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SCAPOLITE (Gr. O'Kairos, rod, )tLOoc,...

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Originally appearing in Volume V24, Page 301 of the 1911 Encyclopedia Britannica.
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SCAPOLITE (Gr. O'Kairos, See also:rod, )tLOoc, See also:stone)  , a See also:group of See also:rock-forming minerals composed of See also:aluminium, See also:calcium and See also:sodium silicate with See also:chlorine . The See also:variations in See also:composition of the different members of the group may be expressed by the isomorphous mixture of the molecules Ca4A16Si6O25 and Na4A13Si9O24C1, which are referred to as the meionite (Me) and marialite (Ma) molecules respectively, since they predominate in these two end-members of the See also:series . Wernerite, or See also:common See also:scapolite (MeaMai to MeiMa2)and mizzonite (MeiMa2 to Me,Maa) are intermediate members . The tetragonal crystals are hemi- hedral with parallel faces (like See also:scheelite), and usually have the See also:form of square columns, some- times of considerable See also:size . There are distinct cleavages parallel to the See also:prism-faces . Crystals are usually See also:white or greyish-white and opaque, though meionite is found as colourless glassy crystals in the ejected See also:limestone blocks of See also:Monte Somma, See also:Vesuvius . The hardness is 5-6, and the specific gravity varies with the chemical com- position between 2.74 (meionite) and 2.56 (marialite) . The scapolites are especially liable to alteration by weathering processes, with the development of See also:mica, See also:kaolin, &c., and this is the cause of the usual opacity of the crystals . Owing to this alteration, and to the variations in composition, numerous varieties have been distinguished by See also:special names . Scapolite is commonly a See also:mineral of metamorphic origin, occur- See also:ring usually in crystalline limestones, but also with See also:pyroxene in See also:schists and gneisses . The See also:long slender prisms abundant in the crystalline limestones and schists in the See also:Pyrenees are known as " dipyre " or " couzeranite." Large crystals of common scapolite (wernerite) are found in the See also:apatite deposits in the neighbourhood of Bamle near Brevik in See also:Norway, and have resulted from the alteration of the See also:plagioclase See also:felspar of a See also:gabbro . (L .

J . S.) Scapolite Rocks . According to their See also:

genesis the scapolite rocks fall naturally into four See also:groups . 1 . The scapolite limestones and contact rocks . As silicates See also:rich in See also:lime, it is to be expected that these minerals will be found where impure limestones have been crystallized by contact with an igneous magma . Even meionite (the variety richest in soda) occurs in this association, being principally obtained in small crystals lining cavities in ejected blocks of crystalline limestone at Vesuvius and the craters of the See also:Eifel in See also:Germany . Scapolite and wernerite are far more common at the contacts of limestone with intrusive masses . The minerals which accompany them are See also:calcite, See also:epidote, See also:vesuvianite, See also:garnet, See also:wollastonite, See also:diopside and See also:amphibole . The scapolites are colourless, flesh-coloured, See also:grey or greenish; occasionally they are nearly See also:black from the presence of very small enclosures of graphitic material . They are not in very perfect crystals, though sometimes incomplete octagonal sections are visible; the tetragonal cleavage, strong See also:double See also:refraction and uniaxial interference figure distinguish them readily from other minerals . Commonly they See also:weather to micaceous aggregates, but sometimes an isotropic substance of unknown nature is seen replacing them .

In crystalline limestones and See also:

tale-silicate rocks they occur in small and usually inconspicuous grains mingled with the other components of the rock . Large, nearly idiomorphic crystals are sometimes found in argillaceous rocks (altered calcareous shales) which have suffered thermal See also:metamorphism . In the Pyrenees there are extensive outcrops of lime-See also:stone which are penetrated by igneous rocks described as See also:ophites (varieties of See also:diabase) and lherzolites (peridotites) . At the contacts scapolite occurs in a See also:great number of places, both in the limestones and in the calcareous shales which accompany them . In some of these rocks large crystals of one of the scapolite minerals (an See also:inch or two in length) occur, usually as octagonal prisms with imperfect terminations . In others the mineral is found in small irregular grains . It is sometimes clear, but often crowded with See also:minute en-closures of See also:augite, See also:tourmaline, See also:biotite and other minerals, such as constitute the surrounding See also:matrix . From these districts also a black variety is well known, filled with minute graphitic enclosures, often exceedingly small and rendering the mineral nearly opaque . The names couzeranite and dipyre are often given to this See also:kind of scapolite . Apparently the presence of chlorine in small quantities, which may often be detected in limestones, to some extent deter-mines the formation of the mineral . 2 . In many basic igneous rocks, such as gabbro and diabase, scapolite replaces felspar by a secondary or metasomatic See also:process .

Phoenix-squares

Some See also:

Norwegian scapolite-gabbros (or dioritee) examined microscopically furnish examples of every See also:stage of the process . The chemical changes involved are really small, one of the most important being the See also:assumption of a small amount of chlorine in the new See also:molecule . Often the scapolite is seen spreading through the felspar, portions being completely replaced, while others are still fresh and unaltered . The felspar does not weather, but remains fresh, and the transformation resembles metamorphism rather than weathering . It is not a superficial process, but apparently takes See also:place at some See also:depth under pressure, and probably through the operation of solutions or vapours containing chlorides . The basic soda-lime felspars (See also:labradorite to See also:anorthite) are those which undergo this type of alteration . Many instances of scapolitization have been de-scribed from the ophites (diabases) of the Pyrenees . In the unaltered See also:state these are ophitic and consist of pyroxene enclosing See also:lath-shaped plagioclase felspars; the pyroxene is often changed to uralite . When the felspar is replaced by scapolite the new mineral is fresh and clear, enclosing often small grains of See also:hornblende . Extensive recrystallization often goes on, and the ultimate product is a spotted rock with white rounded patches of scapolite surrounded by granular aggregates of clear See also:green hornblende: in fact the See also:original structure disappears . 3 . In Norway scapolite-hornblende rocks have long been known at Oedegarden and other localities .

They have been called spotted gabbros, but usually do not contain felspar, the white spots being entirely scapolite while the dark matrix enveloping them is an aggregate of green or brownish hornblende . In many features they See also:

bear a See also:close resemblance to the scapolitized ophites of the Pyrenees . It has been suggested that the See also:conversion of their original felspar (for there can be no doubt that they were once gabbros, consisting of plagioclase and pyroxene) into scapolite is due to the percolation of chloride solutions along lines of weakness, or planes of solubility, filling cavities etched in the substance of the mineral . Subsequently the chlorides were absorbed, and pari passu the felspar was trans-formed into scapolite . But it is found that in these gabbros there are See also:veins of a chlorine-bearing apatite, which must have been de-posited by gases or fluids ascending from below . This suggests that a pneumatolytic process has been at See also:work, similar to that by which, around intrusions of See also:granite, veins rich in tourmaline have been laid down, and the surrounding rocks at the same See also:time permeated by that mineral . In the composition of the active gases a striking difference is shown, for those which emanate from the granites are mainly See also:fluorine and See also:boron, while those which come from the gabbro are principally chlorine and See also:phosphorus . In one See also:case the felspar is replaced by See also:quartz and white mica (in See also:greisen) or quartz and tourmaline (in See also:schorl rocks) ; in the other case scapolite is the See also:principal new product . The See also:analogy is a very close one, and this theory receives much support from the fact that in See also:Canada (at various places in See also:Ottawa and See also:Ontario) there are numerous valuable apatite vein-deposits . They See also:lie in basic rocks such as gabbro and See also:pyroxenite, and these in the neighbourhood of the veins have been extensively scapolitized, like the spotted gabbros of Norway . 4 . In many parts of the See also:world metamorphic rocks of gneissose See also:character occur containing scapolite as an essential constituent .

Their origin is often obscure, but it is probable that they are of two kinds . One series is essentially igneous (ortnogneisses) ; usually they contain See also:

pale green pyroxene, a variable amount of felspar, See also:sphene, See also:iron oxides . Quartz, See also:rutile, green hornblende and biotite are often See also:present, while garnet occurs sometimes; See also:hypersthene is rare . They occur along with other types of pyroxene See also:gneiss, hornblende gneiss, amphibolites, &c . In many of them there is no See also:reason to doubt that the scapolite is a See also:primary mineral . Other scapolite gneisses equally metamorphic in aspect and structure appear to be sedimentary rocks . Many of them contain calcite or are very rich in calc-silicates (wollastonite, diopside, &c.), which suggests that they were originally impure limestones . The frequent association of this type with graphitic-schists and See also:andalusite-schists makes this correlation in every way probable . Biotite is a common mineral in these rocks, which often contain also much quartz and See also:alkali felspar . (J . S .

End of Article: SCAPOLITE (Gr. O'Kairos, rod, )tLOoc, stone)
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