See also:RUST (O.E. rust, a word which appears in -many See also:Teutonic See also:languages, cf. Du. roest, Ger. rost); in origin it is allied with " ruddy " and " red," the reddish-See also:- BROWN
- BROWN, CHARLES BROCKDEN (1771-181o)
- BROWN, FORD MADOX (1821-1893)
- BROWN, FRANCIS (1849- )
- BROWN, GEORGE (1818-188o)
- BROWN, HENRY KIRKE (1814-1886)
- BROWN, JACOB (1775–1828)
- BROWN, JOHN (1715–1766)
- BROWN, JOHN (1722-1787)
- BROWN, JOHN (1735–1788)
- BROWN, JOHN (1784–1858)
- BROWN, JOHN (1800-1859)
- BROWN, JOHN (1810—1882)
- BROWN, JOHN GEORGE (1831— )
- BROWN, ROBERT (1773-1858)
- BROWN, SAMUEL MORISON (1817—1856)
- BROWN, SIR GEORGE (1790-1865)
- BROWN, SIR JOHN (1816-1896)
- BROWN, SIR WILLIAM, BART
- BROWN, THOMAS (1663-1704)
- BROWN, THOMAS (1778-1820)
- BROWN, THOMAS EDWARD (1830-1897)
- BROWN, WILLIAM LAURENCE (1755–1830)
brown powdery substance which forms on the See also:surface of See also:iron or See also:steel exposed to atmospheric corrosio
n
.
Formerly the See also:process was regarded as oxidation pure and See also:simple, and, although it was known that See also:iron did not See also:rust in dry See also:air, yet no See also:attempt was made to explain why See also:water was necessary to the See also:action
.
F
.
Crace-See also:Calvert in 1871 showed that the See also:carbon dioxide of the See also:atmosphere was a See also:factor; and in 1888 Crum See also:- BROWN
- BROWN, CHARLES BROCKDEN (1771-181o)
- BROWN, FORD MADOX (1821-1893)
- BROWN, FRANCIS (1849- )
- BROWN, GEORGE (1818-188o)
- BROWN, HENRY KIRKE (1814-1886)
- BROWN, JACOB (1775–1828)
- BROWN, JOHN (1715–1766)
- BROWN, JOHN (1722-1787)
- BROWN, JOHN (1735–1788)
- BROWN, JOHN (1784–1858)
- BROWN, JOHN (1800-1859)
- BROWN, JOHN (1810—1882)
- BROWN, JOHN GEORGE (1831— )
- BROWN, ROBERT (1773-1858)
- BROWN, SAMUEL MORISON (1817—1856)
- BROWN, SIR GEORGE (1790-1865)
- BROWN, SIR JOHN (1816-1896)
- BROWN, SIR WILLIAM, BART
- BROWN, THOMAS (1663-1704)
- BROWN, THOMAS (1778-1820)
- BROWN, THOMAS EDWARD (1830-1897)
- BROWN, WILLIAM LAURENCE (1755–1830)
Brown published the theory—termed the " carbonic See also:acid theory "—that water and carbon dioxide react with iron to See also:form ferrous carbonate and See also:hydrogen, the ferrous carbonate being subsequently oxidized by moist See also:oxygen to ferric See also:hydrate and regenerating carbon dioxide, which again reacts with more iron
.
This theory was controverted by See also:Wyndham See also:Dunstan, who attempted to prove that carbon dioxide was not necessary to rusting; and in See also:place of the acid theory, he set up a See also:- SCHEME (Lat. schema, Gr. oxfjya, figure, form, from the root axe, seen in exeiv, to have, hold, to be of such shape, form, &c.)
scheme which involved the See also:production of hydrogen peroxide
.
G
.
T
.
See also:Moody has since shown that when all traces of carbon dioxide are removed (which is a matterof See also:great experimental difficulty) iron may be See also:left, in contact with oxygen and water for See also:long periods without rust appearing, but on the See also:admission of carbon dioxide specks are rapidly formed
.
It also appears that rust changes in See also:composition on exposure to the atmosphere, both the ferrous See also:oxide and carbonate being in See also:part oxidized to ferric oxide
.
Acids, other than carbonic, may promote rusting; this is particularly the See also:case with ironwork exposed to the acids—sulphurous, nitric, &c. contained in See also:smoke
.
It is probable that the action depends upon the presence of iron, oxygen and water, and some acid which makes the water an electrolyte
.
See also:Steel differs in many ways from iron in respect of atmospheric corrosion; the heterogeneous nature of steel gives occasion to a selective rusting, ferrite is much more readily attacked than the cementite and pearlite; moreover, the introduction of other elements may retard rusting; this is particularly the case with the See also:nickel-steels
.
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