Online Encyclopedia

PHOSGENITE

Online Encyclopedia
Originally appearing in Volume V21, Page 474 of the 1911 Encyclopedia Britannica.
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PHOSGENITE  , a rare.

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mineral consisting of lead chlorocarbonate, (PbCI)2CO3 . The tetragonal (
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holosymmetric) crystals are prismatic or
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tabular in habit, and are bounded by smooth, bright faces: they are usually colourless and transparent, and have a brilliant adamantine lustre . Sometimes the crystals have a curious helical twist about the tetrad or
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principal axis . The hardness is 3 and the specific gravity 6.3 . The mineral is rather sectile, and consequently-was early known as " corneous lead " (Ger . Hornblei) . The fanciful name phosgenite was given by A . Breithaupt in 1820, from phosgene, the old name of carbon oxychloride, because the mineral contains the elements carbon, oxygen and chlorine . At Cromford, near
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Matlock, it was long ago found in an old lead mine, being associated with afiglesite and matlockite (Pb2OC12) in cavities in decomposed
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galena: hence its
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common name cronfortite .
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Fine crystals are also found in galena at Monteponi near
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Iglesias in Sardinia, but the largest are those recently found near Dundas in
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Tasmania . Crystals of phosgenite, and also of the corresponding bromine compound [PbBr]2CO3, have been prepared artificially . (L .

J .

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