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VALERIC See also:ACID, or VALERIANIC ACID , C4H9•See also:CO2H, an organic See also:acid belonging to the fatty acid See also:series, which exists in four isomeric forms, one of which contains an See also:asymmetric See also:carbon See also:atom and consequently occurs in two optically active modifications and one optically inactive modification . See also:Ordinary valeric acid (baldrianic acid) is a mixture of isovaleric acid or isopropylacetic acid, (See also:CH3)2CH•See also:CH2•CO211,andoptically active methylethylacetic acid, (CH3) (C2HS)CH•CO2H, which occur See also:free or as See also:esters in the See also:vegetable and See also:animal kingdoms, chiefly in the roots of See also:Angelica archangelica and Valeriana officinalis . It may be extracted by boiling with See also:water or soda . A similar product isobtained by oxidizing See also:fermentation amyl See also:alcohol with chromic acid . Isovaleric acid is an oily liquid having the odour of stale See also:cheese and boiling at 174°; the salts are usually greasy to the See also:touch . See also:Potassium permanganate oxidizes it to f3-oxyisovaleric acid (CH3)2•C(OH)•CH2•CO2H, whilst nitric acid gives, among other products, dinitropropane, (CH3)2C(NO2)2 . The acid has been synthesized, as has also the inactive See also:form of methylethylacetic acid; this 'modification is split into its See also:optical See also:antipodes by See also:crystallization of its See also:brucine See also:salt . Normal valeric acid or propylacetic acid, CH3•CH2•CH2•CH2•CO2H, is a liquid boiling at 186° . The remaining isomer, pivalic or trimethylacetic acid, (CH3)3C•CO2H, melts at 35° and boils at 163° . Both these acids are synthetic products . |
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