Online Encyclopedia

OLIVINE

Online Encyclopedia
Originally appearing in Volume V20, Page 89 of the 1911 Encyclopedia Britannica.
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OLIVINE  , a

rock-forming
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mineral composed of magnesium and ferrous crthosilicate, the formula being (Mg, Fe)sSiO4 . The name olivine, proposed by A . G . Werner in 1790, alludes to the olive-green colour commonly shown by the mineral . The transparent varieties, or " precious olivine " used in jewelry, are known as
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chrysolite (q.v.) and
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peridot (q.v.) . The
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term olivine is often applied incorrectly by jewellers to various green stones . Olivine crystallizes in the orthorhombic
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system, but distinctly
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developed crystals are comparatively rare, the mineral more often occurring as compact or granular masses or as grains and blebs embedded in the igneous rocks of which it forms a constituent
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part . There are indistinct cleavages parallel to the macropinacoid (M in the fig.) and the brachypinacoid . The hardness is 6,1; and the sp. gr . 3.27-3.37, but reaching 3.57 in the highly ferruginous variety known as hyalosiderite . The amount of ferrous
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oxide varies from 5 (about 9 % in the gem varieties to 30 % in hyalosiderite . The
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depth of the green, or yellowish-brown colour, also varies with the amount of iron .

The lustre is vitreous . The indices of

refraction ( 1.66 and 1.70) and the double refraction are higher than in many other rock-forming minerals; and these characters, together with the indistinct cleavage, enable the mineral to be readily distinguished in thin rock-sections under the microscope . The mineral is decomposed by hot hydrochloric acid with separation of gelatinous
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silica . Olivine often contains small amounts of nickel and titanium dioxide; the latter replaces silica, and in the variety known as titan-olivine reaches 5% . Olivine is a
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common constituent of many basic and ultrabasic rocks, such as
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basalt,
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diabase,
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gabbro and
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peridotite: the dunite, of Dun Mountain near Nelson in New Zealand, is an almost pure olivine-rock . In basalts it is often
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present as small porphyritic crystals or as large granular aggregates . It also occurs as an
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accessory constituent of some granular dolomitic limestones and crystalline schists . With
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enstatite it forms the bulk of the material of meteoric stones; and in another type of meteorites large blebs of glassy olivine fill spaces in a cellular mass of metallic iron . Olivine is especially liable to alteration into
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serpentine (hydrated magnesium silicate) ; the alteration proceeds from the outside of the crystals and grains or along irregular cracks in their interior, and gives rise to the separation of iron oxides and an irregular
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net-
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work of fibrous serpentine, which in rock-sections presents a very characteristic appearance . Large greenish-yellow crystals from Snarum in Buskerud, Norway, at one time thought to be crystals of serpentine, really consist of serpentine pseudomorphous after olivine . Many of the large rock-masses of serpentine have been derived by the serpentinization of olivine-rocks . Olivine also sometimes alters, especially in crystalline schists, to a fibrous, colourless
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amphibole, to which the name pilite has been given .

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ordinary weathering processes it alters to limop.ite and silica . Closely related to olivine are several other
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species, which are included together in the olivine
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group : they have the orthosilicate formula R"2SiO4, where R" represents calcium, magnesium, iron, manganese and rarely
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zinc; they all crystallize in the orthorhombic system, and are isomorphous with olivine . The following may be mentioned Monticellite, CaMgSiOs, a rare mineral occurring as yellowish-grey crystals and grains in granular
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limestone at
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Monte Solnma, Vesuvius . Forsterite, Mg2SiOs, as colourless or yellowish grains embedded in many. crystalline limestones . Fayalte, Fe2SiO4, or iron olivine is dark brown or black in colour . It occurs as nodules in a volcanic rock at
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Fayal in the Azores, and in granite at the Mourne Mountains in Ireland; and as small crystals in cavities in rhyolite at the Yellowstone Park, U.S.A . It is a common constituent of crystalline iron slags . Tephroite, Mn2SiO4, a grey (rm4p6s, ash-coloured), cleavable mineral occurring with other manganiferous minerals in Sweden and New Jersey . (L . J .

End of Article: OLIVINE
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JUSTE DANIEL OLIVIER (1807-1876)
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OLIVIER EMILE OLLIVIER (1825— )

Additional information and Comments

Dear sir/lady 1) In which temperature is calcined olivine? 2) For tundish masses and foundries application which kind of olivine should be used ? calcined or raw olivine sand?
Principally any material which will contact with molten steel should have no volatiles preferably not more than 1.0% Loss on Ignition. If the green olivine has good refractoriness and LOI not more than 1.00% it can be safely used for tundishes without any calcining ,but firing only for the purpose of making bricks or plates for tundishes. Uncalcined olivines which have LOI more than 1.00% should be never used for tundishes even if they are fired in kilns during shaping because refractory bricks or plates will have too much porosity (low refractoriness) Regards
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