Online Encyclopedia

XANTHIC ACID (xanthogenic acid)

Online Encyclopedia
Originally appearing in Volume V28, Page 881 of the 1911 Encyclopedia Britannica.
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XANTHIC ACID (xanthogenic acid), C2H5O•CS•SH, an organic acid named from the Greek EavBor, yellow, in allusion to the bright yellow colour of its copper salt. The salts of this acid are formed by the action of carbon bisulphide on the alcoholates, or on alcoholic solutions of the caustic alkalis. They react with the alkyl iodides to form dialkyl esters of the dithio-carbonic acid, which readily decompose into mercaptans and thiocarbamic esters on treatment with ammonia: C2H5O•CS•SR1+NH3=C2H5O•CS•NH2+R1•SH; with the alkali alcoholates they give salts of the alkyl thiocarbonic acids: C2H5O•CS•SR +CH3OK+H2O= CH3O•CO•SK+C2H5OH+R•SH. Ethyl xanthic at-id, C2H5O•CS•SH, is obtained by the action of dilute sulphuric acid on the potassium salt at o° C. (Zeise, Bern. Jahresb., 3, p. 83). It is a colourless oil which is very unstable, decomposi at 25° C. into carbon bisulphideand alcohol. The potassium salt crystallizes in colourless needles and is formed by shaking carbon bisulphide with a solution of caustic potash in absolute alcohol. On the addition of cupric sulphate to its aqueous solution it yields a yellow precipitate of cupric xanthate. Potassium xanthate is used in indigo printing and also as an antidote for phylloxera. Tschugaeff (Ber., 1899, 32, p. 3332) has used the xanthic ester formation for the preparation of various terpenes, the methyl ester when distilled under slightly diminished pressure decomposing, in the sense of the equation, C„H2n_1.O.CS•SCH3= C„H2„_2+COS+CH3SH. According to the author molecular change in the hydrocarbon is prevented, since no acid agent is used.
End of Article: XANTHIC ACID (xanthogenic acid)
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