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NON Furoxane . such as furfuracrolein, C4H3O•CH:CH•CHO, and furfuracetone, C4H3O•CH:CH•CO•CH3 . With alcoholic potassiumSee also: cyanide it changes to furoin, C4H3O.CHOH•CO•C4H3O, which can be oxidized to furil, C4H3O•CO•CO•C4H30, whilst alcoholic potash converts it into furfuryl See also: alcohol
.
With fatty acids and acid anhydrides it gives the " Perkin " reaction (see CINNAMIC ACID)
.
Furfurol is shown to have its aldehydic See also: group in the a position, by conversion into furfurpropionic acid, C4H3O•CH2•CH2•CO2H, which on oxidation by bromine See also: water and subsequent reduction of the oxidized product is converted into n-pimelic acid, HO2C(CH2)5CO2H
.
Furfurol in minute quantities can be detected by the red colour it forms with a solution of aniline acetate
.
Furfurane- aa'- dicarboxylic acid or dehydromucic acid, C4H20(See also: CO2H)2, is formed when mucic acid is heated with hydrochloric acid at too° C
.
On being heated, it loses See also: carbon dioxide and gives pyromucic acid
.
By digesting acetoacetic ester with sodium succinate and acetic anhydride, methronic acid, C8H805, is obtained; for the constitution of this acid, see L
.
Knorr, Ber., 1889, 22, p
.
152, and R
.
See also: Fittig, See also: Ann., 1889, 250, p
.
166 . Di- and tetrahydrofurfurane compounds are also known (see A . Lipp, Ber., 1889, 22, p . 1196; W . H . Perkin, junr . Journ . Chem . See also: Soc., 1890, 57, p
.
944; and S
.
Ruhemann, ibid., 1896, 69, p
.
1383)
.
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