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See also:RADIUM (from See also:Lat. See also:radius, See also:ray) , a metallic chemical See also:element obtained from See also:pitchblende, a See also:uranium See also:mineral, by P. and Mme . See also:Curie and G . See also:Bemont in 1898; it was so named on See also:account of the intensity of the radioactive emanations which it yielded . Its See also:discovery was a sequel to H . See also:Becquerel's observation in 1896 that certain uranium preparations emitted a See also:radiation resembling the X rays observed by See also:Rontgen in 1895 . Like the X rays, the Becquerel rays are invisible; they both See also:traverse thin sheets of See also:glass or See also:metal, and cannot be refracted; moreover, they both ionize gases, i.e. they See also:discharge a charged See also:electroscope, the latter, however, much more feebly than the former . Characteristic, also, is their See also:action on a photographic See also:plate, and the See also:phosphorescence which they occasion when they impinge on See also:zinc sulphide and some other salts . Notwithstanding these resemblances, these two sets of rays are not indentical . Mme . Curie, regarding See also:radioactivity—i.e. the emission of rays like those just mentioned—as a See also:property of some undiscovered substance, submitted pitchblende to a most careful See also:analysis . After removing the uranium, it was found that the See also:bismuth separated with a very active substance—polonium; this element was afterwards isolated by Marckwald, and proved to be identical with his radiotellurium; that the See also:barium could be separated with another active substance—See also:radium; whilst a third fraction, composed mainly of the rare earths (See also:thorium, &c.), yielded to Debierne another radioactive element—actinium, which proved to be identical with the emanium of Giesel . Another radioactive substance—ionium—was isolated from carnotite, a uranium mineral, by B . B . Boltwood in 1905 . Radio-active properties have also been ascribed to other elements, e.g. thorium and See also:lead . There is more radium than any other radio-active element, but its excessive rarity may be gauged by the facts that Mme . Curie obtained only a fraction of a gramme of the chloride and Giesel •2 to •3 gramme of the bromide from a ton of uranium residues . There is a See also:mass of See also:evidence to show that radium is to be regarded as an element, and in See also:general its properties resemble those of the metals of the alkaline earths, more particularly barium . To the See also:bunsen See also:flame a radium See also:salt imparts an intense See also:carmine-red See also:colour (barium gives a See also:green) . The spectrum, also, is very characteristic . The atomic See also:weight, 226.4, places the element in a vacant position in See also:group II. of the periodic See also:classification, along with the alkaline See also:earth metals . Generally speaking, the radiation is not See also:simple . Radium itself emits three types of rays: (I) the a rays, which are regarded as positively charged See also:helium atoms; these rays are stopped by a single See also:sheet of See also:paper; (2) the j3 rays, which are identified with the See also:cathode rays, i.e. as a single See also:electron charged negatively; these rays can penetrate sheets of See also:aluminium, glass, &c., several millimetres thick; and (3) the 'y rays—which are non-electrified radiations characterized by a high penetrating See also:power, 1% surviving after traversing 7 cm. of lead or 150 cm. of See also:water . In addition, radium evolves an " See also:emanation " which is an extraordinarily inert See also:gas, recalling the " inactive " gases of the See also:atmosphere . We thus see that radium is continually losing See also:matter and See also:energy as See also:electricity; it is also losing energy as See also:heat, for, as was observed by Curie and Laborde, the temperature of a radium salt is always a degree or two above that of the atmosphere, and they estimated that a gramme of pure radium would emit about roo gramme-calories per See also:hour . The Becquerel rays have a marked chemical action on certain substances . The Curies showed that See also:oxygen was convertible into See also:ozone, and Sudborough that yellow See also:phosphorus gave the red modification when submitted to their See also:influence . More interesting are the observations of D . See also:Berthelot, F . Bordas, C . Doelter and others, that the rays induce important changes in the See also:colours of many minerals . (See RADIOACTIVITY.) The action of radium on human tissues was unknown until rigor, when, See also:Professor Becquerel of See also:Paris having incautiously carried a See also:tube in his waistcoat See also:pocket, there appeared on the skin within fourteen days a severe inflammation which was known as the famous " Becquerel See also:burn." Since that See also:time active investigation into the action of radium on diseased tissues has been carried on, resulting in the See also:establishment in Paris in 1906 of the " Laboratoire biologique du Radium." Similar centres for study have been inaugurated in other countries, notably one in See also:London in 1909 . The diseases to which the application has been hitherto confined are papillomata, See also:lupus vulgaris, See also:epithelial tumours, syphilitic ulcers, pigmentary naevi, angiomata, and See also:pruritus and chronic itching of the skin; but the use of radium in See also:therapeutics is still experimental . The different varieties of rays used are controlled by the intervention of screens or filtering substances, such as See also:silver, lead or aluminium . Radium is analgesic and bactericidal in its action . See Radiumtherapie, by Wickham and Degrais (1909); See also:Die therapeutische Wirkung der Radiumstrahlen, by O . Lassar, in See also:Report of Radiology See also:Congress, See also:Brussels, 1906; E . Dorn, E . Baumann and S . Valentiner in Physische Zeitung (1905); See also:Abbe in Medical See also:Record (See also:October 1907) . |
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