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RUST (O.E. rust, a word which appears...

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Originally appearing in Volume V23, Page 936 of the 1911 Encyclopedia Britannica.
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RUST (O.E. rust, a word which appears in -many See also:Teutonic See also:languages, cf. Du. roest, Ger. rost); in origin it is allied with " ruddy " and " red," the reddish-See also:brown powdery substance which forms on the See also:surface of See also:iron or See also:steel exposed to atmospheric corrosio  n . Formerly the See also:process was regarded as oxidation pure and See also:simple, and, although it was known that See also:iron did not See also:rust in dry See also:air, yet no See also:attempt was made to explain why See also:water was necessary to the See also:action . F . Crace-See also:Calvert in 1871 showed that the See also:carbon dioxide of the See also:atmosphere was a See also:factor; and in 1888 Crum See also:Brown published the theory—termed the " carbonic See also:acid theory "—that water and carbon dioxide react with iron to See also:form ferrous carbonate and See also:hydrogen, the ferrous carbonate being subsequently oxidized by moist See also:oxygen to ferric See also:hydrate and regenerating carbon dioxide, which again reacts with more iron . This theory was controverted by See also:Wyndham See also:Dunstan, who attempted to prove that carbon dioxide was not necessary to rusting; and in See also:place of the acid theory, he set up a See also:scheme which involved the See also:production of hydrogen peroxide . G . T . See also:Moody has since shown that when all traces of carbon dioxide are removed (which is a matterof See also:great experimental difficulty) iron may be See also:left, in contact with oxygen and water for See also:long periods without rust appearing, but on the See also:admission of carbon dioxide specks are rapidly formed . It also appears that rust changes in See also:composition on exposure to the atmosphere, both the ferrous See also:oxide and carbonate being in See also:part oxidized to ferric oxide . Acids, other than carbonic, may promote rusting; this is particularly the See also:case with ironwork exposed to the acids—sulphurous, nitric, &c. contained in See also:smoke . It is probable that the action depends upon the presence of iron, oxygen and water, and some acid which makes the water an electrolyte . See also:Steel differs in many ways from iron in respect of atmospheric corrosion; the heterogeneous nature of steel gives occasion to a selective rusting, ferrite is much more readily attacked than the cementite and pearlite; moreover, the introduction of other elements may retard rusting; this is particularly the case with the See also:nickel-steels .

End of Article: RUST (O.E. rust, a word which appears in -many Teutonic languages, cf. Du. roest, Ger. rost); in origin it is allied with " ruddy " and " red," the reddish-brown powdery substance which forms on the surface of iron or steel exposed to atmospheric corrosio
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RUSSIAN LITERATURE
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