Search over 40,000 articles from the original, classic Encyclopedia Britannica, 11th Edition.
|
NH2CO See also:URETHANE ,C,H5, the See also:ethyl ester of carbamic See also:acid, is synthesized from See also:ammonia and chlorcarbonic ester or diethyl carbonate; by prolonged boiling of See also:urea with See also:alcohol (A . W . See also:Hofmann, Ber., 1871, 4, p . 268); by the See also:action of alcoholic hydrochloric acid on See also:cyanogen; by the action of alcohol on urea chloride (L . Gattermann, See also:Ann., 1888, 244, p . 40); and by warming alcoholic hydrochloric acid with an alcoholic See also:solution of See also:potassium cyanate (0 . Folin, Amer . Chem . Jour., 1897, 19, p . 341) . It crystallizes in large plates, readily soluble in See also:water and melting at 49-50° C . When heated with ammonia to ,8o° C., it gives urea . See also:Cold alcoholic potash decomposes it into potassium cyanate and alcohol . Nitroso-See also:urethane, NO . NH • CO2C2H6, formed by reducing ammonium nitro-urethane with See also:zinc dust and glacial acetic acid (J . Thiele, Ann., 1895, 288, p . 304), crystallizes in needles which melt at 51–52° C . (with decomposition) . |
|
|
[back] URENARDE |
[next] URFE |
There are no comments yet for this article.
Do not copy, download, transfer, or otherwise replicate the site content in whole or in part.
Links to articles and home page are encouraged.