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KARL WILHELM SCHEELE (1742-1786)

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Originally appearing in Volume V24, Page 315 of the 1911 Encyclopedia Britannica.
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KARL WILHELM See also:

SCHEELE (1742-1786)  , See also:Swedish chemist, was See also:born at See also:Stralsund, the See also:capital of See also:Pomerania, which then belonged to See also:Sweden, on the 19th of See also:December 1742 . He was apprenticed at the See also:age of fourteen to an See also:apothecary in See also:Gothenburg, with whom he stayed for eight years . His spare See also:time and See also:great See also:part of his nights were devoted to the experimental examination of the different bodies which he dealt with, and the study of the See also:standard See also:works on See also:chemistry . He thus acquired a large See also:store of knowledge and great See also:practical skill and manipulative dexterity . In 1765 he removed to See also:Malmo, and in 1768 to See also:Stockholm . While there he wrote an See also:account of his experiments with cream of See also:tartar, from which he had isolated tartaric See also:acid, and sent it to T . O . See also:Bergman, the leading chemist in Sweden . See also:Berg-See also:man somehow neglected it, and this caused for a time a reluctance on See also:Scheele's part to become acquainted with that savant, but the See also:paper, through the instrumentality of Anders Johann Retzius (1742-1821), was ultimately communicated to the See also:Academy of Sciences at Stockholm . He See also:left Stockholm in 1770 and took up his See also:residence at See also:Upsala, where through the agency of Johann Gottlieb Gahn (1745-1818), See also:assessor of mines at Fahlun, he made the See also:personal acquaintance of Bergman . A friendship, of mutual See also:advantage, soon sprang up between the two men, and it has been said that Scheele was Bergman's greatest See also:discovery . In 1775, the See also:year in which he was elected into the Stockholm Academy of Sciences, he left Stockholm for Koping, a small See also:place on See also:Lake See also:Malar, where he became provisor and subsequently proprietor of a See also:pharmacy .

The business, however, was not what he had been led to expect, and it took him several years to put it on a See also:

sound footing . Yet in spite of his business cares he found time for an extraordinary amount of See also:original See also:research, and every year he published two or three papers, most of which contained some discovery or observation of importance . His unremitting See also:work, it is said, especially at See also:night, exposing him to See also:cold and See also:draughts, induced a rheumatic attack which brought about his See also:death . He had intended, as soon as his circumstances permitted him, to marry the widow of his predecessor, but his illnessincreased so rapidly that it was only on his death-See also:bed, on the 19th of May 1786, that he carried out his See also:design . Two days later he died, leaving his wife what See also:property he had acquired . Scheele's See also:power as an experimental investigator has seldom if ever been surpassed, and his accuracy is most remarkable when his See also:primitive apparatus, his want of assistance, his place of residence, and the undeveloped See also:state of chemical and See also:physical See also:science in his time, are all taken into account . Research was at once his occupation and his relaxation, and his natural endowments were cultivated by unceasing practice and unwearied See also:attention . Study of his original papers shows that his discoveries were not made at haphazard, but were the outcome of experiments carefully planned to verify inferences already See also:drawn, and successfully designed to See also:settle the point at issue in the simplest and most See also:direct manner . He left nothing in doubt if experiment would decide it, and he evidently did not consider that he had fully investigated any See also:compound until he could both unmake and remake it . His See also:record as a discoverer of new sub-stances is probably unequalled . The See also:analysis of See also:manganese dioxide in 1774 led him to the discovery of See also:chlorine and baryta; to the description of various salts of manganese itself, including the manganates and permanganates, and to the explanation of its See also:action in colouring and See also:decolourizing See also:glass . In 1775 he investigated See also:arsenic acid and its reactions, discovering arseniuretted See also:hydrogen and " Scheele's See also:green " (See also:copper arsenite), a See also:process for preparing which on a large See also:scale he published in 1778 .

Papers published in 1776 were concerned with See also:

quartz, See also:alum and See also:clay and with the analysis of calculus vesicae from which for the first time he obtained uric acid . In 1778 he proposed a new method of making See also:calomel and See also:powder of See also:algaroth, and he got molybdic acid from See also:mineral molybdaena nitens which he carefully distinguished from See also:ordinary molybdena (See also:plumbago or See also:black See also:lead of See also:commerce) . In the following year he showed that plumbago consists essentially of See also:carbon; and he published a record of estimations of the proportions of See also:oxygen in the See also:atmosphere, which he had carried on daily during the whole of 1778—three years before See also:Cavendish . In 178o he proved that the acidity of sour See also:milk is due to what was after-wards called lactic acid; and by boiling milk See also:sugar with nitric acid he obtained mucic acid . His next discovery, in 1781, was the See also:composition of the mineral See also:tungsten, since called See also:scheelite (See also:calcium tungstate), from which he obtained tungstic acid . In 1782 he published some experiments on the formation of See also:ether, and in 1783 examined the properties of glycerine, which he had discovered seven years before . About the same time he showed by a wonderful See also:series of experiments that the colouring See also:matter of Prussian See also:blue could not be produced without the presence of a substance of the nature of an acid, to which the name of prussic acid was ultimately given; and he described the composition, properties and compounds of this See also:body, and even ascertained its See also:smell and See also:taste, quite unaware of its poisonous See also:character . In the last years of his See also:life he returned to the See also:vegetable acids, and investigated citric, malic, oxalic and gallic acids . His only See also:book, on See also:Air and See also:Fire, was published in 1777, but was written some years before . The See also:manuscript was in the hands of the printers in 1775, and most of the experimental work for it was done before 1773 . Although it starts from the erroneous basis of the phlogistic theory, it contains much matter of permanent value . One of the See also:chief observations recorded in it is that the atmosphere is composed of two gases—one which supports See also:combustion and the other which prevents it .

The former, " fire-air," or oxygen, he prepared from " acid of See also:

nitre," from See also:saltpetre, from black See also:oxide of manganese, from oxide of See also:mercury and other substances, and there is little doubt but that he obtained it independently a considerable time before See also:Priestley . Incidentally in 1777 Scheele prepared sulphuretted hydrogen, and noted the chemical action of See also:light on See also:silver compounds and other substances . A See also:list of Scheele's papers is givens in See also:Poggendorff's Biographischliterarisches Handworterbuch (See also:Leipzig, 1863) . They were collected and published in See also:French as Memoires de chymie (See also:Paris, 1785—1788) ; in See also:English as Chemical Essays, by See also:Thomas See also:Beddoes (See also:London, 1786) ; in Latin as Opuscula, translated by Schafer, edited by Hebenstreit (Leipzig, 1788—1789) ; and in See also:German as Sammtliche Werke, edited by Hermbstadt (See also:Berlin, 1793) . The See also:treatise on Air and Fire appeared in German, Leipzig and Upsala in 1777, and again in 1782; in English, by J . R . See also:Forster (London, 178o); and in French, by See also:Dietrich (Paris, 1781) .

End of Article: KARL WILHELM SCHEELE (1742-1786)
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