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C13H34O2 OLEIC See also:ACID or C8H07•CH: CH . [See also:CH2]7 • See also:CO2 H, an organic See also:acid occurring as a glyceride, triolein, in nearly all fats, and in many See also:oils--See also:olive, See also:almond, See also:cod-See also:liver, &c . (see OILS) . It appears as a by-product in the manufacture of candles . To prepare it olive oil is saponified with potash, and See also:lead acetate added; the lead salts are separated, dried, and extracted with See also:ether, which dissolves the lead oleate; the See also:solution is then treated with hydrochloric acid, the lead chloride filtered off, the liquid concentrated, and finally distilled under diminished pressure . Oleic acid is a colourless, odourless solid, melting at 14° and boiling at 223° (10 mm.) . On exposure it turns yellow, becoming rancid . Nitric acid oxidizes it to all the fatty acids from acetic to capric . Nitrous acid gives the isomeric elaidic acid, See also:C8H,7•CH:CH•(CH2]7 •See also:CO2H, which is crystalline and melts at 51° . Hydriodic acid reduces both oleic and elaidic acids to stearic acid . Erucic acid, C8HwCH:CH•[CH2]n•CO2H, and the isomeric brassidic acid, belong to the oleic acid See also:series . They occur as glycerides in See also:rape-See also:seed oil, in the fatty oil of See also:mustard, and in the oil of See also:grape seeds . Linoleic acid, C18H32O2, found as glyceride in drying oils, and ricinoleic acid, C18H33(OH)O2, found as glyceride in See also:castor oil, closely resemble oleic acid . |
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