Search over 40,000 articles from the original, classic Encyclopedia Britannica, 11th Edition.
|
TARTAR
, the name commonly applied to crude See also:acid See also:potassium tartrate or " bitartrate of potash," HK(C4H406)
.
During the See also:process of See also:fermentation wines See also:deposit a crystalline crust of See also:argol; this, after being roughly purified by recrystallization, is known as tartar, and when further purified and freed from colouring matters becomes " cream of tartar," also called technically " cream." With the iatrochemists tartar was a generic See also:term which included both this See also:tartarus vini and various substances obtained from it, and even salts, such as See also:salt of See also:sorrel (potassium oxalate), that resembled it
.
Thus sal fixum tartari was potassium carbonate, which on exposure to the See also:air deliquesces to oleum tartari per deliquium; neutral potassium tartrate was called tartarus tartarisatus, because it was prepared by neutralizing See also:ordinary tartar with the sal fixum; tartarus chalybeatus was a preparation with See also:iron; and spiritus tartari, used by See also:Paracelsus, was prepared by dry See also:distillation of tartar
.
Paracelsus also used the term in a still wider sense to signify abnormal precipitates or sediments deposited from See also:animal secretions; the same See also:idea is apparent in the popular application of the word to the salivary calculus which forms on the See also:teeth
.
Cream of tartar is prepared by dissolving granulated argol in boiling See also:water and allowing the See also:solution to stand
.
The clear liquid is then See also:drawn off and crystallized
.
The slightly coloured crystals thus obtained are redissolved in hot water, the colouring matters got rid of by means of pipeclay or See also:egg-albumen, and the solution filtered and crystallized, the name " crean of tartar " being originally applied to the crust of See also:minute crystals that See also:form on its See also:surface as it cools
.
The salt crystallizes in masses of small, hard, colourless, trans-See also:parent, rhombic prisms
.
It is precipitated when an excess of a potassium salt is added to a solution of tartaric acid, but it dissolves in See also:mineral acids, and in alkalis and alkaline See also:carbonates
.
Solutions of boric acid or See also:borax dissolve it freely, forming soluble cream of tartar, which is a See also: When heated it is decomposed with formation of potassium carbonate and See also:carbon, inflammable gases having an odour of burnt See also:bread being evolved . The salt is used for the manufacture of tartaric acid ; it is also employed in the See also:mordant See also:bath for See also:wool-See also:dyeing, with powdered See also:chalk and See also:alum for cleaning See also:silver, and for the preparation of effervescing drinks and See also:baking-powder . In See also:medicine as potassii tariras acidus it is of some slight importance as a diuretic and purgative . The more soluble normal salt, K2(C4H406), is used for the same purposes; it is formed by dissolving powdered cream of tartar in a hot solution of potassium carbonate . If See also:sodium carbonate is substituted the result is KNa(C4H406), or Rochelle salt . Tartar emetic (potassium antimonyl tartrate) K . (SbO) C4H406•1H2O . This substance has been known for a See also:long See also:period, being mentioned by See also:Basil See also:Valentine . It may be prepared by warming 3 parts of antimonious See also:oxide with 4 parts of cream of tartar, in the presence of water, replacing the water as it evaporates; after digestion is See also:complete, the solution is filtered hot . Powder of See also:algaroth (q.v.) may be used in See also:place of the See also:antimony oxide . Tartar emetic crystallizes in small octahedra, which lose their water of See also:crystallization gradually on exposure to air, and become opaque . It is soluble in 14.5 parts of See also:cold water and 1.9 parts of hot, the solution showing an acid reaction to See also:litmus . It possesses a nauseous metallic See also:taste and produces vomiting when taken internally, whilst in large doses it is poisonous . It is used medicinally, and also as a mordant in dyeing and See also:calico-See also:printing . |
|
|
[back] TARTAN (from F. tiretaine, " linsie-wolsie," Sp. ti... |
[next] TARTARIC ACID (dihydroxy-succinic acid), C4H6O6 |
There are no comments yet for this article.
Do not copy, download, transfer, or otherwise replicate the site content in whole or in part.
Links to articles and home page are encouraged.