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See also:PYROCATECHIN, or PYROCATECHOL
, ortho-dioxybenzene, See also:C6H4(OH)2, first prepared in 1839 by H
.
Reinsch on distilling catechin (the juice of See also:Mimosa See also:catechu); occurs See also:free in kino and in beechwood See also:tar; its sulphonic See also:acid is See also:present in the urine of the See also:horse and See also:man
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It results in the alkaline See also:fusion of many resins, and may be prepared by fusing ortho-phenolsulphonic acid, o-chlorphenol, o-bromphenol, and o-phenoldisulphonic acid with potash, or, better, by See also:heating its methyl See also:ether, guaiacol, C6H4(OH) (OCH3), a constituent of beechwood tar, with hydriodic acid
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See also:Pyrocatechin crystallizes in See also: The valerianic ester of guaiacol is known as geosote, the benzoic as benzosol, the salicylic as guaiacolsalol, while the See also:glycerin ether appears as guaiamar . Pyrocatechin readily condenses to See also:form heterocyclic compounds; cyclic See also:esters are formed by See also:phosphorus trichloride and oxychloride, carbonyl chloride, sulphuryl chloride, &c.; whilst ortho-phenylenediamine, o-aminophenol, and o-aminothiophenol give See also:phenazine, phenoxazine and thiodiphenylamine . |
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