid., 1900, 33, p . 30) ; and by the See also:electrolysis of See also:hydrazine and its salts (E . Ch . Szarvasy, Jour . Chem . See also:Soc., 1900, 77, p . 603) . The See also:chief importance of nitrogenous compounds depends upon their assimilation by living See also:plants, which, in their development, absorb these compounds from the See also:soil, wherein they are formed mainly by the action of nitrifying bacteria . Since these compounds are essential to plant See also:life, it becomes necessary to replace the amount abstracted from the soil, and hence a demand for nitrogenous See also:manures was created . This was met in a very large measure by deposits of natural nitre and the products of artificial nitrieres, whilst additional supplies are available in the ammoniacal liquors of the gas-manufacturer, &c .

The possible failure of the nitre deposits led to attempts to convert atmospheric nitrogen into manures by processes permitting economic success . See also:

Combination can be made in five directions, viz. to See also:form (1) oxides and nitric acids, (2) ammonia, (3) readily decomposable nitrides, (4) cyanides, (5) cyanamides .

End of Article: 0=16] atomic weight 14.01 NITROGEN [symbol N.
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