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PETROLOGY
, the See also:science of rocks (Gr. itrETpos), the See also:branch of See also:geology which is concerned with the investigation of the See also:composition, structure and See also:history of the See also:rock masses which make up the accessible portions of the See also:earth's crust
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Rocks have been defined as " aggregates of minerals." They are the See also:units with which the geologist deals in investigating the structure of a See also:district
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Some varieties See also:cover enormous areas and are among the commonest and most See also:familiar See also:objects of nature
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See also:Granite, See also:sandstone, See also:clay, See also:limestone, See also:slate often See also:form whole provinces and build up lofty mountains
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Such unconsolidated materials as See also:sand, See also:gravel, clay, See also:soil are justly included among rocks as being See also:mineral masses which See also:play an important role in See also: The volcanic rocks, found typically as See also:lava flows, include See also:rhyolite and See also:obsidian (with. sometimes See also:perlite), See also:trachyte and See also:phonolite (and leucitophyre which is treated under See also:leucite), See also:andesite and See also:dacite, See also:basalt (with the related See also:dolerite, variolite and tachylyte), nephelinite and tephrite . Among sedimentary rocks we recognize a volcanic group (including See also:tuff, See also:agglomerate and some kinds of See also:pumice) ; an arenaceous See also:series such as sand (some with See also:glauconite), sandstone, See also:quartzite, See also:greywacke and gravel; an argillaceous group including clay, See also:firebrick, See also:phyllite, See also:laterite shale and slate; a calcareous series with chalk, limestone (often forming See also:stalactites and stalagmites), See also:dolomite and marls or argillaccous limestones (See also:flint occurs as nodules in chalk) ; the natural See also:phosphates may be mentioned here . The metamorphic rocks are commonly gneisses and See also:schists (including See also:mica-schist) ; other types are See also:amphibolite, See also:charnockite, See also:eclogite, See also:epidiorite, See also:epidosite, granulate, See also:itacolumite, See also:hornfels, See also:mylonite and the See also:sea polite rocks . Composition.—Only the commonest minerals are of importance as rock formers . Their number is small, not exceeding a hundrod in all, and much less than this if we do not reckon the subdivisions into which the commoner species are broken up . The vast See also:majority of the rocks which we see around us every See also:day consist of quartz, See also:felspar, mica, See also:chlorite, See also:kaolin, See also:calcite, See also:epidote, See also:olivine, See also:augite, See also:hornblende, See also:magnetite, See also:haematite, See also:limonite and a few other minerals . Each of these has a recognized position in the See also:economy of nature . A See also:main determining See also:factor is the chemical composition of the See also:mass, for a certain mineral can be formed only when the necessary elements are present in the rock . Calcite is commonest in limestones, as these consist essentially of carbonate of See also:lime; quartz in sandstones and in certain igneous rocks which contain a high percentage of See also:silica . Other factors are of equal importance in determining the natural association or paragenesis of rock-making minerals, principally the mode of origin of the rock and the stages through which it has passed in attaining its present See also:condition . Two rock masses may have very much the same bulk composition and yet consist of entirely different assemblages of minerals . The tendency is always for those compounds to be formed which are See also:stable under the conditions under which the rock mass originated .
A granite arises by the consolidation of a molten magma (a fused rock mass; Gr
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µfiy,ua, from µaaaety, to knead) at high temperatures and great pressures and its component minerals are such as are formed in such circumstances
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Exposed to moisture, carbonic See also:acid and other subaerial agents at the See also:ordinary temperatures of the earth's surface, some of these See also:original minerals, such as quartz and See also: Crystalline rock masses have See also:con- solidated from See also:solution or from See also:fusion . The vast majority of igneous rocks belong to this group and the degree of perfection in which they have attained the crystalline state depends primarily on the conditions under which they solidified . Such rocks as granite, which have cooled very slowly and under great pressures, have completely crystallized, but many lavas were poured out at the surface and cooled very rapidly; in this latter group a small amount of non-crystalline or glassy matter is frequent . Other crystalline rocks such as rock-See also:salt, See also:gypsum and See also:anhydrite have been deposited from solution in See also:water, mostly owing to evaporation on exposure to the See also:air . Still another group, which includes the See also:marbles, mica-schists and quartzites, are recrystallized, that is to say, they were at first fragmental rocks, like limestone, clay and sandstone and have never been in a molten condition nor entirely in solution . Certain agencies however, acting on them, have effaced their See also:primitive structures, and induced See also:crystallization, This is a See also:kind of metamorphism . The fragmental structure needs little explanation; wherever rocks disintegrate fragments are produced which are suitable for the formation of new rocks of this group . The original materials may be organic (shells, See also:corals, plants) or vitreous (volcanic glasses) or crystalline (granite, See also:marble, &c.); the pulverizing See also:agent may be See also:frost, See also:rain, See also:running water, or the See also:steam explosions which shatter the lava within a volcanic See also:crater and produce the fragmental rocks known as volcanic ash, tuffs and agglomerates . The materials may be loose and incoherent (sand, clay, gravel) or compacted by pressure and the See also:deposit of cementing substances by percolating water (sandstone, shale, See also:conglomerate) . The grains of which fragmental rocks are composed may be coarse or See also:fine, fresh or decayed, See also:uniform or diverse in their composition; the one feature which gives unity to the class is the fact that they are all derived from pre-existing rocks or organisms . Because they are made up of broken pieces these rocks are often said to be " elastic." Origin of Rocks.—The study of the structure of rocks evidently leads us to another method of regarding them, which is more fundamental than those enumerated above, as the structure depends on the mode of origin . Rocks are divided into three great classes, the Igneous, the Sedimentary and the Metamorphic . The igneous (See also:Lat. ignis, See also:fire) rocks have all consoli- dated from a state of fusion . Some of them are crystalline or " massive "; others are fragmental . The massive igneous rocks include a few which are nearly com- pletely vitreous, and still more which contain a small amount of amorphous matter, but the majority are completely crystal- lized . Among the best known examples are obsidian, pumice, basalt, trachyte, granite, diorite . The fragmental igneous rocks consist of volcanic ashes more or less firmly compacted . The sedimentary rocks form a second group; they sedimentary have all been laid down as deposits on the earth's Rocks . surface subject to the conditions of temperature, moisture and pressure which obtain there . They include fragmental and crystalline varieties . The former consist of the debris of pre-existing rocks, accumulated in seas, lakes or dry See also:land and more or less indurated by pressure and cementing substances . Gravel, sand and clay, conglomerate, sandstone, shale are well-known examples . Many of them are fossiliferous as they contain fragments of organisms . Some are very largely made up of remains of animals or plants, more or less altered by mineralization . These are sometimes placed into a See also:special group as rocks of organic origin; limestone, See also:peat and See also:coal are typical of this class . The crystalline sediments are such as rock-salt and gypsum, deposits of saline lakes or isolated portions of the sea . They were formed under conditionsunfavourable to See also:life and hence rarely contain fossils . The metamorphic rocks are known to be almost entirely altered igneous or sedimentary masses . Metamorphism consists in the destruction of the original structures Metamorphtc Rocks. and the development of new minerals . The chemical composition of the rocks however suffers little See also:change . The rock becomes as a See also:rule more crystalline; but all stages in the See also:process may be found and in a metamorphosed sediment, e.g. a sandstone, remains of the original sand grains and See also:primary fragmental structure may be observed, although extensive recrystallization has taken See also:place . The agencies which produce metamorphism are high temperatures, pressure, interstitial moisture and in many cases movement . The effects of high temperatures are seen best in the rocks surrounding great out-crops of intrusive granite, for they have been baked and crystallized by the heat of the igneous rock (thermo-metamorphism) . In folded mountain chains where the strata have been greatly compressed and their particles have been forced to move over one another a different type of metamorphism prevails (regional or dynamic metamorphism) . Methods of Investigation.—The macroscopic (Gr. garcpos, large) characters of rocks, those visible in See also:hand-specimens without the aid of the See also:microscope, are very varied and Macroscopic difficult to describe accurately and fully . The characters . geologist in the field depends principally on them and on a few rough chemical and physical tests; and to the See also:practical engineer, architect and See also:quarry-See also:master they are all-important . Although frequently insufficient in themselves to determine the true nature of a rock, they usually serve for a preliminary classification and often give all the See also:information which is really needed . With a small See also:bottle of acid to test for carbonate of lime, a See also:knife to ascertain the hardness of rocks and minerals, and a See also:pocket See also:lens to magnify their structure, the field geologist is rarely at a loss to what group a rock belongs . The fine grained species are often indeterminable in this way, and the See also:minute mineral components of all rocks can usually be ascertained only by microscopic examination . But it is easy to see that a sandstone or grit consists of more or less rounded, waterworn sand-grains and if it contains dull, weathered particles of felspar, shining scales of mica or small crystals of calcite these also rarely See also:escape observation . Shales and clay rocks generally are soft, fine grained, often laminated and not infrequently contain minute organisms or fragments of plants . Limestones are easily marked with a knife-blade, effervesce readily with weak See also:cold acid and often contain entire or broken shells or other fossils . The crystalline nature of a granite or basalt is obvious at a glance, and while the former contains white or See also:pink felspar, clear vitreous quartz and glancing flakes of mica, the other will show yellow-See also:green olivine, black augite and See also:grey striated See also:plagioclase . But when dealing with unfamiliar types or with rocks so fine grained that their component minerals cannot be determined with the aid of a lens, the geologist is obliged to have recourse to more delicate and searching methods of investigation . With the aid of the See also:blowpipe (to test the fusibility of detached crystals), the See also:goniometer, the magnet, the magnifying See also:glass and the specific gravity See also:balance, the earlier travellers attained surprisingly accurate results . Examples of these may be found in the See also:works of von See also:Buch, See also:Scrope, See also:Darwin and many others . About the end of the 18th See also:century, See also:Dolomieu examined crushed rock powders under the microscope and Cordier in 1815 crushed, levigated and investigated the finer ground-mass of igneous rocks . His researches are See also:models of scrupulous accuracy, and he was able to announce that they consisted essentially of such minerals as felspar, augite, See also:iron ores and volcanic glass, and did not differ in nature from the coarser grained rocks . See also:Nicol, whose name is associated with the See also:discovery of the Nicol's See also:prism, seems to have been the first to prepare thin slices of mineral substances, and his methods were applied by See also:Witham (1831) to the study of plant petrifactions . This method, of such far-reaching importance in petrology, was not at once made use of for the systematic Fragmental Rocks . Igneous Rocks . Microscopic Characters . refractive See also:index of the mineral by comparison with those of different mounting See also:media . Further information is obtained by inserting the polarizer and rotating the See also:section . The See also:light vibrates now only in one See also:plane, and in passing through doubly refracting crystals in the Pleochroslide is, speaking generally, broken up into two rays, ism which vibrate at right angles to one another . In many coloured minerals such as biotite, hornblende, See also:tourmaline, chlorite, these two rays have different See also:colours, and when a section containing any of these minerals is rotated the change of See also:colour is often very striking . This See also:property, known as " pleochroism " (Gr. irXelwv, more; xpwr, colour), is of great value in the determination of rock-making minerals . It is often especially intense in small spots which surround minute enclosures of other minerals, such as See also:zircon and epidote; these are known as " pleochroic halos." If the analyser be now inserted in such a position that it is crossed relatively to the polarizer the field of view will be dark where there are no minerals, or where the light passes through isotro- See also:Double See also:pie substances such as glass, liquids and cubic crystals . See also:Refraction . All other crystalline bodies, being doubly refracting, will appear See also:bright in some position as the See also:stage is rotated . The only exception to this rule is provided by sections which are perpendicular to the optic axes of birefringent crystals; these remain dark or nearly dark during a whole rotation, and as will be seen later, their investigation is of special importance . The doubly refracting mineral sections, however, will in all cases appear black in certain positions as the stage is Extinction. rotated . They are said to be " extinguished " when this takes place . If we See also:note these positions we may measure the See also:angle between them and any cleavages, faces or other structures of the crystal by means of the rotating stage . These angles are characteristic of the See also:system to which the mineral belongs and often of the mineral species itself (see See also:CRYSTALLOGRAPHY) . To facilitate measurement of extinction angles various kinds of eyepieces have been devised, some having a stauroscopic calcite See also:plate, others with two or four plates of quartz cemented together; these are often found to give more exact results than are obtained by observing merely the position in which the mineral section is most completely dark between crossed nicols . The mineral sections when not extinguished are not only bright but are coloured and the colours they show depend on several factors, the most important of which is the strength of the double refraction . If all the sections are of the same thickness as is nearly true of well-made slides, the minerals with strongest double refraction yield the highest polarization colours . The See also:order in which the colours are arranged is that known as See also:Newton's See also:scale, the lowest being dark grey, then grey, white, yellow, See also:orange, red, See also:purple, See also:blue and so on . The difference between the refractive indexes of the ordinary and the extraordinary See also:ray in quartz is .009, and in a rock-section about aka of an See also:inch thick this mineral gives grey and white polarization tints; nepheline with weaker double refraction gives dark grey; augite on the other hand will give red and blue, while calcite with still stronger double refraction will appear pinkish or greenish white . All sections of the same mineral, however, will not have the same colour; it was stated above that sections perpendicular to an optic See also:axis will be nearly black, and, in general, the more nearly any section approaches this direction the See also:lower its polarization colours will be . By taking the See also:average, or the highest colour given by any mineral, the relative value of its double refraction can be estimated; or if the thickness of the section be precisely known the difference between the two refractive indexes can be ascertained . If the slides be thick the colours will be on the whole higher than in thin slides . It is often important to find out whether of the two axes of See also:elasticity (or vibration traces) in the section is that of greater elasticity (or lesser refractive index) . The quartz See also:wedge or selenite plate enables us to do this . Suppose a doubly refracting mineral section so placed that it is " extinguished "; if now it is rotated through 45° it will be brightly illuminated . If the quartz wedge be passed across it so that the See also:long axis of the wedge is parallel to the axis of elasticity in the section the polarization colours will rise or fall . If they rise the axes of greater elasticity in the two minerals are parallel; if they sink the axis of greater elasticity in the one is parallel to that of lesser elasticity in the other . In the latter See also:case by pushing the wedge sufficiently far See also:complete darkness or See also:compensation will result . Selenite wedges, selenite plates, mica wedges and mica plates are also used for this purpose . A quartz wedge also may be calibrated by determining the amount of double refraction in all parts of its length . If now it be used to produce compensation or complete extinction in any doubly refracting mineral section, we can ascertain what is the strength of the double refraction of the section because it is obviously equal and opposite to that of a known See also:part of the quartz wedge . A further refinement of microscopic methods consists of the use of strongly convergent polarized light (konoscopic methods) . This is obtained by a wide angled achromatic See also:condenser above the polarizer, and a high See also:power microscopic See also:objective . Those sections are most useful which are perpendicular to an optic axis, and consequently remain dark on rotation . If they belong to uniaxial crystals they show a dark See also:cross or convergent light between crossed nicols, investigation of rocks, and it was not till 1858 that Sorby pointed out its value . Meanwhile the See also:optical study of sections of crystals had been advanced by See also:Sir See also:David See also:Brewster and other physicists and mineralogists and it only remained to apply their methods to the minerals visible in rock sections . Very rapid progress was made and the names of See also:Zirkel, See also:Allport, Vogelsang, Schuster, Rosenbusch, See also:Bertrand, See also:Fouque and See also:Levy are among those of the most active pioneers in the new field of See also:research . To such importance have microscopical methods attained that textbooks of petrology at the present See also:time are very largely devoted to a description of the appearances presented by the minerals of rocks as studied in transparent micro-sections . A See also:good rock-section should be about one-thousandth of an inch in thickness, and is by no means very difficult to make . A thin Sections. splinter of the rock, about as large as a See also:halfpenny may be taken; it should be as fresh as possible and free from obvious cracks . By grinding on a plate of planed See also:steel or See also:cast iron with a little fine See also:carborundum it is soon rendered See also:flat on one See also:side and is then transferred to a See also:sheet of plate glass and smoothed with the very finest See also:emery till all minute pits and roughuesses are removed and the surface is a uniform plane . The rock-chip is then washed, and placed on a See also:copper or iron plate which is heated by a spirit or See also:gas See also:lamp . A microscopic glass slip is also warmed on this plate with a drop of viscous natural See also:Canada See also:balsam on its surface . The more volatile ingredients of the balsam are dispelled by the heat, and when that is accomplished the smooth, dry, warm rock is pressed firmly into contact with the glass plate so that the film of balsam intervening may be as thin as possible and free from air-bubbles .
The preparation is allowed to cool and then the rock chip is again ground down as before, first with carborundum and, when it becomes transparent, with fine emery till the desired thickness is obtained
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It is then cleaned, again heated with a little more balsam, and covered with a cover glass
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The labour of grinding the first surface may be avoided by cutting off a smooth slice with an iron disk armed with crushed See also:diamond See also:powder
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A second application of the slitter after the first See also:face is smoothed and cemented to the glass will in See also:expert hands leave a rock-section so thin as to be already transparent
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In this way the preparation of a section may require only twenty minutes
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The microscope employed is usually one which is provided with a rotating stage beneath which there is a polarizer, while above the Microscope. objective or the eyepiece an analyser is mounted; alter-
natively the stage may be fixed and the polarizing and analysing prisms may be capable of simultaneous rotation by means of toothed wheels and a connecting-See also:rod
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If ordinary light and not polarized light is desired, both prisms may be withdrawn from the axis of the See also:instrument; if the polarizer only is inserted the light transmitted is plane polarized; with both prisms in position the slide is viewed between " crossed nicols." A microscopic rock-section in ordinary light if a suitable magnification (say 30) be employed is seen to consist of grains or crystals varying in colour, Characters See also:size and shape
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Some minerals are colourless and trans-
See also:parent parent (quartz, calcite, felspar, muscovite, &c.), others
are yellow or See also: III.) . The refractive index is also clearly shown by the See also:appearance of the sections, which are rough, with well-defined See also:borders if they have a much stronger refraction than the See also:medium in which they are mounted . Some minerals decompose readily and become turbid and semi-transparent (e.g. felspar); others remain always perfectly fresh and clear (e.g. quartz), others yield characteristic secondary products (such as green chlorite after biotite) . The inclusions in the crystals are of great See also:interest; one mineral may enclose another, or may contain spaces occupied by glass, by fluids or by gases . Lastly the structure of the rock, that is to say, the relation of its components to one another, is usually clearly indicated, whether it Micro- be fragmental or massive; the presence of glassy matter structure. in contradistinction to a completely crystalline or holo-crystalline " condition; the nature and origin of organic fragments; banding, foliation or lamination; the pumiceous or porous structure of many lavas; these and many other characters, though often not visible in the hand specimens of a rock, arc rendered obvious by the examination of a microscopic section . Many refined methods of observation may be introduced, such as the measurement of the size of the elements of the rock by the help of micrometers; their relative proportions by means of a glass plate ruled in small squares; the angles between cleavages or faces seen in section by the use of the rotating graduated stage, and the estimation of the 326 the bars of which remain parallel to the wires in the field of the See also:eye-piece . Sections perpendicular to an optic axis of a biaxial mineral under the same conditions show a dark See also:bar which on rotation becomes curved to a hyperbolic shape . If the section is perpendicular to a " See also:bisectrix " (see CRYSTALLOGRAPHY) a black cross is seen which on rotation opens out to form two hyperbolas, the apices of which are turned towards one another . The optic axes emerge at the apices of the hyperbolas and may be surrounded by coloured rings, though owing to the thinness of minerals in rock sections these are only seen when the double refraction of the mineral is strong . The distance between the axes as seen in the field of the microscope depends partly on the axial angle of the crystal and partly on the numerical See also:aperture of the objective . If it is measured by means of an eye-piece See also:micrometer, the optic axial angle of the mineral can be found by a See also:simple calculation . The quartz wedge, See also:quarter mica plate or selenite plate permit the determination of the See also:positive or negative See also:character of the crystal by the changes in the colour or shape of the figures observed in the field . These operations are precisely similar to those employed by the mineralogist in the examination of plates cut from crystals . It is sufficient to point out that the petrological microscope in its See also:modern development is an optical instrument of great precision, enabling us to determine physical constants of crystallized substances as well as serving to produce magnified images like the ordinary microscope . A great variety of See also:accessory apparatus has been devised to See also:fit it for these special uses . The separation of the ingredients of a crushed rock powder from one to another in order to obtain pure samples suitable Separation for See also:analysis is also extensively practised . It may ofcompo- be effected by means of a powerful electro-magnet nents. the strength of which can be regulated as desired . A weak magnetic field will attract magnetite, then haematite and other ores of iron . Silicates containing iron will follow in definite order and biotite, See also:enstatite, augite, hornblende, garnet and similar ferro-magnesian minerals may be successively abstracted; at last only the colourless, non-magnetic compounds, such as muscovite, calcite, quartz and felspar, will remain . Chemical methods also are useful . A weak acid will dissolve calcite from a crushed limestone, leaving only dolomite, silicates or quartz . Hydrofluoric acid will attack felspar before quartz, and if employed with great caution will dissolve these and any glassy material in a rock powder before dissolving augite or See also:hypersthene . Methods of separation by specific gravity have a still wider application . The simplest of these is levigation (Lat. levigare, to make smooth, See also:levis) or treatment by a current of water; it is extensively employed in the See also:mechanical analysis of soils and in the treatment of ores, but is not so successful with rocks, as their components do not as a rule differ very greatly in specific gravity . Fluids are used which do not attack the majority of the rock-making minerals and at the same time have a high specific gravity . Solutions of See also:potassium mercuric iodide (sp. gr . 3•i96), See also: |