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See also:RHYOLITE (Gr. peiv, to flow, because of the frequency with which they exhibit fluxion structures) , the See also:group name of a type of volcanic See also:rock, occurring mostly as See also:lava flows, and characterized by a highly See also:acid See also:composition . They are the most siliceous of all lavas, and, with the exception of the dacites, are the only lavas which contain See also:free See also:primary See also:quartz . In chemical composition they very closely resemble the granites which are the corresponding rocks of plutonic or deep-seated origin; their minerals also See also:present many points of similarity to those of See also:granite though they are by no means entirely the same . Quartz, See also:orthoclase and See also:plagioclase felspars, and See also:biotite are the commonest ingredients of both rocks, but the quartz of rhyolites is full of See also:glass enclosures and the potash See also:felspar is pellucid sanidine, while the quartz of granite contains dust-like fluid cavities of very See also:minute See also:size and its potash felspar is of the turbid variety which is properly called orthoclase . The granites also are holocrystalline, while in the rhyolites there are usually porphyritic crystals floating in a See also:fine ground-See also:mass . Rhyolites have also been called liparites because many of the lavas of the Lipari Islands are excellent examples of this group . Above all rocks they have a disposition to assume vitreous forms, as when fused they crystallize with See also:great difficulty . Hence it has See also:long baffled experimenters to produce See also:rhyolite synthetically by See also:fusion; it is stated that these difficulties have now been over-come, but geologists believe that the presence of See also:steam and other gases in the natural See also:state expedites See also:crystallization . In crucibles these cannot be retained at the temperatures employed; when the rocks are melted the gases See also:escape and on cooling a pure glass is formed . The vitreous forms of rhyolite are known as See also:obsidian, See also:perlite and See also:pumice (qq.v.) . The minerals of the first See also:generation, or phenocrysts, of rhyolite are generally orthoclase, See also:oligoclase, quartz, biotite, See also:augite or See also:hornblende . The felspars are usually glassy clear, small but of well-See also:developed crystalline See also:form: the potash felspar is sanidine, usually See also:Carlsbad twinned; the soda-See also:lime felspar is almost always oligoclase, with characteristic polysynthetic structure .
Both of these may be corroded and irregular in their outlines; their cleavage and twinning then distinguish them readily from quartz
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Glass en-closures, sometimes rectangular with small immobile bubbles, are frequent
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The quartz occurs as blebs or sub-rounded grains, which are corroded See also:double hexagonal pyramids
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Its glass enclosures are many and nearly always rounded or elliptical in See also:section
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No proper cleavage is seen in the quartz, though arcuate (conchoidal) fractures may often be noticed; they may have been produced by See also:strain on cooling
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Phenocrysts of micropegmatite are known in some rhyolites; they may have the shape of felspar or of quartz crystals; in the former See also:case Carlsbad twinning is by no means uncommon, but in other cases See also:hour-glass structure is very conspicuous
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Biotite is always deep See also: See also:Olivine is never a normal ingredient, but occurs in the hollow See also:spherulites or lithophysae of some rhyolites with See also:garnet, See also:tridymite, See also:topaz and other minerals which indicate pneumatolytic See also:action . Among the less common See also:accessory minerals of the rhyolites are cordierite in crystals which resemble hexagonal prisms but break up under polarized See also:light into six radiating sectors owing to complicated twinning: they See also:weather to green aggregates of See also:chlorite and muscovite (pinite) ; garnet, See also:sphene and orthite may also be met with in rhyolites . The ground-mass of rhyolitic rocks is of three distinct types which are stages in crystalline development, viz. the vitreous, the felsitic or cryptocrystalline, and the microcrystalline . Hence some authorities have proposed to subdivide the group into the vitrophyres, the felsophyres and the granophyres, but this is.not now in use, and the last of these terms has obtained a signification quite different from that originally assigned to it . Mixtures of the different kinds occur; thus a vitreous rhyolite has often felsitic areas in its ground-mass, and in the same lava flow some parts may be vitreous while others are felsitic . The vitreous rhyolites are identical in most respects with. the obsidians, from which they can only be separated in an artificial See also:classification; and in their glassy See also:base the banded or eutaxitic, spherulitic and perlitic structures of pure obsidians are very frequently present (see OBSIDIAN; PERLITE) . The felsoliparites or liparites with stony ground-mass are especially common among the pre-See also:Tertiary igneous rocks (see QUARTZ-See also:PORPHYRY), as liparite glass is unstable and experiences devitrification in course of See also:time . Many of these felsites have fluxion banding, spherulites and even perlitic cracks, which are strong See also:evidence that they were originally glassy . In other cases a hyaloliparite, obsidian, or See also:pitchstone becomes felsitic along its See also:borders and See also:joint planes, or even along perlitic cracks, and we may assume that the once fibrous rock has changed into See also:felsite under the action of percolating moisture or even by atmospheric decomposition . In many rhyolites the felsite is See also:original and represents an incipient crystallization of the vitreous material which took See also:place before the rock was yet See also:cold . The felsite in turn is liable to See also:change; it becomes a fine See also:mosaic of quartz and See also:alkali felspar; and in this way a See also:matrix of the third type, the microcrystalline, may develop . This is proved by the occurrence of the remains of spherulitic and perlitic structures in rocks which are no longer felsitic or glassy .
Many micro-crystalline rhyolites have a ground-mass in which much felsitic See also:matter occurs; but as this tends to recrystallize in course of time, the older rocks of this group show least of it
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Whilst no quartz-bearing rhyolites are known to have been erupted in See also:recent years, See also:Lacroix proved that portions of the " See also:dome " which See also:rose as a great See also:tower or See also:column out of the See also:crater of Mont Pelee after the eruption in 1906 contained small crystals of quartz in the ground-mass
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The rock was an acid See also:andesite; and it was ascribed by Lacroix to the action of steam retained in the rock under considerable pressure
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The microcrystalline ground-mass of rhyolites is never micrographic as in the porphyries (granophyres); on the other See also:hand it is often micropoikilitic, consisting of small felspars, often sub-rectangular, embedded in little rounded or irregular plates of quartz
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The ground-mass of rhyolites is liable to other changes, of which the most important are silicification, kaolinization and sericitization
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Among the older rocks of this group it is the exception to find that secondary quartz has not been de-posited in some parts of them
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Often indeed the matrix is completely replaced by See also:silica in the form of finely crystalline quartz or See also:chalcedony; and these rocks on See also:analysis prove to contain over 9o% of silica
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In the recent rhyolites of See also:Hungary, New See also:Zealand, &c., the See also:deposit of coarse See also:opal in portions of the rock is a very common phenomenon
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Kaolinization may be due to weathering, and the stony dull See also:appearance of the matrix of many microcrystalline rhyolites is a consequence of the decomposed state of the felspar grains in them; it is even more typically developed by See also:fumarole action, which replaces the felspars with soft, cloudy See also:
The " See also: In other parts of See also:Europe rhyolites have a fairly wide See also:distribution though they are not very numerous . In Hungary (Hlinik, &c.) there are many well-known examples of this class . They extend along the margin of the Carpathians and are found also in Siebenburgen . In See also:Italy they occur in the Euganean Hills and in the Lipari Islands; the latter being the See also:principal source of pumice at the present See also:day . Rhyolites of Recent See also:age occur in See also:Iceland (Myvatn, &c.), where they are characterized by the frequent See also:absence of quartz, and the presence of much plagioclase and See also:pyroxene . Some of these rocks have been called See also:trachyte-obsidians, but they seem to be rhyolites which contain an exceptionally large amount of soda . The older rhyolites, which are generally called quartz-porphyries in Germany, are mostly of See also:Permian or Carboniferous age and are numerous in the See also:Vosges, Odenwald, Thuringerwald, &c . They are often accompanied by basic rocks (melaphyres) . Permian rhyolites occur also at See also:Lugano in Italy . Rhyolites are known also in See also:Asia See also:Minor and the See also:Caucasus, in New Zealand, See also:Colorado, See also:Nevada and other parts of western North See also:America . In the Yellowstone See also:National See also:Park there is a well-known cliff of obsidian which shows remarkably perfect columnar jointing . Some of the rhyolites of Nevada are exceedingly See also:rich in porphyritic minerals, so that they appear at first sight to be holocrystalline rocks, since the ground-mass is scanty and inconspicuous . To this type the name nevadite has been given, but it is rare and See also:local in its distribution . In the See also:island.of Pantellaria, which lies to the See also:south-See also:west of See also:Sicily, there are rocks of rhyolitic See also:affinities which present so many unusual features that they have been designated pantellarites . They contain less silica and alumina and more alkalis and See also:iron than do See also:ordinary rhyolites . Their felspars are of the anorthoclase group, being rich in soda together with potash, and are very variable in crystalline development . Aegirine-augite and forms of soda-See also:amphibole are also characteristic of these rocks: dark brown aenigmatite or cossyrite often occur in them . Quartz is not very plentiful; other ingredients are olivine, arfvedsonite and tridymite . The ground-mass varies much, being sometimes quite vitreous, at other times a glass filled with swarms of microliths, while in certain pantellarites it is a microcrystalline aggregate of quartz and alkali felspar . The absence . of plagioclase and biotite are marked distinctions between these rocks and the rhyolites, together with the scarcity of quartz and the prevalence of soda-bearing pyroxenes and amphiboles . Among the Palaeozoic volcanic rocks of Germany there is a group of lavas, the quartz-keratophyres, which are of acid composition and rich in alkali felspar . Their dominant alkali is soda: hence their felspars are See also:albite and cryptoperthite, not sanidine as in rhyolites . Quartz occurs sometimes as corroded phenocrysts, but is often scarce even in the ground-mass . Porphyritic biotite or augite are very rare, but occur in the matrix along with felspars and quartz . Micropegmatite is not infrequent in these rocks, and they may be silicified like the rhyolites . As quartz-keratophyres mostly occur in districts where there has been a See also:good See also:deal of folding, they are often crushed and more or less sericitized . They are best known from the Devonian rocks of See also:Westphalia and the Harz, but are also found in See also:Queensland, and similar rocks have been described (as soda-felsites) from See also:Ireland . The rocks which they accompany are usually diabases and spilites . The other group of rhyolitic rocks rich in alkali felspars and soda pyroxenes and amphiboles are the comendites . They are often porphyritic, with crystals of quartz, sanidine, microperthite or albite: the ground-mass is microcrystalline or rarely micrographic, and often filled with spongy growths of aegirine and riebeckite . They are known from the recent eruptive districts of See also:East See also:Africa, from See also:Sardinia and See also:Texas, and very similar rocks occur as intrusive masses which may be grouped with the porphyries . The following analyses show the composition of some of the principal types of rhyolites: SiO, Al20a Fe20a FeO CaO MgO K2O Na2O See also:H2O I . 76'34 13.22 1.93 1.85 0.21 3.67 2.84 o•61 II . 72.15 13.50 3.12 0.93 0.16 4.54 4'20 o•85 IV . 67.48 9.70 7.42 2.21 1.45 0.77 2.94 7.21 0.96 V . 70.97 13.84 3.21 0.78 1.26 0.20 1.57 6.27 0.74 VI . 74'76 Ii•6o 3.50 0.19 0.07 0.18 4'92 4'35 0'64 I . Rhyolite, Telki Banya, Hungary . II. do . Mafahlid, Iceland . IV . Pantellarite, Pantellaria . V . Quartz-keratophyre, Muhlenthal, Harz . VI . Comendite, Sardinia . We See also:note in the rhyolites I.-III. the very high silica, with alkalis and alumina also in considerable amount, while lime, See also:magnesia and iron are very See also:low . In the pantellarite, keratophyre and comendite the silica tends to be less abundant, while the alkalis, especially soda, increase; they have less alumina but are richer in iron and magnesia.' It is easy to see why the latter types contain less quartz, felspars often very rich in soda, and femic minerals which contain iron and alkalis in notable amounts such as aegirine, riebeckite and arfvedsonite . (J . S . |
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