OAO 0B0
OcO See also:ODO pep OFO
a b
------------------
(ti)
ja~~~E
-0
a WI
0
0
0
Gal,
.
0
and when made as directed below it has at t° C. an electromotive force E, volts, such that
E =1.0184 -0.0000406 (t -20) -0.00000095 0—20)2 +
0.00000001 (t-20)3
.
After the See also:platinum wires have been sealed through the See also:glass, a
little aqua regia is placed in the See also:cell legs until bubbles pi See also:gas arise
from the platinum, when it is thrown out and replaced by a See also:solution of mercurous nitrate
.
Then, by the use of another piece of platinum as anode, See also:mercury is electrolytically deposited upon the platinum, which may also be amalgamated by making it See also:- WHITE
- WHITE, ANDREW DICKSON (1832– )
- WHITE, GILBERT (1720–1793)
- WHITE, HENRY KIRKE (1785-1806)
- WHITE, HUGH LAWSON (1773-1840)
- WHITE, JOSEPH BLANCO (1775-1841)
- WHITE, RICHARD GRANT (1822-1885)
- WHITE, ROBERT (1645-1704)
- WHITE, SIR GEORGE STUART (1835– )
- WHITE, SIR THOMAS (1492-1567)
- WHITE, SIR WILLIAM ARTHUR (1824--1891)
- WHITE, SIR WILLIAM HENRY (1845– )
- WHITE, THOMAS (1628-1698)
- WHITE, THOMAS (c. 1550-1624)
white hot in a See also:Bunsen See also:flame and plunging it in mercury
.
To prepare the See also:cadmium See also:amalgam, one See also:part of pure cadmium is dissolved in six parts of pure mercury, and the product while warm and fluid is placed in one See also:limb of the cell and warmed, to ensure perfect contact with the platinum See also:wire
.
The cadmium sulphate solution is
prepared by digesting a saturated solution of cadmium sulphate with cadmium hydroxide to remove See also:free See also:acid, care being taken not to raise the temperature above 7o° C., and then by digesting it still further with mercurous sulphate until no more precipitation occurs
.
The cadmium sulphate solution must be saturated and have free crystals of the See also:salt in it
.
The mercurous sulphate must be free from acid, and made neutral by trituration with finely divided mercury
.
In making the See also:paste, so much cadmium sulphate must be added that a saturated solution of that salt is formed and is See also:present in the cell
.
The cell has the electromotive force above stated if the amalgam of cadmium has from 6 to 13 parts of mercury to 1 of cadmium
.
The See also:German investigators seem to have a See also:great preference for the H See also:form of cell, but it is clear that a narrow tubular cell of the See also:British See also:board of See also:trade form not only comes more quickly to the temperature of the See also:water See also:bath in which it is placed, but is more certain to be wholly at one temperature
.
In a modification of the H form devised by F
.
E
.
See also:- SMITH
- SMITH, ADAM (1723–1790)
- SMITH, ALEXANDER (183o-1867)
- SMITH, ANDREW JACKSON (1815-1897)
- SMITH, CHARLES EMORY (1842–1908)
- SMITH, CHARLES FERGUSON (1807–1862)
- SMITH, CHARLOTTE (1749-1806)
- SMITH, COLVIN (1795—1875)
- SMITH, EDMUND KIRBY (1824-1893)
- SMITH, G
- SMITH, GEORGE (1789-1846)
- SMITH, GEORGE (184o-1876)
- SMITH, GEORGE ADAM (1856- )
- SMITH, GERRIT (1797–1874)
- SMITH, GOLDWIN (1823-191o)
- SMITH, HENRY BOYNTON (1815-1877)
- SMITH, HENRY JOHN STEPHEN (1826-1883)
- SMITH, HENRY PRESERVED (1847– )
- SMITH, JAMES (1775–1839)
- SMITH, JOHN (1579-1631)
- SMITH, JOHN RAPHAEL (1752–1812)
- SMITH, JOSEPH, JR
- SMITH, MORGAN LEWIS (1822–1874)
- SMITH, RICHARD BAIRD (1818-1861)
- SMITH, ROBERT (1689-1768)
- SMITH, SIR HENRY GEORGE WAKELYN
- SMITH, SIR THOMAS (1513-1577)
- SMITH, SIR WILLIAM (1813-1893)
- SMITH, SIR WILLIAM SIDNEY (1764-1840)
- SMITH, SYDNEY (1771-1845)
- SMITH, THOMAS SOUTHWOOD (1788-1861)
- SMITH, WILLIAM (1769-1839)
- SMITH, WILLIAM (c. 1730-1819)
- SMITH, WILLIAM (fl. 1596)
- SMITH, WILLIAM FARRAR (1824—1903)
- SMITH, WILLIAM HENRY (1808—1872)
- SMITH, WILLIAM HENRY (1825—1891)
- SMITH, WILLIAM ROBERTSON (1846-'894)
Smith, of the See also:National See also:Physical Laboratory (Phil
.
Trans., A, 207, pp
.
393-420), a contraction formed in the See also:side of the See also:vertical See also:tube tends to hold the contents in See also:place
.
Fig
.
4 shows this cell, hermetically sealed, mounted in a See also:brass See also:case
.
In cases when great accuracy is not required, a See also:Daniell cell can be used as a See also:standard of electromotive force
.
The form designed by J
.
A
.
See also:Fleming (Phil
.
Mag., 20, p
.
126) consists of a U tube, one See also:leg of which contains a See also:rod of pure amalgamated See also:zinc, and the other a rod of freshly electrotyped See also:copper
.
The legs are filled with solutions of zinc sulphate and copper sulphate, the zinc rod being in the zinc sulphate and the copper rod in the copper sulphate
.
When so made, the cell has an electromotive force of 1.072 volts and no sensible temperature variation
.
The solutions are made by dissolving the purest recrystallized sulphate of copper and sulphate of zinc in distilled water
.
For the zinc solution, take 55.5 parts by See also:weight of crystals of zinc sulphate (ZnSOa7OH2) and dissolve in 44.5 parts by weight of distilled water; the resulting solution should have a specific gravity of 1.200 at about 2o° C
.
For the sulphate of copper solution, take 16.5 parts by weight of pure crystals of copper sulphate (CuSO4,5OH2) and dissolve in 83.5 parts by weight of water; the resulting solution should have a specific gravity of 1.100 at 20° C
.
The solutions should be adjusted exactly to these densities and kept in stock bottles, from which the reservoirs of the cell should be filled up as required
.
A form of See also:potentiometer employing a vibration See also:galvanometer and suitable for alternating current measurement by null methods has been devised by Dr Drysdale (see Proc
.
Phys
.
See also:Soc
.
Lond
.
1909, 21, 561.)
See J
.
A
.
Fleming, Handbook for the See also:Electrical Laboratory and Testing See also:Room, vol. i
.
(See also:London, 1903)-vol. i contains on pp
.
108-110 an extensive See also:list of various See also:original See also:memoirs published on the See also:Clark and See also:Weston cells; G
.
D
.
Aspinall See also:Parr, Electrical See also:Engineering Measuring See also:Instruments (London, 1903) ; W
.
C
.
See also:Fisher, The Potentiometer and its Adjuncts (London, 1906)
.
End of Article: